While the best energy solutions may seem obvious to the LCA community, we often see wind turbines voted down for aesthetics and policy makers leaning toward solutions that show poor return, kilojoule per kilojoule. If we are to move forward with wise energy solutions, we will need to broaden our perspective to include the social impacts that influence policy-makers and communities, creating a decision-system that encompasses both social and environmental impacts.

Starting with LCA and Total Cost Assessment, a case study of a biodiesel facility in Vermont begins to incorporate social goals with reduced environmental impacts. We'll then look at other energy systems and how these decision-making tools might be used to bring policy makers, environmentalists, and communities together making wise energy choices for our future.

The NEEDS project of the European Commission (2004-2008) continues the ExternE series, aiming at improving and integrating external cost assessment, LCA, and energy-economy modeling, using multi-criteria decision analysis for technology roadmap up to year 2050. The LCA covers power systems suitable for Europe. The paper presents environmental inventories and cumulative results for selected representative evolutionary hard coal and lignite power technologies, namely the Ultra-Supercritical Pulverized Combustion (USC-PC) and Integrated Gasification Combined Cycle (IGCC) technologies. The power units are modeled with and without Carbon Capture and Storage (CCS). The three main technology paths for CO2 capture are represented, namely pre-combustion, post-combustion, and oxy-fuel combustion. Pipeline transport and storage in geological formations like saline aquifers and depleted gas reservoirs, which are the most likely solutions to be implemented in Europe, are modeled for assumed average conditions. The entire energy chains from fuel extraction through, when applicable, the ultimate sequestration of CO2, are assessed, using ecoinvent as background LCA database.

The results show that adding CCS to fossil power plants, although resulting in a large net decrease of the CO2 effluents to the atmosphere per unit of electricity, is likely to produce substantially more GHG than claimed by near-zero emission power plant promoters when the entire energy chain is accounted for, especially for post-combustion capture technologies and hard coal as a fuel. Besides, the lower net power plant efficiencies lead to higher consumption rate of non-renewable fossil fuel. Furthermore, consideration of the full spectrum of environmental burdens besides greenhouse gas (GHG) results in a less definite picture of the energy chain with CCS than obtained by just focusing on GHG reduction.

The authors have drafted three alternative scenarios for the technological improvement and market penetration of photovoltaics in the next four decades, based on the preliminary results of the EU FP6 Integrated Project NEEDS, Research Stream 1a. The long-term diffusion of PV is foreseen to depend on the achievable module efficiencies and on the maturity of the different technologies in terms of their manufacturing costs, energy pay-back times, additional BOS costs, and even raw material reserves. Last but not least, the co-evolution of a suitable energy storage network (e.g. hydrogen) is also foreseen to be a mandatory requirement. Cumulative installed capacity worldwide is projected to reach 9,000 GWp in 2050 in the most optimistic scenario, which is reduced to 2,400 GWp in the intermediate scenario. In the third “pessimistic” scenario the current economic incentives are not assumed to be sustained long enough to allow PV to become competitive with bulk electricity, resulting in a stunted market growth (500 GWp in 2050). The resulting predictions in terms of costs range from 0.50 to 1.50 €/Wp in 2050, respectively corresponding to 2 - 8 €-cents per kWh in Southern Europe and 4 - 14 €-cents per kWh in Northern Europe. Within the framework of these three general scenarios, special attention is then put to the role that is likely to be played by thin film technologies, namely amorphous Si, CdTe and CIS/CIGS. These technologies are expected to collectively reach a market share of approximately 45% by as early as 2025 in all but the most pessimistic scenario, wherein the same goal is put off until 2050. Marked increases in module efficiencies and material and energy consumption are also expected, to varying degrees depending on the assumptions made in the three scenarios.

Experimental wet chemical approaches have been demonstrated in the synthesis of a new chainlike (C60-Fe-C60-Fe)n complex. This structure has been proposed based on 13C solid-state nuclear magnetic resonance, electron paramagnetic resonance, high-resolution transmission electron microscopy, energy-dispersive spectroscopy, and X-ray diffraction. Furthermore, this structure has been shown to have unique binding sites for dihydrogen molecules with the technique of temperature-programmed desorption. The new adsorption sites have binding energies that are stronger than that observed for hydrogen physisorbed on planar graphite, but significantly weaker than a chemical C-H bond. Volumetric measurements at 77 K and 2 bar show a hydrogen adsorption capacity of 0.5 wt%. Interestingly, the BET surface area is ∼31 m2/g after degassing, which is approximately an order of magnitude less than expected given the measured experimental hydrogen capacity. Nitrogen and hydrogen isotherms performed at 75 K also show a marked selectivity for hydrogen over nitrogen for this complex, indicating hidden surface area for hydrogen adsorption.

