Adsorption of tebuthiuron N-[5-(1,1-dimethylethyl)-1,3,4-thiadiazol-2-yl]-N,N’-dimethylurea appeared to be related to organic matter and clay content. After six successive desorption extractions, 40% of the tebuthiuron was adsorbed in soil with 4.8% organic matter but less than 1% was adsorbed in soil with 0.3% organic matter. Differences in adsorption were also reflected in the activity of tebuthiuron on soybeans [Glycine max (L.) Merr.] and corn (Zea mays L.) where it took 4.9 and 9.5 times as much tebuthiuron, respectively in soil with the greater adsorption to reduce growth by 50%. Soil mobility of tebuthiuron was identical to fluometuron[1,1-dimethyl-3-(α,α,α-trifluoro-m-tolyl),urea] in three soils tested. Soil mobility of herbicides was greater in soil with low organic matter and low clay content. Both temperature and soil moisture had an effect on persistence of tebuthiuron. Greater dissipation occurred at 15% soil moisture and 30 C than at lower moisture and temperature levels.

14C-glyphosate [N-(phosphonomethyl)glycine] degradation to 14CO2 was examined in a Spinks sandy loam, Collamer silt loam, and a Norfolk loamy sand. After 32 days, 40, 9.5, and 3% of the 14C-glyphosate was recovered as 14CO2 in the three soils, respectively. The degradation was primarily microbial. Phosphate additions stimulated 14C-glyphosate degradation to a limited extent in the Collamer silt loam but not in the Norfolk loamy sand. Additions of Fe+++ and Al+++ ions reduced degradation in the Spinks sandy loam. It is postulated that formation of colloidal Fe and Al precipitates in modified soils with concomitant adsorption of 14C-glyphosate is responsible for decreased availability of 14C-glyphosate to microorganisms. Mn++ additions were found to increase degradation. Spinks soil and carbon substrate amendments failed to substantially increase degradation rates in both soils with low degradation rates.

Vapor losses of trifluralin (α,α,α-trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine), benefin (N-butyl-N-ethyl-α,α,α-trifluoro-2,6-p-toluidine), and nitralin [4-(methylsulfonyl)-2,6-dinitro-N,N-dipropylaniline] were studied under controlled laboratory conditions using a Florisil vapor trap. No nitralin vapor losses were detected at 50 C from a Lakeland loamy sand at field capacity with an air flow rate of 0.04 m3/hr for 3 hr; whereas, 24.5% and 12.5% of trifluralin and benefin, respectively, were lost as vapors. Volatility of trifluralin and benefin increased with increasing temperatures of 30, 40, and 50 C and increasing soil moisture from air dryness to field capacity. Vapor losses from granular benefin were similar to the spray applications at 30 and 40 C. Volatilization of granular trifluralin was reduced when compared to the spray application at 40 C and 30 C but was similar for both formulations for benefin. No significant losses from photodecomposition were noted for trifluralin, benefin, or nitralin when comparing radiated and unradiated soil surface treated samples.

Postemergence applications of BAS 9052 OH, {2-[1-(ethoxyimino)butyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one}, at 0.25 and 0.5 kg ai/ha were made to 27 temperate and 28 tropical species of Gramineae. Annual bluegrass (Poa annua L. ♯3 POAAN) and rattail fescue (Festuca myuros L. ♯ VLPMY) were resistant to these rates of BAS 9052 OH. Five species of fescue and three species of bluegrass received postemergence applications of BAS 9052 OH at rates of 0.1 to 6.4 kg ai/ha. The germination of seeds and the subsequent growth of the seedlings of these species as influenced by various concentrations of BAS 9052 OH were also studied. Meadow fescue (Festuca pratensis Huds. ♯ FESPR), tall fescue (Festuca arundinacea Schreb. ♯ FESAR), Kentucky bluegrass (Poa pratensis L. ♯ POAPR), and rough-stalked meadowgrass (Poa trivialis L. ♯ POATR) were most susceptible; annual bluegrass was somewhat less resistant; hard fescue (Festuca longifolia Thuill) was resistant; red fescue (Festuca rubra L. ♯ FESRU) and rattail fescue were very resistant.

