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Metal Hydrides for Hydrogen Storage

Published online by Cambridge University Press:  01 February 2011

Jason Graetz
Affiliation:
[email protected], Brookhaven National Laboratory, Energy Sciences and Technology, 815 Rutherford Dr., Upton, NY, 11973, United States, 631-344-3242
James J Reilly
Affiliation:
[email protected], Brookhaven National Laboratory, Energy Sciences and Technology, Upton, NY, 11973, United States
James Wegrzyn
Affiliation:
[email protected], Brookhaven National Laboratory, Energy Sciences and Technology, Upton, NY, 11973, United States
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Abstract

The emergence of a Hydrogen Economy will require the development of new media capable of safely storing hydrogen with high gravimetric and volumetric densities. Metal hydrides and complex metal hydrides, where hydrogen is chemically bonded to the metal atoms in the bulk, offer some hope of overcoming the challenges associated with hydrogen storage. Many of the more promising hydrogen materials are tailored to meet the unique demands of a low temperature automotive fuel cell and are therefore either entirely new (e.g. in structural or chemical composition) or in some new form (e.g. morphology, crystallite size, catalysts). This proceeding presents an overview of some of the challenges associated with metal hydride hydrogen storage and a few new approaches being investigated to address these challenges.

Type
Research Article
Copyright
Copyright © Materials Research Society 2008

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References

1. Sandrock, G., J. Alloys Compd. 293–295, 877 (1999).10.1016/S0925-8388(99)00384-9Google Scholar
2. Bogdanovic, B. and Schwickardi, M.. J. Alloys Compd. 253–254, 1 (1997).Google Scholar
3. Srinivasan, S. S., Brinks, H.W., Hauback, B.C., Sun, D. and Jensen, C.M., J. Alloys Compd. 377, 283 (2004).Google Scholar
4. Luo, W. and Sickafoose, S., J. Alloys Compd. 407, 274 (2006).10.1016/j.jallcom.2005.06.046Google Scholar
5. Wang, J., DOE Metal Hydride Center of Excellence Kick-Off Meeting, Livermore, CA, 2005.Google Scholar
6. Mosher, D., DOE Hydrogen Program: 2006 Annual Progress Report – Storage, p, 281, http://www.hydrogen.energy.gov/annual_progress06_storage.html.Google Scholar
7. Vajo, J. J., Mertens, F., Ahn, C. C., Bowman, R. C. Jr and Fultz, B., J. Phys. Chem. B 108, 13977 (2004).Google Scholar
8. Vajo, J. J., Olson, G. L., Scripta Materialia 56, 829 (2007).Google Scholar
9. Graetz, J., Lee, Y., Reilly, J. J., Park, S. and Vogt, T., Phys. Rev. B 71, 184115 (2005).10.1103/PhysRevB.71.184115Google Scholar
10. Ronnebro, E. and Majzoub, E. H., J. Phys. Chem. B 110, 25686 (2006).Google Scholar
11. Sandrock, G., Reilly, J., Graetz, J., Zhou, W.-M., Johnson, J. and Wegrzyn, J., Appl. Phys. A 80, 687 (2005).Google Scholar
12. Graetz, J. and Reilly, J. J., J. Alloys Comp. 424, 262 (2006).10.1016/j.jallcom.2005.11.086Google Scholar
13. Konovalov, A. K. and Bulychev, B. M., Inorg. Chem. 34, 172 (1995).Google Scholar
14. Graetz, J., Chaudhuri, S., Lee, Y., Vogt, T. and Reilly, J.J., Phys. Rev. B 74, 214114 (2006).Google Scholar
15. Graetz, J. and Reilly, J.J., Kulleck, J.G. and Bowman, R. C. Jr, J. Alloys Comp. 446–447, 271 (2007).Google Scholar
16.DOE Hydrogen, Fuel Cells & Infrastructure Technologies Program Multi-Year Research, Development, and Demonstration Plan, Hydrogen Storage Technical Plan, 2007 http://www1.eere.energy.gov/hydrogenandfuelcells/mypp/Google Scholar
17. Graetz, J. and Reilly, J. J., J. Phys. Chem. B 109, 22181 (2005).10.1021/jp0546960Google Scholar
18. Brower, F.M., Matzek, N.E., Reigler, P.F., Rinn, H.W., Roberts, C.B., Schmidt, D.L., Snover, J.A., Terada, K., J. Am. Chem. Soc. 98, 2450 (1976).10.1021/ja00425a011Google Scholar
19. Graetz, J., Chaudhari, S., Wegrzyn, J., Celebi, Y., Johnson, J.R., Zhou, W., Reilly, J.J., J. Phys. Chem. C 111 19148 (2007).Google Scholar