The consolidation and casting processes of fine silicon powders, by-product of high purity silicon rods making process in the current method, were systematically investigated for use as economical solar-grade feedstock. Morphology, size, and contamination type of the fine silicon powders were inspected by combined analysis of SEM, particle size analyzer, and FT-IR. Silicon powder compacts were tried to fabricate by a consolidation process without a binding agent and then their density ratio and strength were evaluated. Finally, the electrical resistivity of the specimens prepared by an electromagnetic casting method was examined for purity assessment.

Recently, the data for photovoltaics in the ecoinvent database have been updated on behalf of the European Photovoltaics Industry Association and the Swiss Federal Authority for Energy. Data have been collected in this project directly from manufacturers and were provided by other research projects. LCA studies from different authors are considered for the assessment. The information is used to elaborate a life cycle inventory from cradle to grave for the PV electricity production in 3kWp plants in the year 2005.

The inventories cover mono- and polycrystalline cells, amorphous and ribbon-silicon, CdTe and CIS thin film cells. Environmental impacts due to the infrastructure for all production stages and the effluents from wafer production are also considered. The ecoinvent database is used as background database.

Results from the LCA study are presented, comparing different types of cells and analysing also the electricity production in a range of different countries. It is also discussed how the environmental impacts of photovoltaics have been reduced over the last 15 years, using the CED indicator. The consistent and coherent LCI datasets for basic processes make it easier to perform LCA studies, and increase the credibility and acceptance of the life cycle results. The content of the PV LCI datasets is made publicly available via the website www.ecoinvent.org for ecoinvent members.

High electrochemical capacity of alkaline boride anodes is presented. The alkaline anodes based on transition metal borides can deliver exceptionally high discharge capacity. Over 3800 mAh/g discharge capacity is obtained for the commercial available vanadium diboride (VB2), much higher than the theoretical capacity of commonly used zinc metal (820 mAh/g) alkaline anode. Coupling with the super-iron cathodes, the novel Fe6+/B2- battery chemistry generates a matched electrochemical potential to the pervasive, conventional MnO2-Zn battery, but sustains a much higher electrochemical capacity.

Adsorption of hydrogen and the occupancy of different binding sites as a function of hydrogen loading in MOF-74 are studied using inelastic neutron scattering (INS). Hydrogen molecules are observed to fully occupy the strongest binding site before populating other adsorption sites. The comparison of the INS spectra at 4 K and 60 K indicates that hydrogen adsorbed at the strongest binding site is strongly bound and localized. We also show that when two hydrogen molecules are adsorbed into a single, attractive potential well, the shortest inter-H2 distance is about 3 Å, consistent with our previous observation of inter-H2 distance when adsorbed in two neighboring potential wells.

Since the publication of the 2003 report on Basic Energy Needs for the Hydrogen Economy, many important advances in hydrogen research have occurred, a cadre of enthusiastic researchers has entered the field with great interest shown by students, and private industry has made significant commitment to this technology and investment in its development worldwide. Concurrently, other energy technologies have made major strides forward. These technologies must be evaluated for their scalability, usability, cost and life cycle footprint on the environment. This overview discusses these topics and looks toward the role for the hydrogen economy into our energy future.

We give an overview of historical developments with respect to the price and the Energy Pay-Back Time of crystalline silicon photovoltaic modules. We investigate the drivers behind both developments and observe that there is a large overlap between them. Reduction of silicon consumption, improved cell efficiency and the production technology for solar grade silicon have been identified as major drivers for both cost and impact reductions in the past. Also we look into future prospects for reduction of environmental impacts. It is estimated that developments underway to reduce costs will also result in a reduction of the Energy Pay-Back Time of a PV installation (in South-Europe) from 1.5-2.0 year presently to well below 1 year.

Life cycle analysis becomes especially important for characterizing new material forms in new energy generation technologies intended to replace or improve the current infrastructure of energy production. We propose a comparative life-cycle analysis framework for investigating the effect of introducing nanotechnology in the life cycle of new photovoltaics, which focuses on the differences between the new technologies and the ones that they may replace. The following parameters are investigated within this framework: methods of synthesizing nanoparticles, physicochemical specifications of the precursors, material utilization rates, deposition rates, energy-conversion efficiencies, and lifetime expectancy of the final product. We introduce the application of this framework in comparing nano-structured cadmium telluride and silicon films with their nano- and amorphous- structured equivalents.

