Regolith-hosted rare earth element (REE) deposits hosted by the granitic regolith in South China provide >90% of the world’s heavy REEs. Kaolinite is one of the major carriers of REE ions in regolith. The formation and transformation of kaolinite can be affected by chemical weathering and hydrodynamic conditions, but the contribution of each factor has not been evaluated. This study systematically investigated the variation in abundance of phyllosilicate minerals and structural order of kaolinite in the Renju regolith-hosted REE deposit. The total abundance of 1:1 phyllosilicate minerals increased upwards along the profile from Section I to Section III. However, semi-quantitative analyses indicated that Section III-1 (depth at 10–16 m) featured an evident decrease in both abundance and structural order of kaolinite upward along the profile. The morphological feature and abundance of kaolinite revealed intensive kaolinite-to-halloysite transformation and kaolinite dissolution in Section III-1. This suggests that the alternating wetting and drying zone in Section III-1 provided a favorable kinetic environment for the entry of water molecules into the kaolinite interlayer and the kaolinite-to-halloysite transformation, resulting in both lower structural order and abundance of kaolinite in Section III-1. Moreover, REE ions started to be enriched from the alternating wetting and drying zone and formed high-grade ores at the lower part of the water table, due to a significant increase in pore water and decrease in the seepage velocity. Therefore, the abundance and structural order of secondary kaolinite can serve as important indicators of hydrodynamic changes in regolith, as well as the mineralization of regolith-hosted REEs.

The alteration of bentonite under alkaline conditions and the subsequent changes in properties such as permeability and self-sealing ability should be evaluated for the performance assessment of radioactive waste repositories. As the period of evaluation for alterations is extremely long, natural analog (NA) studies that can observe long-term phenomena similar to the system of radioactive waste repositories have significant advantages. However, locations that can be set up as NA study sites with significant similarity are limited and should be pursued by localizing analog systems. This literature review summarized studies reporting secondary phases formed at low temperatures (<100°C) under a broader range of natural sites which are chemically similar to the alkaline conditions expected at bentonite in radioactive waste repositories, including near pyrometamorphic rocks, near ophiolites, and in alkaline saline lakes. This review provides insights into the species, formation conditions, and stability of secondary phases that could be formed during cement–bentonite interactions and the timescale for mineralogical transitions from a metastable to a stable phase. The findings could be useful for selecting secondary phases to be considered in reactive transport modeling for predicting cement–bentonite interactions in radioactive waste repositories.

Precise information on the location of charge in clay minerals and their charge density in smectite-dominant soils is rare. The present study was undertaken with three benchmark Vertisols to establish the relationship between the clay cation exchange capacity (CEC), charge density, as well as the location of charge in smectitic soil clay minerals and their relationship with potassium (K) fixation and release. Potassium fractions and their threshold levels in the Vertisols were determined by standard methods. Soils were segregated into silt, total clay and fine clay fractions for X-ray diffraction analysis and fine clay fractions were used to determine the CEC using standard methods. The Hofmann-Klemen effect (HK) and modified Greene-Kelly test was done with the fine clay to determine the CEC of the tetrahedral sheet. Subsequently, the CEC of the octahedral sheet was calculated as the difference between total CEC and the tetrahedral CEC. The results showed that ~60–64% of the total CEC is attributed to the tetrahedral layers. The tetrahedral CEC that is proportional to the tetrahedral charge density was significant and negatively correlated with K release threshold values and all fractions of K. The tetrahedral CEC contributed more toward the K fixation and release than the octahedral CEC. The study shows that the dominant presence of high-charge smectites in the fine clay fractions of these Vertisols contributed to the tetrahedral CEC and consequently to the charge density of these soils, which implied a tendency to fix K easily and release it with greater difficulty compared to soils with low-charge smectites.

