Flow patterns of causal significance to three-dimensional isotropic turbulence are identified through the recently introduced algorithm of Jiménez (J. Fluid Mech., vol. 854, 2018, R1). Localised perturbations are introduced at arbitrary regions of a triple-periodic decaying flow at ${Re}_\lambda \approx 190$, and their evolution is used as a marker of the significance of said regions to the flow. Their dimensions are found to be an important parameter, with sizes of the order of the integral scale being controlled by the kinetic energy content, and sizes within the dissipative range, by the enstrophy and dissipation. The three quantities are found to be important at intermediate (inertial) scales. Prominent differences emerge between regions of high and low significance. The former typically contain strong gradients and/or kinetic energy and the latter are weak. An analysis of the structure of significant and insignificant flow patterns reveals that strain is more efficient than vorticity at propagating the contents of the perturbation to other regions of the flow. Moreover, the flow patterns of significant regions are found to be more complex, typically containing vortex clusters, while simpler vortex sheets are found in insignificant regions. The present results suggest that strategies aiming to manipulate the flow should focus on strain-dominated vortex clusters, avoiding enstrophy-dominated vortex sheets. This is confirmed through an assimilation experiment, in which greater synchronisation between two simulations is achieved when simulations share significant regions rather than insignificant ones. These conclusions have implications for both the control of turbulent flows and the making of predictions based on limited or noisy measurements.

Heat and mass transports through a rough surface are among the most fundamental and important phenomena in either natural or engineering problems. In this paper, theoretical modelling and direct simulation Monte Carlo method are employed to study the heterogeneous reaction–diffusion features induced by microscale roughness which is comparable to the molecular mean free path of the ambient gas. A quasi-one-dimensional homogeneous model is proposed, and it consists of an external diffusion region outside the roughness elements and an internal reaction–diffusion region which could be equivalent to a smooth surface with an effective chemical property. The external macroscopic diffusion can be characterized by a non-equilibrium criterion – the Damköhler number. The internal diffusion in micro-cavities must be analysed by considering the rarefied gas effects on the diffusivity, and another non-equilibrium criterion, the Thiele number, is introduced to evaluate the effective boundary condition imposed on the external region. Analytical formulae based on these criteria are derived to predict the equivalent surface reaction–diffusion performance, and the predictions compare well with the numerical results of different types of surface reaction, even on the three-dimensional roughness. This reveals that the roughness could either enhance or weaken the apparent reaction rate depending on the non-equilibrium degree. This study could enrich our understanding of the gas–surface interactions on a rough wall, such as the oxidation, catalysis and energy accommodation, and also preliminarily provides a practical method for evaluation of the aerothermochemical performance of coating materials of hypersonic vehicles.

Viscous fingering or Saffman–Taylor instability shows fingering interfacial patterns when a more mobile fluid displaces a less mobile one in porous media. The effective interfacial tension (EIT) is like capillary force, acting at the miscible interface on time scales shorter than interface relaxation. It has been numerically reported so far that the fingers are wider with EIT compared with those without EIT. A recent experiment observed finger widening with increasing flow rate in a miscible system with EIT, which is not observed in classical immiscible and miscible systems. In this study, we have numerically investigated the effect of $Pe$ (which corresponds to the injection flow rates in the experiment) on miscible viscous fingering with/without EIT. We have shown that the fingers are monotonically thinner with an increase in $Pe$ in the system without EIT, while finger widening with increasing $Pe$ is observed in the system with EIT. Furthermore, we have also examined a one-dimensional underlying concentration profile and EIT profile by using a one-dimensional diffusion–convection model because EIT is proportional to the squared concentration gradient. We have then shown that the concentration gradient is steeper and, thus, the EIT is larger as $Pe$ is larger. Therefore, this is the first numerical study that can theoretically verify finger widening with increasing flow rate, which occurs only in a miscible system with EIT to the extent of our targeting EIT values, and explain the mechanism by one-dimensional analysis.