The emergence of a Hydrogen Economy will require the development of new media capable of safely storing hydrogen with high gravimetric and volumetric densities. Metal hydrides and complex metal hydrides, where hydrogen is chemically bonded to the metal atoms in the bulk, offer some hope of overcoming the challenges associated with hydrogen storage. Many of the more promising hydrogen materials are tailored to meet the unique demands of a low temperature automotive fuel cell and are therefore either entirely new (e.g. in structural or chemical composition) or in some new form (e.g. morphology, crystallite size, catalysts). This proceeding presents an overview of some of the challenges associated with metal hydride hydrogen storage and a few new approaches being investigated to address these challenges.

The mechanical effect on the oxygen ion mobility in zirconia stabilized with 8 mol% yttria was investigated in this study. A dynamic mechanical thermal analysis showed that the dynamic modulus decreased gradually with temperature while the mechanical loss had two peaks due to different relaxation mechanisms. From the comparison of activation energies between the ionic conductivity and the mechanical relaxation, the dominant factor for oxygen mobility was determined to be the migration of oxygen vacancies in the simple complexes. An impedance analysis under mechanical tensile-loading conditions showed that the mechanical load increased ionic conductivity by 6% at maximum.

We investigate the area of land used and/or transformed during conventional (i.e., coal, natural gas and nuclear), and renewable fuel cycles (i.e., photovoltaics, wind, biomass, and geothermal). Both direct and indirect land use/transformation are examined in a life cycle framework. For average US insolation, the photovoltaic fuel cycle disturbs the least amount of land per GWh among renewable options, requiring less area than the coal fuel cycle. Renewable technologies could harvest infinite amount of energy per unit area and eliminates the need for restoring disturbed mine lands. Further investigations would be necessary for secondary and accidental land disturbance by conventional fuel cycles through transport of effluents and emissions to adjacent land.

In this work infrared thermography was used as a diagnostic tool for the performance assessment of a photovoltaic array integrated on the southern façade of NTUA's Chemical Engineering Building. This grid-connected 50 kWp solar photovoltaic array, installed under an EC Thermie Project (SE-142-97-GR-ES), operates in a standard and hybrid PV-Thermal configuration, meant to save conventional energy. The thermographic system used for the analysis covers the 8-12 ìm of wavelength region. The thermal images obtained showed that there are temperature differences on the PV panels, which may be attributed to PV material defects, manufacturing faults, external abuse, or PV malfunction.

Ambient air is used as an oxygen source in SOFCs to be commercialized. Various chemical species which can lead to poisoning of SOFC cathodes are included as minor constitutions in air, such as water vapor, SOx, NOx and NaCl etc. However, their effects on the cathode performance have not yet well known, even though they are expected to cause a degradation of the electrode performance and to reduce the long-term durability of SOFCs. Therefore, in this study, we focused on the poisoning caused by water vapor and SOx in the oxygen source to clarify their effects on SOFCs performances and to reveal the degradation mechanism of cathodes. SOFCs with typical electrolyte-supported structure were used in this work, which were composed with ScSZ (10 mol% Sc2O3, 1mol% CeO2, 89 mol% ZrO2) plate with the thickness of 200 µm as electrolyte, NiO-ScSZ (mixture of 56 wt% NiO and 44 wt% ScSZ) porous layer as anode, and two cathode layers of LSM ((La0.8Sr0.2)0.98MnO3) and LSM-ScSZ (mixture of 50 wt% LSM and 50 wt% ScSZ). Power generation characteristics of the cells had been analyzed by measuring cell voltage at a constant current density (200 mA/cm2) and by comparing changes in cell impedance, upon supplying the artificially-contaminated air with water vapor or SOx, to the SOFC cathodes at various operational temperatures. High-resolution FESEM (S-5200, Hitachi) was used to analyze microstructural changes caused by the impurities. Mg Kα radiation from a monochromatized X-ray source was used for XPS measurements (ESCA-3400, KRATOS). AC impedance was measured at various temperatures under the open circuit voltage condition by an impedance analyzer (Solatron 1255B/SI 1287, Solatron), in a frequency range from 0.1 to 105 Hz with an amplitude of 10 mV.

It is well known that the transport sector causes significant environmental impacts worldwide and as a consequence influences the results of Life Cycle Assessment (LCA) studies. Today's fuels are dominated by crude oil derived fuels. In Europe currently 98 % of the road transportation is based on such crude oil derived fuels. Similar ratios can be observed e.g. in the US and other countries. In addition to the environmental impacts, the high dependency on the imports of fossil fuels motivates most European countries to investigate in other than fossil fuel based transport systems. Therefore the European Commission presented an action plan including a strategy with the objective to substitute 20% of crude oil derived fuels by alternative fuel until 2020. To achieve these goals, actions to reduce the import dependency of fuels, the usage of non renewable (fossil) resources and the environmental burdens connected to the use of fuel / propulsion systems have to be addressed. Besides, the energy carrier mix has to be broadened. Especially alternative fuels from renewable resources, BtL (Biomass to Liquid) are supposed to have a high potential.