To develop more economical and efficient heavy metal adsorbents, natural bentonite was employed as a raw material, and triethoxyvinylsilane served as a grafting agent to achieve the grafting bonding of sodium polyacrylate and bentonite. Structural alterations in the modified bentonite were analyzed through thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and X-ray diffraction (XRD). The adsorption and desorption characteristics of SAPAS-Bentonite and raw bentonite were compared and tested under various conditions, including time, temperature, pH, and lead ion concentration. The adsorption and desorption properties of sodium polyacrylate-grafted bentonite (SAPAS-Bentonite) were compared under various conditions (time, temperature, pH, and lead ion concentration). The results revealed that the modified method successfully achieved nano-scale coating of bentonite particles with sodium polyacrylate, leading to an increase in the maximum adsorption capacity of lead ions by 47.5%, reaching 165.73 mg g. A greater adsorption affinity for lead ions was exhibited by the outer sodium polycarboxylate portion of SAPAS-Bentonite compared with the inner bentonite. The adsorption of internal bentonite was limited by blocking when the adsorption of sodium polyacrylate did not reach the upper limit. The adsorption isotherm shifted from the Langmuir monolayer characteristic of the original bentonite to the S-shaped isotherm, reflecting the sodium polycarboxylate properties of SAPAS-Bentonite. Both bentonites demonstrated strong retention capacity for lead, with SAPAS-Bentonite surpassing raw bentonite in performance. This study provides valuable insights into the potential of SAPAS-Bentonite in the treatment of heavy metal pollution.

The sustainability of high-level radioactive waste repositories situated in fractured crystalline rocks depends on the stability of bentonite liners, and this can pose a problem in certain groundwater conditions that favor the formation of colloids from backfill materials that are prone to erosion. The influence of different environments on the structure of Gaomiaozi bentonite (GMZ) and GMZ colloids (GMZC) is presented here. Different hydrated interlayer structures of bulk and colloidal forms of this bentonite from small-angle X-ray scattering (SAXS) data are demonstrated. Analysis of the scattering data showed that GMZ had three interlayer water structures: dehydrated (0W), monohydrated (1W), and bi-hydrated (2W). The colloids readily agglomerated at acidic pH (pH <5) but showed resistance to agglomeration in an alkaline condition (pH >7). The effect of Na+, K+, Mg2+, and Ca2+ on the lamellar structure and agglomerate morphology of GMZC particles was investigated. In general, the tendency of colloids to agglomerate was greater in the presence of divalent metal cations compared with monovalent metal cations. High concentrations (10–5 to 10–3 mol L–1) of divalent ions imparted order into the stacked lamellar structure after the saturation of the interlayer. In contrast, monovalent ions reduced the tendency of the particles to aggregate, leading to an abundance of colloidal nanoparticles prone to erosion. This work helps to better understand the structural characteristics of GMZC in the groundwater environment, and provides a valuable reference for the evaluation of nuclide migration in the deep geological disposal of high-level radioactive wastes.

Clay exhibits the capability to adsorb dyes such as Rhodamine B (RhB); practical application reveals its susceptibility to desorption, however, compromising its efficacy for RhB removal. To address this concern, modification of Natural Boyolali Region Clay (NBR Clay) was conducted by introducing TiO2 pillars and incorporating Co and Ni as dopants. This modification aimed to augment the clay’s photodegradation capability and its RhB removal capacity. The principal objective of this study was to assess the characteristics of TiO2-pillared clay doped with Co and Ni and to evaluate its effectiveness in RhB removal. The prepared samples were analyzed using Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis with differential scanning calorimetry (TGA-DSC), and gas sorption analysis (GSA). TGA results indicated stability for all samples up to 650°C, except for Co-Ti/NBR Clay. After 2.5 min, the adsorption capacity of both NBR Clay and NBR Clay+ethanol (EtOH) significantly surpassed that of Ti/NBR Clay, Ni-Ti/NBR Clay, and Co-Ti/NBR Clay. However, the adsorption energy of Ti/NBR Clay, Ni-Ti/NBR Clay, and Co-Ti/NBR Clay exceeded that of NBR Clay and NBR Clay+EtOH. Furthermore, all samples adhered to the Langmuir isotherm model, indicative of a physisorption mechanism. Notably, after 80 min, the percentage of photocatalytic degradation for plain clay reached 99.61%, and this value increased with the introduction of TiO2 and doping. The Co-Ti/NBR Clay sample exhibited the highest degradation rate at 99.97%. These findings underscore the favorable influence of TiO2 addition and doping on enhancing RhB removal efficiency.