Controlled environment experiments showed that velvetleaf plants grown under drought stress or low temperature (LT) treatments had greater leaf epicuticular wax (ECW) deposition compared to plants grown in soil with moisture at field capacity (FC) or a high temperature (HT) regime. Light intensity did not affect ECW deposition; however, increasing light intensity decreased the leaf ECW ester content and increased the secondary alcohol content. Plants grown at an LT regime or under FC had leaf ECW with fewer hydrocarbons and more esters than those grown at an HT or drought stress regime. Velvetleaf absorption of acifluorfen increased as light intensity decreased for plants grown in adequate soil water content, while the opposite was true for drought-stressed plants. Velvetleaf absorption of acifluorfen was approximately 3 and 10 times greater, respectively, with the addition of 28% urea ammonium nitrate (UAN) in comparison to crop oil concentrate (COC) or no adjuvant, regardless of the environmental treatments. Plants absorbed more acifluorfen when subjected to the LT regime in comparison to the HT regime when UAN was the adjuvant, while the opposite was true when COC was the adjuvant. Velvetleaf absorption of acifluorfen was not affected by drought stress when COC or no adjuvant was used and varied between studies when UAN was used. Velvetleaf absorption of bentazon was greatest for plants grown under HT/FC or high light/FC treatments and least with plants grown under HT/drought stress or low light/drought stress treatments, regardless of the adjuvant. However, bentazon absorption was higher with the addition of an adjuvant and for plants grown at a high light intensity or FC condition compared with medium to low light intensity or drought stress treatments.

Rice flatsedge and barnyardgrass are widespread and competitive weeds in direct-seeded rice. Developing integrated weed management strategies that elevate suppression of weeds by rice through crop density, nutrition, and cultivar choice requires better understanding of the extent to which rice interferes with the growth of these weeds and how these species respond to resource limitation with crop interference. Rice interference reduced the height of barnyardgrass but did not affect height of rice flatsedge. These weed species were able to grow taller than rice and thus avoided being shaded. Increased specific stem length under crop interference may demonstrate a strategy of stem elongation to allow the top portion of the weeds to be kept out of shade. Rice interference reduced inflorescence and shoot biomass of both weed species. Barnyardgrass showed the ability to reduce the effects of rice interference by increasing leaf weight ratio. The present study shows that crop interference alone may reduce weed growth but may not give complete control of these weed species. This highlights the need for the integration of management practices to achieve control of these weed species.

Herbicides used as harvest aids are applied at crop maturity to desiccate weed and crop foliage. Weeds present in the harvested crop can increase moisture content and foreign material, reducing grade and market price. Weeds can also delay the harvest operation and reduce harvest efficiency. Glyphosate can be used to desiccate weeds in glyphosate-resistant crops without concern for crop injury. Carfentrazone and pyraflufen-ethyl used as harvest aids can be effective in desiccating broadleaf weeds in corn and soybean. Paraquat, although effective on grass and broadleaf weeds when applied late season, can cause significant crop injury if applied too early. With expanded production of early maturing soybean cultivars in the mid-South (Arkansas, Louisiana, Mississippi, Missouri bootheel, and west Tennessee), presence of green stems, green pods, or green leaf retention, or combinations of these at harvest has increased. Interest in harvest aids has shifted to use as a crop desiccant. Paraquat also is an effective soybean desiccant, but application timing differs for indeterminate and determinate cultivars. Paraquat applied after soybean seed reached physiological maturity reduced number of green stems, pods, and retained green leaves present, allowing harvest to proceed 1 to 2 wk earlier than nontreated soybean. Seed moisture, foreign material, and seed damage also were reduced when paraquat was applied.

Herbicidal activity of foliar-applied oxyfluorfen [2-chloro-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoromethyl)benzene] was light dependent in buckwheat (Fagopyrum esculentum Moench. ‘Tokyo’). Plants were not injured when placed in the dark for as long as 4 days after herbicide treatment. When these plants were brought to the light, injury occurred, albeit more slowly than when plants were placed in the light immediately after treatment. The rate of injury increased as light intensity increased. The most effective wave length was 565 to 615 ηm, suggesting the involvement of a pigment with its absorption spectrum in this region. Chlorophyll content was not reduced by oxyfluorfen. Preliminary evidence suggests that photosynthesis was affected only after membrane integrity was disrupted.

