Hydrocarbon migration mechanism into a reservoir is one of the most controversial in oil and gas geology. The research aimed to study the effect of supercritical carbon dioxide (СО2) on the permeability of sedimentary rocks (carbonates, argillite, oil shale), which was assessed by the yield of chloroform extracts and gas permeability (carbonate, argillite) before and after the treatment of rocks with supercritical СО2. An increase in the permeability of dense potentially oil-source rocks has been noted, which is explained by the dissolution of carbonates to bicarbonates due to the high chemical activity of supercritical СО2 and water dissolved in it. Similarly, in geological processes, the introduction of deep supercritical fluid into sedimentary rocks can increase the permeability and, possibly, the porosity of rocks, which will facilitate the primary migration of hydrocarbons and improve the reservoir properties of the rocks. The considered mechanism of hydrocarbon migration in the flow of deep supercritical fluid makes it possible to revise the time and duration of the formation of gas–oil deposits decreasingly, as well as to explain features in the formation of various sources of hydrocarbons and observed inflow of oil into operating and exhausted wells.

The integration of biostratigraphical, wireline log, geophysical and available geochronological ages has identified two principal periods of volcanism in the Faroe–Shetland and Rockall basins. The first is pre-breakup, upper Danian to lower Thanetian: in the Rockall and Faroe–Shetland basins, isolated volcanic activity from 62 Ma to 58.7 Ma is identified in areas closely linked to the SSW–NNE structural fabric of the continental margin. Volcanic activity was concentrated at basin flank fissures and localised point sources. This rift-flank volcanism led to widespread volcanic ash deposition, localised lava flow fields and the formation of igneous centres. Some of the Hebridean and onshore central complexes (e.g., Rum) were uplifted and rapidly eroded during the later pre-breakup period, while additional accommodation space was developed in the adjacent offshore basins. Onset and termination of pre-breakup volcanism is correlated to intra-plate stress regimes in Europe, following the cessation of convergence of Africa and Europe in the Danian. The second is syn-breakup, upper Thanetian to Ypresian, initiated at ca.57 Ma in the Rockall and Faroe–Shetland basins. Initial high-volume extrusive igneous successions were focussed to the W in the Faroe–Shetland Basin. In the centre and E of the Faroe–Shetland and Rockall basins, separate eruption loci developed along pre-existing lineaments either as fissure or point-sourced lava fields. Short-term cessation of eruption at ~55.8 Ma was followed by resumption of flood basalt eruptions and a shift in focus to the NW. Fluctuations in the syn-breakup eruption tempo are reflected in the formation and subsequent rejuvenation of prominent unconformities, only previously recognised as a single erosive event. The W and northward shift of eruption focus, and the eruption of mid ocean ridge basalt-type lavas in the syn-breakup period reflect the onset of lithospheric thinning in the nascent North Atlantic Rift prior to flooding of the rift and eruption of the widespread lower Ypresian Balder Formation tephras.

Groundwater is widely used in the semi-arid region of Remila plain (Khenchela, Algeria) for urban and agricultural supplies. An integrated statistical and hydro-geochemical approach was performed with 70 water samples in order to identify the main processes and the origin of water salinisation. The results have suggested the dominance of three chemical facies: Sulphato cloruro calcic (SO4–Cl–Ca) in the northeastern part, Sulphato cloruro calci magnisian (SO–4Cl–Ca–Mg) in most of the waters andalkali-earth bicarbonate (HCO3–Ca–Mg) in the southeastern part. Although based on principal component analysis and hierarchical clustering analysis, the statistical approach identified three water groups: (1) saline water (17 %; total dissolved solids >1000 mg l−1 with the dominance of Sulphate (SO42−)); (2) moderately saline water (17 %) with a dominance of bicarbonate (HCO3−); and (3) moderately saline water (66 %) with mixed facies. The binary diagrams confirmed the predominance of three processes: evaporite dissolution and/or precipitation, combined by ionic exchange. In the northeastern part of the area, however, another process was detected – the saline intrusion of Sabkha water, favoured by extensive groundwater use.