Leaching and volatilization of N from urea, and precipitation and fixing of Zn by commercial fertilizers, has led to excessive costs for farmers and problems for the environment. Incorporating fertilizers in a porous material such as diatomite can prevent these losses by slowing the nutrient release. A new fertilizer formulation, based on the urea-zinc (UZn) complex in the eutectic solution of salt-urea was prepared. In the following, UZn was incorporated into diatomite and nano-diatomite by using hydroxypropyl methylcellulose (HPMC) as a binder. The treatments included the following: U: urea; UZn: urea-Zn; UZn-D: urea-Zn-diatomite; UZn-ND: urea-Zn-nano-diatomite; UZn-D-B: urea-Zn-diatomite-binder; and UZn-ND-B: urea-Zn-nano-diatomite-binder. The slow-release urea fertilizers (SRUFs) were characterized using FESEM/EDS, FTIR, CHN, XRD, DLS, and zeta potential techniques. Urea slow-release behavior, kinetics in water, and available Zn and N-forms leaching in the soil column were evaluated compared with conventional urea and zinc fertilizers. The pattern of release of urea in water was sigmoidal and after 12 h, only 20% of urea was released from fertilizers containing diatomite and HPMC. The NO3– release pattern in the soil started with a 12-day delay, and after that, the rate of NO3– leaching decreased by two to three times in the application of fertilizers containing HPMC compared with urea. The Zn concentration in the leachates of columns supplied with SRUFs was 35% less than for those supplied with ZnSO4. The results showed that the SRUFs make N and Zn available in the soil and but reduce the rate of their release.

In order to gain a better understanding of clay and Fe (oxyhydr)oxide minerals formed during pedogenesis of basalts in tropical monsoonal Hainan (southern China), a basalt-derived lateritic soil at Nanyang, Hainan, was investigated comprehensively. The results show that the lateritic regolith consists uniformly of kaolinite and Fe (oxyhydr)oxide minerals, with trace gibbsite only in the AE horizon. Abundant dioctahedral smectite in the basalt bedrock formed due to primary hydrothermal alteration, and transformed to kaolinite rapidly in the highly weathering saprolite horizon. The ‘crystallinity’ of kaolinite is notably low and its Hinckley index fluctuates along the soil profile, resulting from intense ferrolysis due to fluctuations between wet/dry climate conditions. From the base to the top of the profile, maghemite shows a decreasing trend, whereas magnetite, hematite, and goethite exhibit a slightly increasing trend, indicating that maghemite formed as an initial product of basalt weathering. Formation of Fe (oxyhydr)oxide species in basalt-derived soil is mainly controlled by local environmental conditions such as soil moisture, redox, and acidic conditions; thus, iron mineral-based paleoclimatic proxies could not be used for subtropical to tropical soils. The highly weathered saprolite has a similar δ56Fe value (+0.06‰) to that (+0.07‰) of the parent rock, while the AE to middle E horizons have greater δ56Fe values of +0.12‰ to +0.19‰. Fe isotopic signatures correlate positively with the Fe mass transfer coefficient (R2=0.77, n=6, ρ<0.05), indicating repetitive weathering and relative accumulation of isotopically heavier Fe in the upper soil horizons, which occurred by reductive dissolution of organic matter under oxic conditions, as reflected by the greater U/Th.

One potential solution to the rising threat of antibacterial drug resistance is the application of therapeutic clays to treat wound infections. Clays with antibacterial activity have been identified from a range of sources with their antibacterial properties often attributed to the release of toxic metal ions such as Fe(II) and Al(III). Here, clays from Afghanistan, Azerbaijan and Bangladesh that are utilized for washing and healing purposes were examined. Their antibacterial activities were assessed in suspension and as aqueous leachates against representative Gram-negative, Escherichia coli, and Gram-positive, Bacillus subtilis, bacteria. The majority of the clays conferred no deleterious effect and, in fact, tended to promote bacterial growth, likely as a result of released organic and inorganic nutrients. However, one of the clays, obtained from the Dhaka region of Bangladesh, displayed significant bactericidal activity against E. coli and B. subtilis as a clay suspension but not as an aqueous leachate. Further experiments confirmed that contact between clay and the bacteria was necessary for most of the antibacterial effects. Detailed analysis of bulk and <2 μm clay fraction mineralogy and geochemistry revealed no single defining parameter or mineral component that could be used to easily distinguish natural clays with antibacterial properties from those without. Overall, the results suggest a mechanism of antibacterial action of the Dhaka clay that arises from acidic conditions, likely enabled by the absence of calcite in the bulk clay, metal release, the presence of interstratified chlorite-smectite, and direct clay–bacteria interactions.