As determined by bioassay of segmented soil columns, a,a,a-trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine (trifluralin), N-butyl-N-ethyl-a,a,a-trifluoro-2,6-dinitro-p-toluidine (benefin), and 4-(methylsulfonyl)-2,6-dinitro-N,N-dipropylaniline (nitralin) varied in their leachability in a clay loam soil, even though their water solubility is the same. Nitralin was by far the more easily leached, benefin was least leached, and trifluralin slightly more so than benefin. Four A-in or more of water readily leached nitralin deep enough into the soil in amounts great enough to adversely affect the root growth of sensitive crop plants. Trifluralin and benefin were leached into the soil in relatively minute amounts, and these amounts were not great enough to affect root growth of sensitive crop plants when at least 0.5-in of untreated soil separated the seed from the layer of soil in which the herbicides had been mixed. The apparent breakdown product of nitralin present in moist soil was leached as readily as nitralin.

Glyphosate-resistant giant ragweed has become an increasing problem, and the potential spread of these biotypes is a threat to production agriculture and to the long-term utility of glyphosate and glyphosate-resistant crops. The fate of glyphosate resistance in a giant ragweed population is dependent on the fitness of the resistant biotype. Our objective was to determine the fitness of glyphosate-resistant giant ragweed in the absence and presence of glyphosate. We compared the growth and seed production of glyphosate-resistant (GR) and glyphosate-susceptible (GS) giant ragweed under field conditions in the absence of glyphosate. A greenhouse study was also conducted to determine the survival of GR and GS giant ragweed and their open-pollinated progeny from the field study under glyphosate-induced selection pressure. In the absence of glyphosate, GR giant ragweed displayed rapid, early season growth, but 50 d after planting, the biotypes were similar in height, shoot weight, and leaf area. During reproduction, the GR biotype flowered earlier and produced 25% less seed than the GS biotype. In the presence of glyphosate, an outcrossing rate of 31% was detected between GR and GS biotypes because 61% of progeny were resistant to glyphosate at 840 g ae ha−1. A second application 14 d later at 2,520 g ae ha−1 completely removed the GS alleles from the population, whereas several homozygous and heterozygous GR plants survived and produced seed. These results indicate GR will persist in the population when subjected to glyphosate and that glyphosate resistance in giant ragweed has the potential to spread rapidly in our current agricultural ecosystem.

Pulse crop management can increase pulse yields and N fixation, but the effects of previous pulse crop management on subsequent crop performance is poorly understood. Field studies were conducted at three locations, in the Parkland region of Alberta, Canada, between 2004 and 2006. Tannin-free faba bean, narrowleaf lupin, and field pea were planted at 0.5, 1.0, 1.5, and 2.0 times the recommended pulse planting density (PPD), with or without barley as a model weed. Faba bean produced the highest seed yields in higher precipitation environments, whereas pea produced the highest seed yields in lower precipitation environments. Lupin seed yields were consistently low. In the absence of weed interference, faba bean, pea, and lupin N-fixation yields ranged from 70 to 223, 78 to 147, and 46 to 173 kg N ha−1, respectively. On average, faba bean produced the highest N-fixation yield. The absence of weed interference and a high PPD increased pulse seed and N-fixation yields. Quality wheat crops were grown on pulse stubble without additional N fertilizer in some site–years. Management practices that increased N fixation resulted in only marginal subsequent wheat yield increases. Subsequent wheat seed yield was primarily influenced by pulse species. Pea stubble produced 11% higher wheat yields than lupin stubble but only 2% higher wheat yields than faba bean stubble. Consistently high wheat yields on pea stubble may be attributed to synchronized N release from decomposing pea residues with subsequent crop N demand and superior non-N rotational benefits.