Recent developments show, that there is a variety of options for fuels available as well as for propulsion technologies that utilize fuels based on renewable resources. It is therefore of key importance to select and promote the fuel/ propulsion system technology which is most beneficiary for a country or region from an environmental but also from an economic and social perspective. For such a sustainability evaluation it is essential to consider the local/regional boundary conditions such as availability of fuel resources, major pollution issues which need to be addressed, supply of secondary energy (e.g. power) etc. LCA is therefore a suitable approach to evaluate and compare different options, due to its transparent consideration of all life cycle stages.

Besides the environmental impacts and resource consumption which are addressed in LCA considerations the needed land is another important aspect when talking about biomass as a resource. As land is a scarce resource that is used for all industry sectors there is a need to address this issue also in LCA. Up to now, no commonly agreed upon methods exist which allow the integration of land use aspects in a consistent way into LCA Software and Database. Currently at LBP-GaBi, University of Stuttgart together with PE International, a method is developed to integrate land use aspects into LCA. Backward processes are now implemented in an applicable way into a LCA database system.

This Paper describes the main approach of the developed methodology for land use consideration within LCA.

The point of view taken here is that systems analysis is a kind of learning process, not data gathering, not decision making, but the production and effective communication of arguments relevant in a particular context. This idea, that the intended application of the result of an assessment has consequences for methodological choices, is beginning to spread in the LCA research community. One problem is that standard LCA methodology is developed to answer questions about environmental impacts of the current production and use of one unit of a product or minor product or process changes. When this methodology, unchanged, is used to provide answers to questions about strategic technology choice, i.e. not decisions that aim at improving a process within an existing technological environment, but with the long-term goal of changing large-scale technological systems, the result could be of little value or misleading. In many cases, LCAs produce more noise than knowledge. This observation seems to be of particular importance for LCAs of energy technologies and for how energy use is treated in all kinds of LCAs. Here, it is suggested that a better understanding of some critical methodological issues related to time, universality, cause-effect relationships, technical maturity and system innovation, could result in better studies that reveal fundamental environmental issues related to the objects of study and reduce the noise from irrelevant information. Examples are given from the technology fields of solar cells, fuel cells, batteries, renewable transport fuels and carbon nanoparticles.

With its ultra-large specific surface area, a nanoporous material is an ideal, yet relatively unexplored, platform for accepting or actuating liquids, with potential performance gains for energy dissipation and output typical of disruptive technologies. Our experimental and theoretical results indicate either dramatically improved performance or unique combinations of properties and capabilities not attainable in conventional materials, which make the novel nanoporous structures studied herein very attractive as advanced protective intelligent systems.

An overview is given of the development of advanced nanoporous carbons as storage ma-terials for natural gas (methane) and molecular hydrogen in on-board fuel tanks for next-generation clean automobiles. The carbons are produced in a multi-step process from corncob, have surface areas of up to 3500 m2/g, porosities of up to 0.8, and reversibly store, by physisorp-tion, record amounts of methane and hydrogen. Current best gravimetric and volumetric storage capacities are: 250 g CH4/kg carbon and 130 g CH4/liter carbon (199 V/V) at 35 bar and 293 K; and 80 g H2/kg carbon and 47 g H2/liter carbon at 47 bar and 77 K. This is the first time the DOE methane storage target of 180 V/V at 35 bar and ambient temperature has been reached and exceeded. The hydrogen values compare favorably with the 2010 DOE gravimetric and volu-metric targets for hydrogen. A prototype adsorbed natural gas (ANG) tank, loaded with carbon monoliths produced accordingly and currently undergoing a road test in Kansas City, is de-scribed. A preliminary analysis of the surface and pore structure is given that may shed light on the mechanisms leading to the extraordinary storage capacities of these materials. The analysis includes pore-size distributions from nitrogen adsorption isotherms; spatial organization of pores across the entire solid from small-angle x-ray scattering (SAXS); pore entrances from scanning electron microscopy (SEM) and transmission electron microscopy (TEM); H2 binding energies from temperature-programmed desorption (TPD); and analysis of surface defects from Raman spectra. For future materials, expected to have higher H2 binding energies via appropriate sur-face functionalization, preliminary projections of H2 storage capacities based on molecular dy-namics simulations of adsorption of H2 on graphite, are reported.