Because of the interfacial interactions between mineral soil particles and soil organic matter (SOM), SOM occurs in various forms in the soil, and the mineral-associated and particulate forms are fundamental. Many recent studies have concentrated on the effects of SOM content and type on the geotechnical behavior of soil. However, the influence of SOM occurrence forms is not well understood, nor is there a scientific classification standard for SOM in geotechnical engineering. The main objectives of this study were to explore the effects of SOM occurrence forms on a few physical properties of clays to develop an engineering classification standard of SOM. First, this paper reviews the interfacial interaction mechanism, factors that influence the relation between mineral soil particles and SOM, and the classification method of SOM in soil science. Three predominant clays (montmorillonite, illite, and kaolinite) were then used as the matrix, and three groups of artificial soil samples with different SOM contents (wu ranging from 0 to 50% by weight) were prepared by adding peat. A chemical extraction method was used to determine the amount of different forms of SOM. Moreover, the Atterberg limits wL (wp) and thermal conductivity λ of artificial soil samples were tested. Based on the experimental results, the relationship between the form of SOM and these physical parameters was established. The experimental results show that the wL (wp) vs wu, and λ vs wu fitted curves were not monotonic but piecewise linear and could be divided into two straight lines with different slopes; wu corresponded to the inflection point of wL (wp) vs wu, and λ vs wu curves were closer to the threshold value wu,2. Finally, a simple engineering classification method of SOM is proposed.

Most clay minerals are characterized by a platy morphology. By contrast, palygorskite has a fibrous morphology and is structurally distinct from the typical 1:1 and 2:1 layer structures. Diverse opinions exist on the origin of palygorskite in soils. Many authors suggest that palygorskite forms after smectite. Others favor its authigenesis during pedogenic processes or its inheritance from the parent material. This review provides a critical synthesis on the origin of palygorskite in the semi-arid-tropical (SAT) Vertisols and arid calcic soils of the Thar Desert of India. It also highlights the specific genetic pathway for the presence of palygorskite in the soils. The ubiquitous association of smectite with palygorskite is inadequate to explain the formation at the expense of smectite, because at pH 8.2 and above the smectite structure is subjected to dissolution to create soluble Si and Al, and the recrystallization of the soluble Si and Al to form palygorskite may not be possible in the Vertisols of the Indian SAT environment. Thus, mildly to moderate alkaline pedochemcial environments of the SAT Vertisols do not favor authigenic precipitation of the palygorskite in such soils. This review shows that the presence of palygorskite in the SAT Vertisols is due to its inheritance from the exhumed inter-trappean beds, infra-trappean beds, and bole beds. This view on the genesis of the palygorskite is also justified by its presence in weakly developed calcic soils of the Thar Desert as detrital flux from the adjoining marine sedimentary rocks.

The development of active and low-cost transition metal oxide-based catalysts was vital for the catalytic oxidation of toluene. This study aimed to prepare Fe-Mn oxide catalysts by Mn-rich limonite, and investigate the catalytic activity and mechanism for toluene oxidation. The natural Mn-rich limonite was thermally activated at different temperatures and these thermally activated samples exhibited different oxidation activities. YL-300, obtained through thermal treatment at 300°C, exhibited excellent catalytic activity, showing 90% toluene conversion at 239°C (1000 ppm toluene) and remarkable catalytic stability even in the presence of water vapor (5 vol.%). The amount of oxygen vacancies in the catalyst was regulated by tuning the thermal treatment temperatures. Optimal thermal treatment facilitated the increase of oxygen vacancies and enhanced the oxygen mobility and redox capacity of YL-300, contributing to the complete oxidation of toluene to H2O and CO2. The oxidation of toluene was greatly influenced by the adsorbed oxygen species. This study demonstrates the potential of Mn-rich limonite as a promising catalyst for toluene oxidation, thereby promoting the utilization of natural mineral materials in the field of environmental pollution control.

