In the present paper, we have theoretically predicated some significant physical parameters, i.e., coordination number, constraints, density, molar volume, cohesive energy, heat of atomization, etc., for glassy Se80Te20 and glassy Se80Te10M10 (M = Cd, In, Sb) alloys. A theoretical study of the glassy Se80Te20 and glassy Se80Te10M10 (M = Cd, In, Sb) alloys reveals that there is a significant change in the structural environment of the system due to rigidity percolation.