During the Upper Ordovician–Lower Silurian, chert was widely distributed in the Zhongbao Formation in the eastern part of the North Qilian Orogen. The origin and the tectonic setting of these chert were largely unknown. In order to analyse the material provenance, sedimentary environment, their formation and the tectonic setting, we present petrology and geochemical research on chert samples collected from Shihuigou Section. The evidence provided by radiolarite occurrences, Aluminium (Al)–iron (Fe)–manganese diagram and the silicon(Si)/Si + Al + Fe + calcium ratios suggesting a non-hydrothermal input and the biogenic origin chert. The geochemical features and the petrographic signatures have shown that the chert was also influenced by a terrigenous origin. It is considered that the deposition of the Late Ordovician chert is mainly affected by tectonic collision and volcanic ash events. During the Late Ordovician–Early Silurian transition, huge amounts of volcanic ash were released by massive volcanic activity that fell into the ocean, triggering the proliferation of radiolarians. Finally, in the Late Ordovician–Lower Silurian the tectonic setting of the North Qilian Orogen was not a typical deep-water basin, nor a typical continental margin, but a multi-island deep-water basin, which is closed to the mainland.

The quality and richness of Perthshire's natural environment were formative influences on a young James Croll (1821–1890), which left him with a life-long appreciation of nature, landscape and natural meditation. Although Croll himself declares to have had little interest in geology in his earlier years, it became a central theme of his scientific understanding, which implies the clear influence of both his local environment and of his father David, a stonemason. His family and friends also shaped him in other ways, not least his love of reading, his unconstrained thinking and intellectual acuity. He inherited his father's moral character, amiability and an excitement about intellectual inquiry, which drew friends to him who made great efforts to assist him in his work, both personally and professionally, and played a role in his being offered a position by James Geikie with the Geological Survey of Scotland. Croll's financial position was often precarious; he spent a good deal of his life in relative poverty. Whilst this affected his opportunities for formal learning, it may well have led to his ability to think creatively and to seek answers more broadly than he might have if he had been able to engage in a more formal education. Ill health, which affected him throughout his life, could be seen to both hamper his work – but also through circumstance lead him to pursue a more academic path, as other routes of work were shut off to him. Ultimately Whitefield, Wolfhill and the wider Perthshire countryside in which he grew up can clearly be seen to have influenced his life in many ways, even, perhaps, to the extent of his chosen surname.

While the external infiltration of water has been identified from modern geothermal and/or fossil hydrothermal systems through stable isotopes, the physicochemical boundary conditions like the initial oxygen isotopes of water $( {{\rm \delta }^{ 18}{\rm O}_{\rm W}^{\rm i} } ) $ and rock as well as alteration temperature were implicitly presumed or empirically estimated by the conventional forward modelling. In terms of a novel procedure proposed to deal with partial re-equilibration of oxygen isotopes between constituent minerals and water, the externally infiltrated meteoric and magmatic water are theoretically inverted from the early Cretaceous post-collisional granitoid and intruded Triassic gneissic country rock across the Dabie orogen in central-eastern China. The meteoric water with a $ {{\rm \delta }^{ 18}{\rm O}_{\rm W}^{\rm i} } $ value of −11.01 ‰ was externally infiltrated with a granitoid and thermodynamically re-equilibrated with rock-forming minerals at 140°C with a minimum water/rock (W/R)o ratio around 1.10 for an open system. The lifetime of this meteoric hydrothermal system is kinetically constrained less than 0.7 million years (Myr) via modelling of surface reaction oxygen exchange. A gneissic country rock, however, was externally infiltrated by a magmatic water with $ {{\rm \delta }^{ 18}{\rm O}_{\rm W}^{\rm i} } $ value of 4.21 ‰ at 340°C with a (W/R)o ratio of 1.23, and this magmatic hydrothermal system could last no more than 12 thousand years (Kyr) to rapidly re-equilibrate with rock-forming minerals. Nevertheless, the external infiltration of water can be theoretically inverted with oxygen isotopes of re-equilibrated rock-forming minerals, and the ancient hydrothermal systems driven by magmatism or metamorphism within continental orogens worldwide can be reliably quantified.