The role of micro- and mesopores of archaeological ceramics in preserving ancient biomolecules is not well established. To understand the formation of these nano-sized pores in ceramics, reference pottery briquettes were made using two different clay types (illitic and kaolinitic clays), two different tempers (sand and chalk), and two different firing temperatures (600 and 800°C). The mineral content of the briquettes was determined by quantitative X-ray diffraction, and the micro- and mesopores were characterized with the N2 adsorption method. The Brunauer–Emmett–Teller method, the adsorbed volume near liquefaction, and application of non-local density functional theory (NLDFT) were used on the N2 adsorption data to determine specific surface areas, specific pore volumes, and pore-size distributions. Values of the micro- and mesoporosity parameters of most of the briquettes were approximately proportional to the initial clay content and unrelated to temper; the proportionality factors were much larger for illitic clay than for kaolinitic clay. When chalk-tempered briquettes were fired at the higher firing temperature of 800°C, the parameters were no longer proportional to the initial clay content; they decreased in most briquettes formed of illitic clay due to reaction of the clay with lime, and they increased in briquettes formed of kaolinitic clay due mostly to the porosity of unreacted lime. Micropore volumes in briquettes formed mostly of illitic clay were substantial: of the order of 5 mm3 g−1. The work presented here forms a basis for future studies to establish a plausible mechanism of organic residue absorption and preservation in ancient ceramics.

The mobility of rare-earth elements (REE) in low-grade diagenetic regimes, potentially leading to their clay-mediated fractionation, remains poorly understood. This study draws evidence from the argillitized Miocene tuff of the Southwestern Pannonian Basin (SPB) and adjacent Dinarides intramontane basins (DIB) to investigate the role of illite-smectite (I-S) in controlling early diagenetic REE behavior. The present research relies on detailed mineralogical, geochemical, and gas adsorption characterization of altered tuff, focusing on comparative analyses of the REE chemistry obtained by in situ laser ablation inductively coupled plasma mass spectrometry of glass shards and that of spatially related authigenic clay minerals. The depositional environment, in which the volcanic glass alteration took place, gave rise to the composition of secondary paragenesis, revealing a dominance of I-S. The normalized REE geochemistry of clay separates show similarities to unaltered glass, but notable differences indicate fluctuations in fluid/rock ratio environments. The redox conditions during glass alteration are reflected in Ce and Eu anomalies and indicate the ranges from oxic to anoxic across the analyzed tuffs. The results showed that I-S, formed through volcanic glass diagenesis, inherits magmatic REE signatures but also fractionates REE based on more reducing physiochemical conditions. The strong correlation between smectite content of I-S and a total budget of fractionated REE posits the smectite interlayers as prime factors controlling the REE fractionation during volcanic ash diagenesis. Furthermore, greater specific surface area values and development of slit-shaped porosity along the non-basal edges of I-S particles contributed to REE adsorption. These findings contribute to our understanding of REE behavior in low-temperature diagenetic environments, emphasizing the significance of clay minerals in retaining and fractionating these elements which may lead ultimately to the formation of economically viable ion-adsorption clay deposits.

Smectite growth is of importance across various fields due to its abundance on the surface of both Earth and Mars. However, the impact of the crystallinity of initial materials on smectite growth processes remains poorly understood. In this study, the kinetic processes of smectite growth were examined via experimental synthesis of trioctahedral Mg-Ni saponites. Mg-Ni saponites were synthesized using mixed precursors, specifically end-member Mg-saponite and Ni-saponite, which exhibit different crystallinities. The crystal chemistry and morphology of samples were analyzed using X-ray diffraction, Fourier-transform infrared spectroscopy, and high-angle annular dark-field scanning transmission electron microscopy. The experimental results converge towards these main conclusions: (i) the formation of Mg-Ni saponite solid solutions are promoted when the precursors are small particles, whereas large-particle precursors limit their own dissolution and do not yield Mg-Ni saponite solid solutions under the experimental conditions; (ii) because Ni exhibits a greater stability within the saponite structure compared to Mg, the Mg-Ni-saponite solid solutions formed more easily from the mixture of Ni-saponite germs and well-crystallized Mg-saponite precursors than from the mixture of Mg-saponite germs and well-crystallized Ni-saponite precursors; (iii) the dissolution extent (DE) of precursor mixtures increases with longer synthesis time, higher synthesis temperature, and larger gap between synthesis temperature of precursors and of samples, and stabilizes once it reaches a certain value. Thus DE can be used to estimate the kinetics of Mg-Ni saponite crystallization from precursor mixtures. These results obtained from the experimental Mg-Ni saponite system are useful for predicting the evolution processes of smectite in natural systems.

