Direct numerical simulation is employed to study the effect of small-scale wall corrugations on scalar transfer through the wavy surface of a vertically falling liquid film in interaction with a strongly confined counter-current gas flow. Three wall geometries are considered: (i) a flat wall for reference; (ii) a sinusoidal corrugation typically found on structured packings in chemical engineering devices; and (iii) a heuristic design consisting of isolated semicircular bumps distanced by the wavelength of the surface waves. We consider the limiting case of a Dirichlet condition for the transported scalar (temperature or mass fraction) at the liquid–gas interface and focus on liquid-side transport. We consider convection-dominated regimes at moderate and large Péclet numbers, representative of heat and mass transfer respectively, and confront forced and noise-driven wave regimes. Our results show that sinusoidal wall corrugations increase transfer by up to 30 per cent in terms of the exchange length required to transfer a fixed amount of the transported quantity. A slightly greater intensification is achieved through the bump-shaped corrugations, which intermittently disrupt the moving-frame vortex forming within the large-amplitude solitary waves, allowing these to replenish with unsaturated liquid. However, when the velocity of the strongly confined gas flow is increased above a certain threshold, the bumps can trigger the flooding of the channel.