Two field experiments were conducted from 1993–1994 through 1995–1996 growing seasons in Harney County, OR, to determine the relative competitive abilities of Elymus elymoides (squirreltail) a native perennial range grass, and Taeniatherum caput-medusae (medusahead), an exotic annual grass weed. The 1993–1994 growing season was very dry, 1994–1995 was dry, and 1995–1996 was wetter than average. One experiment tested seedlings vs. seedlings in each of three seasons. The second experiment tested seedlings plus second- and third-year established E. elymoides plants vs. 77 caput-medusae over 2 yr. Biomass, seed production, and soil moisture utilization 15, 30, 45, and 60 cm deep by the two species were measured. A randomized block design with factorial arrangement was used, with 25 2.25-m2 plots per block. Initial seeding densities of each species were 0, 10, 74, 550, and 4,074 seeds m−2 in all combinations of density. In the seedling vs. seedling experiment, intraspecific competition by 77 caput-medusae on itself was always significant (P ≤ 0.10) for both biomass and seed production. Interspecific competition by E. elymoides seedlings on T. caput-medusae biomass and seed production was not significant (P ≥ 0.10) in 2 of 3 yr and was always less than intraspecific competition by 77 caput-medusae. Only 0.4% of E. elymoides seed germinated, and no seed was produced in the very dry first year, but 84% of remaining seed was viable for the next year, which had better moisture conditions for germination and establishment. Interspecific competition affected (P ≤ 0.10) E. elymoides seedling biomass and seed production throughout the study. Intraspecific competition affected (P ≤ 0.10) seedling E. elymoides seed production in the dry year but not in the wetter than average year. In the mature E. elymoides experiment, intraspecific competition by T. caput-medusae on weight and seed production per plant was greater than interspecific competition from E. elymoides. Seedling/mature E. elymoides reduced T. caput-medusae weight per plant in the dry year but the effect was not biologically significant. Larger, mature Eelymoides plants produced 600 to 3,000 seeds per plant during the wet year; neither intra- nor interspecific competition was a factor. Taeniatherum caput-medusae was better able to access deeper soil moisture and was more aggressive at extracting soil moisture than were E. elymoides seedlings in the wet year. Cold soils and low oxygen due to wet soils may have restricted E. elymoides seedling root activity. Mature E. elymoides plants did not appear restricted by cold soils or low oxygen. Established second- and third-year E. elymoides plants were able to compete for soil moisture down to 45 cm. The generally greater interspecific competitive effects of T. caput-medusae on E. elymoides than vice versa suggested that it will be difficult to establish an E. elymoides stand in an existing T. caput-medusae community without first suppressing T. caput-medusae. Individual E. elymoides plants did establish and were productive with and without T. caput-medusae competition.

Low soil water content for 10 to 14 days before and 7 days after herbicide application reduced control of green foxtail with fenoxaprop, fluazifop-P, haloxyfop, and sethoxydim. Withholding irrigation for 10 to 14 days before herbicide application did not reduce control of green foxtail with normal use rates of herbicides if plots were irrigated at the time of application. Low soil water content reduced the activity of sethoxydim less than the other herbicides.

Seedbank studies often suffer from major methodological inadequacies such as absence of appropriate statistical data analysis and low sampling intensity. Multivariate analysis and computer mapping are innovative ways to treat seedbank data. Computer contour mapping was used to visualize spatial patterns of a population of common lambsquarters at three intervals during a growing season. At one site, high spring seed density of 600 000 seed m-2 was decreased to 18.3% of its original size by July, while at another site, low spring seedbank of common lambsquarters of 25 000 seed m-2 increased to 40 000 seed m-2 by autumn. Seedbank studies usually report results on total seed density or on densities of the most abundant species because of difficulties in analyzing large species matrices using parametric statistics. Multivariate analysis and specifically canonical discriminant analysis (CDA) are well suited for seedbank populations. The seedbanks of six agricultural habitats were demonstrated to be floristically different based on the analysis of the relative abundance of weed species in each site using CDA. Organic soils either under grassland or cultivated had significantly larger total seedbanks than mineral soils. If seedbanks are to be used in predictive population models, quantitative data that are reliable, rapidly obtained with limited resources, and logistically feasible for large sampling protocols are needed. Image analysis may be a potential rapid technique for weed seed recognition of washed soil samples.