Cementitious materials and their alkaline pore fluids can change the structure of bentonite used as a raw material for road embankments or concrete storage of garbage cans. This study investigated the alteration of montmorillonite-rich bentonite from northeast Morocco (Trebia deposit, Nador) in alkaline media rich in Ca2+, Mg2+, Na+, or K+. Specimens based on raw bentonite mixed with variable proportions of oxides (CaO, MgO) or hydroxides (NaOH, KOH) and water were prepared and aged for 28 days. Mineralogical composition by X-ray diffraction (XRD) was determined on raw bentonite and specimens to follow phase changes. Chemical composition and thermal characteristics were determined for raw bentonite and specimens by Fourier-transform infrared spectroscopy (FT-IR) and thermogravimetric/differential thermal analysis (TGA/DTA). Microstructural evolution and alteration of the external surface of bentonite were evaluated using scanning electron microscopy coupled with energy dispersive X-ray (SEM/EDX) analysis. XRD results of bentonite-CaO mixture demonstrated the formation of gels (e.g. C-S-H) and calcite. When the amount of CaO added increased, excess portlandite and the precipitation of calcite in the outer surface of bentonite occurred, stopping pozzolanic reaction and consequently decreasing the compressive strength of specimens. On the other hand, the addition of MgO allowed the formation of brucite. Sodalite and cancrinite were neoformed with the addition of 32 wt.% NaOH after 28 days of hydration. The addition of hydroxides (NaOH or KOH) to bentonite did not reveal any setting due to the absence of the formation of cementitious phases.

Smectite may impact the ability of saline aquifer–caprock systems to store CO2 effectively, because of changes in pressure, temperature, and brine concentration induced by the injection of CO2. These changes influence the molar volume of smectite, affecting the short-term structural and stratigraphic trapping, or the dissolution of smectite via the long-term geochemical trapping. This study investigated the d001 value of an interlayer-cation-exchanged smectite, Na-rich SWy-2 (Na-SWy-2), with Ca or Mg (hereafter CaSWy-2 and MgSWy-2). Molar volume experiments used X-ray diffraction and a high-pressure environmental chamber. The extent of smectite dissolution was simulated at experimental conditions by geochemical modeling using a rate equation derived from the transition state theory. CaSWy-2-CaCl2 and MgSWy-2-MgCl2 brine systems showed that increasing the brine concentration from 0.17 M to saturation results in a <18% decrease in d001 values, and increasing the temperature from approximately 33 to 150°C results in <11% decrease. The effect of the interlayer cation shows the d001 values of MgSWy-2 are <0.4 Å higher compared with CaSWy-2. Geochemical modeling shows the extent of dissolution of Na-SWy-2, CaSWy-2, or MgSWy-2 is only <1.1% in acidic conditions. Furthermore, the calculated swelling pressure needed to decrease the H2O sheets in the interlayer, from 3W to 2W, of MgSWy-2 and CaSWy-2 are higher compared with Na-SWy-2. The swelling pressure was approximated from the sum of the osmotic repulsive pressure, the van der Waals attractive pressure, and the hydration pressure. The data suggest that Na-SWy-2, CaSWy-2, and MgSWy-2 may affect saline aquifer–caprock systems to store CO2. The molar volume is affected by changes in pressure, temperature and brine concentration, or swelling pressure from the injection of CO2. An increase in the d001 value of SWy-2 can enhance the sealing capabilities of a caprock by making saline aquifers less porous and less permeable and thus increasing the capability for CO2 storage. In contrast, a decrease in the d001 value can create cracks in a caprock and thus provide conduits for the CO2 to escape. Furthermore, the CO2 injection will cause a decrease in pH, causing smectite to dissolve until it reaches a steady state. However, despite acidic aquifer conditions, SWy-2 has low solubility.