Popular and scholarly information concerning the life of James Croll has been accumulating slowly since the death in 1890 of the self-taught climate change pioneer. The papers in the current volume offer thorough assessments of topics associated with Croll's work, but this contribution seeks to provide a personal context for an understanding of James Croll the man, as well as James Croll the scholar of sciences and religion. Using archival as well as published sources, emphasis is placed upon selected components of his life and some of the less recognised features of his biography. These include his family history, his many homes, his health, participation in learned societies and attitudes to collegiality, financial problems including the failed efforts to secure a larger pension, and friendship. Life delivered a mixture of ‘trials and sorrows’, but it seems clear from the affection and respect accorded him that many looked upon James Croll as a ‘man greater far than his work’.

Pareiasaurs were globally distributed, abundant, herbivorous parareptiles with the basal-most members found only in the mid-Permian of South Africa. These basal forms form a monophyletic group and were locally abundant and became extinct at the top of the Tapinocephalus Assemblage Zone at the end of the Guadalupian. Four species of basal pareiasaurs are currently recognised: Bradysaurus baini, B. seeleyi, Embrithosaurus schwarzi and Nochelesaurus alexanderi, but they are all poorly understood and there remains historic uncertainty as to their validity. In this paper, our second contribution designed to improve understanding of the basal group, we present the first detailed cranial description and updated diagnosis for Nochelesaurus alexanderi and demonstrate that it is a distinct taxon based on one cranial autapomorphy, a large transversely wide postparietal, and a combination of cranial characters. Within the local group of mid-Permian pareiasaurs, we recognise new dental features of Nochelesaurus alexanderi: non-symmetrical marginal cusp arrangements on upper and lower teeth resulting from an extra basal mesial cusp; an incipient horizontal cingulum on lower jaw teeth, sometimes with one or two tiny medial cingular cusps; and up to ten marginal cusps. Our study demonstrates that tooth morphology and orientation, cranial ornamentation, morphology of the cheek bosses, shape of the postfrontal and postparietal, and morphology of the distal paroccipital process of the opisthotic are the most useful to identify South African mid-Permian pareiasaurs.

Antibiotic residues have entered into the environment owing to the unreasonable use and disposal of antibiotics. The emergence of antibiotic resistance poses a huge threat to ecosystems and human health. In this study, the network analysis method was used to compare publications on antibiotics in water, soil and sediment from the aspects of countries, institutes, journals, subject categories and keywords based on Web of Science Core Collection. The results indicated that the United States of America and China had dominant positions of studies on antibiotics. The Chinese Academy of Sciences published the most articles on antibiotic research. ‘Chemosphere’, ‘Science of the Total Environment’, ‘Environmental Science and Technology’ and ‘Applied and Environmental Microbiology’ all appeared in the top six journals. ‘Environmental Sciences and Ecology’ was the core subject category of antibiotic research. Further analysis results depicted that ‘Antibiotics’, ‘Tetracycline’ and ‘Antibiotic Resistance’ were found as the research hotspots. Tetracycline and oxytetracycline all showed in the top 50 keywords of antibiotics research in water, soil and sediment. However, chlortetracycline, sulfadiazine and tylosin all emerged only in the top 50 keywords of antibiotics study in soil. In future, more attention should be paid to antibiotic resistance genes and antibiotic resistance bacteria in antibiotics research.

