In May, 1936, a quantity of pale yellow, rounded fragments, averaging 7 mm. across, was submitted to us by Mr. Arthur Russell for examination, with the information that the material came from the Castle-an-Dinas wolfram mine, and contained bismuth and tungsten. Chemical and spectroscopic examination showed that, besides bismuth and tungsten, the mineral contained only traces of silicon, arsenic, and iron. A sample of the same material had also been given to the British Museum by Mr. E. H. Davison in 1934 and registered provisionally as bismuth tungstate. This, however, would not have provided sufficient of the yellow mineral for chemical analysis. We are also indebted to Mr. Davison for a further generous supply of yellow pellets picked from the wolfram concentrates received since tile present work was begun. The mineral has all the attributes of an alteration product probably of native bismuth. It is fine-grained and compact, with hardness 3½, and on fracture it gives a clay-like odour. Some of the pellets show traces of a micaeeous mineral and quite frequently enclose native bismuth, wolframite, and bismuthinite. Mr. Russell has picked out from tihe material he had collected a few green pellets and some showing both the yellow and the green mineral. Spectrographs of the two are identical, but an X-ray powder photograph of the green mineral is quite distinct from that of tile yellow mineral.