Models of cation exchange mechanisms and driving forces have proven effective predictors of clay behavior and chemistry, but are largely theoretical, particularly in complex systems involving high ionic strength brines or systems where hydration is controlled by relative humidity. In arid and cold environments, such as Mars, cyclical relative humidity variations may play a role in chemical alteration, particularly if clay minerals such as smectite are in the presence of salts. This study examines the effects of relative humidity on smectite-salt mixtures using environmental scanning electron microscopy (ESEM) to observe the physiochemical effects of salt deliquescence and desiccation on smectite textures and elemental distributions. Results demonstrate that even reaction periods as short as a few minutes allow ample time for relative humidity to affect the smectite-salt mixtures. In addition to smectite swelling and salt deliquescence, we also observed rapid changes in element distributions within the smectite and new crystal growth in the presence of high relative humidity. Even in the absence of bulk liquid water, exchangeable cations migrated out of the smectite and formed new crystals at the smectite-salt interface. The observed microscopic changes in elemental distributions indicate that the migration of cations driven by cation exchange led to secondary mineral precipitation, likely a CaSO4 mineral, within a sub-micrometer-thick layer of water on the smectite grains. The results of this study demonstrate that during periods of elevated relative humidity, active smectite mineral alteration and secondary mineral precipitation may be possible on present-day Mars where salts and smectites are in direct physical contact.

Bentonite is an abundant natural resource in the Maghnia region of Algeria that may have potential value in catalysis, but heretofore has been considered of low value for this purpose due to its low acidity and low catalytic activity. Low cost is one of the main criteria for choosing a suitable material for catalysis. Because bentonite is abundant and low-cost, its use as a starting material for the preparation of catalysts deserves reconsideration. The present study was undertaken, therefore, to optimize the performance of bentonite as a catalyst in one of the most promising reactions in organic synthesis, namely, cyclohexene epoxidation. The bentonite was subjected to adjustment of its structure by means of a number of laboratory treatments based on its large cation exchange capacity. These modifications aimed to achieve an environmentally friendly catalytic process by incorporating transition metals, specifically titanium and vanadium, into the modified bentonite structure through acid activation. Redox properties were enhanced and Lewis and Brønsted acidities were introduced. The vanadium oxide, supported on titania-pillared, acid-activated bentonite (5V/Ti-AAC), was characterized comprehensively using various techniques, including diffuse-reflectance UV-visible spectroscopy (DR UV-Vis), Fourier-transform infrared spectroscopy (FTIR) for surface acidity analysis, X-ray diffraction (XRD), nitrogen adsorption-desorption isotherms, and scanning electron microscopy (SEM) coupled with energy-dispersive X-ray elemental analysis (EDX). The catalytic activity was investigated in response to certain variables, such as catalyst mass, nature of the solvent, amount of oxidant, and reaction temperature. A kinetic study was conducted to understand the reaction behavior. The experimental results demonstrated intriguing catalytic activity, achieving a 42% conversion rate with ~68% selectivity toward the epoxide product when employing tert-butyl hydroperoxide (TBHP) as the oxidant and heptane as the solvent. This study highlights the potential of 5V/Ti-AAC as an environmentally friendly catalyst applied in the epoxidation of cyclohexene.

Individuals may experience health issues attributable to environmental pollution, sedentary lifestyles, and unhealthy dietary habits. In response, numerous non-pharmaceutical treatments and techniques have emerged, with therapy mud being one such approach. The primary aim of this research was to analyze the chemical and mineralogical compositions of peloids obtained from six salt lakes: Taigan (LI), Duruu (LII), Khadaasan (LIII), Ikhes (LIV), Tonkhil (LV), and Khulmaa (LVI) in the Gobi-Altai province of Mongolia. Sample analyses involved X-ray diffraction for mineralogical assessment and inductively coupled plasma-mass spectrometry (Agilent Technologies 7800 series in Canada) for determining the chemical composition of the solid phase. Among essential macro- and microelements, Mg, Cа, Na, K, Sr, Ga, Mo, and Se had been leached from peloid to artificial sweat. Sn (0.01 μg g–1) at LIV and LVI lakes and Cu (0.01 μg g–1) at LV lake transferred from peloids to sweat, but no mobility of these elements in other peloids was detected. Li (0.02–0.04 μg g–1) was adsorbed from the sweat to potential peloids in LV, LIV, LIII, and LI lakes, while As (0.04–0.09 μg g–1) leached from peloids to sweat in all lakes except for LII. Zn (0.01 μg g–1) and Cr (0.04 μg g–1) transferred from the sweat to peloids in all lakes. Macroelements (Na, K, Ca, and Mg) and microelements (Mo, Se), which are essential for the human body, leached from the peloid to sweat. However, the mobility of toxic elements was minimal. Among micro-elements, the transition of Sr occurred the most, which can be explained by the Sr content in the peloid.