This research evaluated the variability of current characteristics and seawater properties in the middle part of the southern shelf of the Caspian Sea. The effect of the coastal flow on marine debris dispreading was assessed in the southern Caspian Sea for the first time. The findings showed the existence of thermal stratification containing seasonal thermocline with thickness of about 40 m in the water column. Maximum monthly along-shore current velocities around 1.3 m s−1 were observed in November and December. Monthly variations were clearly found in both flow velocity and local wind components. However, no significant levels of correlation between wind and current speeds were observed during the study in the region. In some cases, the mean monthly cross-shore component velocities were measured at about 29 cm s−1 in November. The findings indicated that there was no upwelling phenomenon associated to the regional wind in the study area. In situ current measurements indicated dominant east and north-northeast directions, presumably related to the effect of general circulation in the southern basin. Current profiles in the water column displayed similarity in directions at 10, 15 and 20 m depths over the continental shelf. The field samples and analysis revealed that the soft and smaller-scale seawater litters can be carried long distances by the current along the coast. Most coastal based and marine litters originated from the tourist activities (in the middle and western parts of the shores) and waste emanated from the river (Tonekabon-Nowshahr).

James Croll left school at the age of 13 years, yet while a janitor in Glasgow he published a landmark paper on astronomically-related climate change, claimed as ‘the most important discovery in paleoclimatology’, and which brought him to the attention of Charles Darwin, William Thomson and John Tyndall, amongst others. By 1867 he was persuaded to become Secretary and Accountant of the newly established Geological Survey of Scotland in Edinburgh, and a year after the appearance of his keynote volume Climate and time in 1875, he was lauded with an honorary doctorate from Scotland's oldest university, Fellowship of the Royal Society of London and Honorary Membership of the New York Academy of Sciences. Using a range of archival and published sources, this paper explores aspects of his ‘journey’ and the background to the award of these major accolades. It also discusses why he never became a Fellow of his national academy, the Royal Society of Edinburgh. In the world of 19th-Century science, Croll was not unusual in being both an autodidact and of humble origins, nor was he lacking in support for his endeavours. It is possible that a combination of Croll's modesty and innovative genius fostered advancement, though this did not hinder a willingness to engage in vigorous argument.

Scientific societies played a crucial role in the emergence of a professional culture of science in Britain in the mid- to late-19th Century. At first sight, James Croll's membership of a limited number of scientific associations may be assumed to be the result of his lack of social credit and scientific connections. In this article, by examining Croll's correspondence, I demonstrate that Croll's select participation in scientific clubs and associations reflected his strategic pursuit of a vision of science set apart from party or societal affiliation. I focus on the contrasting histories of the Royal Society of Edinburgh and the Geological Survey, as well as the institutional history of the Philosophical Magazine. Situating the institutions in their respective social and cultural contexts, I argue that the more meritocratic, inclusive social structure of the Survey and Magazine helps explain Croll's choice to avoid affiliation with the Royal Society of Edinburgh.

Moradisaurine captorhinid eureptiles were a successful group of high-fibre herbivores that lived in the arid low latitudes of Pangaea during the Permian. Here we describe a palaeoassemblage from the Permian of Menorca (Balearic Islands, western Mediterranean), consisting of ichnites of small captorhinomorph eureptiles, probably moradisaurines (Hyloidichnus), and parareptiles (cf. Erpetopus), and bones of two different taxa of moradisaurines. The smallest of the two is not diagnostic beyond Moradisaurinae incertae sedis. The largest one, on the other hand, shows characters that are not present in any other known species of moradisaurine (densely ornamented maxillar teeth), and it is therefore described as Balearosaurus bombardensis gen. et sp. nov. Other remains found in the same outcrop are identified as cf. Balearosaurus bombardensis gen. et sp. nov., as they could also belong to the newly described taxon. This species is sister to the moradisaurine from the lower Permian of the neighbouring island of Mallorca, and is also closely related to the North American genus Rothianiscus. This makes it possible to suggest the hypothesis that the Variscan mountains, which separated North America from southern Europe during the Permian, were not a very important palaeobiogeographical barrier to the dispersion of moradisaurines. In fact, mapping all moradisaurine occurrences known so far, it is shown that their distribution area encompassed both sides of the Variscan mountains, essentially being restricted to the arid belt of palaeoequatorial Pangaea, where they probably outcompeted other herbivorous clades until they died out in the late Permian.