The absorption, translocation, and metabolism of metribuzin [4-amino-6-tert-butyl-3-(methylthio)-as-triazin-5(4H) one] by soybean (Glycine max Merr. ‘Lee 68′) and hemp sesbania (Sesbania exaltata L.) grown in nutrient solution and in soil treated with 14C-metribuzin were investigated. Absorption studies indicated there were no significant differences in the amount of 14 C-metribuzin absorbed from treated nutrient solution by soybean (tolerant) and hemp sesbania (susceptible). When these species were grown in 14C-metribuzin treated soil, hemp sesbania absorbed appreciably more herbicide than did soybean. 14 C-metribuzin and (or) its 14C-metabolites were translocated from the roots to the shoots of both species. Radioactivity was rapidly translocated and accumulated in all the leaves of hemp sesbania, but it tended to accumulate to the greatest extent in the roots and lower leaves of soybean. Translocation differences between the two species were apparent in plants grown either in soil or nutrient solution treated with 14C-metribuzin. However, differences were greatest in plants grown in treated soil. Preliminary metabolic studies indicated that a higher rate of metribuzin degradation occurred in soybean than in hemp sesbania. The major 14 C-metabolite appeared to be the relatively nonphytotoxic deaminated diketo derivative [6-tert-butyl-1,2,4,-triazine-3-5(2H,4H)dione]. Thus, differences in the absorption, translocation, and metabolism of metribuzin all appeared to contribute to the differential susceptibility of soybean and hemp sesbania to metribuzin.

A 4-yr field test was initiated in 1975 to determine susceptibility of a natural infestation of six morningglory species to herbicides which can be applied to the soil and foliage in soybeans [Glycine max (L.) Merr.]. The species studied were pitted morningglory (Ipomoea lacunosa L.), entireleaf morningglory [Ipomoea hederacea (L.) Jacq. var. integriuscula], ivyleaf morningglory [Ipomoea hederacea (L.) Jacq.], purple moonflower [Ipomoea muricata (L.) Jacq.], palmleaf morningglory [Ipomoea wrightii (Gray)], and small flower morningglory [Jacquemontia tamnifolia (L.) Griseb.]. Control with herbicides applied preplant incorporated and preemergence was dependent on morningglory species and on rainfall to allow plant uptake of the herbicide. Herbicides applied to the soil were not as effective as those applied postemergence. Oxadiazon [2-tert-butyl-4-(2,4-dichloro-5-isopropoxyphenyl)-δ2-1,3,4-oxadiazolin-5-one] gave the best and longest lasting preemergence control, averaging 79% control for all species. Preemergence control with metribuzin [4-amino-6-tert-butyl-3-(methylthio)-as-triazin-5(4H)-one] was dependent on species, with 84% control of small flower morningglory and only 26% for ivyleaf and 18% for entireleaf morningglory. At V2 (one trifoliolate) and V5 stages of soybean growth, acifluorfen {5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoic acid} at 0.56 kg/ha applied over-the-top and oxyfluorfen [2-chloro-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoromethyl)benzene] at 0.28 kg/ha applied post-directed gave 90 and 92% control of all species, respectively. Most effective were repeated post-directed applications at V5 and V7 stages of soybean growth. Metribuzin + 2,4-DB [4-(2,4-dichlorophenoxy)butyric acid] (99%), linuron [3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea] + 2,4-DB (98%), 2,4-DB (95%), and paraquat (1,1′-dimethyl-4,4′-bipyridinium ion) + 2,4-DB (93%) provided excellent control regardless of the morningglory species.

Earlier studies on the source of signals controlling correlative inhibition of root buds (underground adventitious buds located on the lateral roots) in Euphorbia esula indicated that either growing meristems (apical or axillary buds) or fully expanded leaves could prevent root buds from breaking quiescence. An investigation of the production and transport requirements of the leaf-derived signal is described. As few as three leaves remaining on budless stems greatly reduced the growth of (but not the number of growing) root buds. Also, light and CO2 fixation were necessary for the leaf effects on root bud growth, but not necessary for correlative inhibition imposed by growing axillary buds. Treatment of plants with Ametryn induced root bud growth on budless plants but not on plants with intact axillary buds. The polar auxin transport inhibitor N-1-naphthylphthalamic acid prevented transmission or the signal from growing axillary buds, but it had only a minor effect on the transmission of the leaf-derived signal. Treatment of plants with gibberellic acid (GA) induced growth of root buds under otherwise noninducing conditions to some extent in all plants. However, the greatest effects of GA were on plants with intact leaves (meristemless/budless and meristemless). GA had no significant effect on root bud quiescence under conditions that induced root bud growth.

Exotic weeds can interfere with neighboring species by releasing allelochemicals that either directly inhibit growth and distribution of associated species or affect them indirectly by disrupting their interaction with soil organisms, such as arbuscular mycorrhizal fungi (AMF). The allelopathic potential of tall hedge mustard was assessed using aqueous root and shoot extracts in seed germination and radicle growth bioassays. Aqueous tall hedge mustard root and shoot extracts strongly inhibited seed germination and growth of bluebunch wheatgrass, Idaho fescue, and spotted knapweed, but had minimal autotoxicity. Chemical analysis of tall hedge mustard tissues revealed the presence of two major glucosinolates—isopropyl and sec-butyl glucosinolate. The degradation products of these glucosinolates (isopropyl isothiocyanate and sec-butyl isothiocyanate) were identified in dichloromethane extracts of tall hedge mustard aqueous root and shoot extracts. Commercially available isopropyl isothiocyanate and sec-butyl isothiocyanate inhibited seed germination and radicle growth, suggesting their role in the allelopathic potential of tall hedge mustard. Tall hedge mustard aqueous extracts and isothiocyanates incorporated into an agar medium inhibited the spore germination of the AMF, Glomus intraradices. Tall hedge mustard infestations were also found to reduce the AMF inoculum potential of soil under field conditions. The results from this study show that tall hedge mustard produces chemicals that can inhibit the growth of neighboring plant species and their AMF associates.

Differences in the depth of weed seedling recruitment due to agronomic management practices, such as reduced tillage, have implications for weed competitive ability and management strategies. Depth of seedling recruitment of Avena fatua, Triticum aestivum, Setaria viridis, Polygonum convolvulus, and Echinochloa crus-galli was measured in situ in 1997 and 1998 prior to seeding (preseeding) and before in-crop spraying (prespray) in a total of 44 zero-tillage and 44 conventional-tillage fields located across approximately 3 million ha of southern Manitoba, Canada. For the monocot species, depth of recruitment was measured from the soil surface to the intact seed coats, which marked the point of germination. For P. convolvulus, a dicot, greenhouse studies were conducted prior to sampling in the field to identify a reliable morphological marker indicating the point of germination. For all species, mean recruitment depth was found to be significantly shallower in zero- vs. conventional-tillage fields and significantly shallower in the preseeding vs. the prespray period. There were relatively few differences in mean recruitment depth among weed species. Within a sampling period and tillage system, for example, the greatest difference in mean recruitment depth between species was less than 1.2 cm, and the maximum mean recruitment depth across species, sampling times, and tillage practice was very shallow (less than 4.2 cm). Locating weed seedling recruitment depth is the first step in characterizing weed seedling recruitment microsites. Results indicate this information should be specific to tillage and sampling time.

The biochemical basis of resistance to the acetyl-coenzyme A carboxylase (ACCase)-inhibiting herbicide diclofop-methyl was investigated in a resistant wild oat population (R1), which does not exhibit a resistant ACCase. Rates of foliar uptake and translocation of [14C]-diclofop were the same in the R1 vs. susceptible (S) populations. However, the level of phytotoxic diclofop acid was always found to be lower in the R1 vs. S plants, with a concomitant higher level (up to 1.7-fold) of nontoxic polar diclofop metabolites in R1 relative to the S plants. These results indicate that a non–target-site-based mechanism of enhanced rate of diclofop acid metabolism confers resistance in population R1. Moreover, the high-performance liquid chromotography elution profile of the major diclofop metabolites in R1 is similar to that of wheat, suggesting resistance in individuals of population R1 involves a wheat-like detoxification system mediated by cytochrome P450 monooxygenases. In addition, lower level of tissue diclofop acid was also observed using nonradioactive ultra-performance liquid chromatography–mass spectrometry analysis in resistant individuals of three other resistant wild oat populations (R2, R3, and R4) known to posses ACCase gene resistance mutations. These results establish that either one or at least two independent resistance mechanisms (target-site ACCase resistance mutations and non–target-site enhanced rates of herbicide metabolism) can be present in individual wild oat plants.