Science, for James Croll, began and ended in metaphysics. Metaphysics, in turn, provided proof of a First and Final Cause of all things. This proof rested on two metaphysical principles: that every event must have a cause, and that the determination of a cause is distinct from its production. This argument emerged from his deeply held religious commitments. As a 17-year-old, he converted to a Calvinist and evangelical form of Christianity. After a period of questioning the Calvinist system, he embraced it again through reading the famous treatise on the will by the New England theologian, Jonathan Edwards. This determinedly metaphysical work, which engaged as much with Enlightenment thought as with Calvinism, defended the view that the will was not a self-determining cause of human action. This ‘hard case’ provided the basis for a larger claim that every act whatever has a cause, and that the production of an act was different from its determination. In part through reading Edwards, Croll remained a devout and convinced ‘moderate’ Calvinist for the rest of his life. He also developed a deep love of metaphysics and became convinced that without it, everything, including science, remained confused and in darkness. For Croll, even the most basic science could not be properly conducted without prior metaphysical principles. But this was more than just an argument about the philosophical foundations of scientific inquiry. It was also based on Croll's conviction that the cosmos, earth history and life (including his own) was fully determined by a supreme and perfect intellect. This conviction entered into the marrow of Croll's scientific theories and shaped his interpretation of the twists and turns of his own life. In short, to take seriously Croll's own self-understanding, we need to allow him to ‘do God’.

Echimyidae is the most widely diversified family among hystricognath rodents, both in the number of species and variety of lifestyles. In the Patagonian Subregion of southern South America, extinct echimyids related to living arboreal species (Echimyini) are recorded up to the middle Miocene, whereas all the known southern fossils since the late Miocene are linked to terrestrial and fossorial lineages currently inhabiting the Chacoan open biome in eastern South America. In this work, we describe a new genus of echimyid rodent, Paralonchothrix gen. nov., from the late Miocene of northwestern Argentina and western Brazil. Its single recognised species, Paralonchothrix ponderosus comb. nov., is represented by two hemimandibles. One of them comes from a level of Loma de Las Tapias Formation, underlying a tuff dated at 7.0 ± 0.9 Ma (Huayquerian age, late Miocene); the other specimen comes from the ‘Araucanense’ of Valle de Santa María (type locality, Huayquerian age, late Miocene). A phylogenetic analysis linked Paralonchothrix to Lonchothrix, both being the sister group to Mesomys. Thereby, for the first time, an echimyid linked to living Amazonian arboreal clades is recognised for the late Miocene of southern South America. Paralonchothrix gen. nov. thus represents an exceptional record that raises the need to review the postulated evolutionary pattern for echimyids recorded at high latitudes since the late Miocene. The new genus provides a minimum age (ca.7 Ma) in the fossil record for the divergence between Mesomys and Lonchothrix. The palaeoenvironmental conditions inferred for the late Miocene in western and northwestern Argentina suggest savanna-type environments, with areas with more closed woodlands in peri-Andean valleys. The record of Paralonchothrix gen. nov. supports the hypothesis that this area would have maintained connections with tropical biomes of northern South America during the late Miocene.

James Croll was a pioneer in studies of the impact of the slowly changing orbital dynamics of the Earth on climate change. His book Climate and Time in their Geological Relations (1875) was far ahead of its time in seeking correlations between climate change, the occurrence of ice ages and perturbations to the Earth's orbit about the Sun. The astronomical cycles he discovered are now called ‘Milankovitch Cycles’ after the Serbian scientist whose research was first published in the Handbuch der Klimatologie in 1930. The celestial mechanical and astronomical background to Croll's research is the focus of this essay. The development of the understanding of the impact of perturbations of the elliptical planetary orbits by other bodies in the solar system paralleled new mathematical techniques, many of which were developed in association with celestial mechanical problems. The central contributions of many of the major mathematicians of the late 18th and 19th Centuries, including Euler, Lagrange, Laplace and Le Verrier, are highlighted. Although Croll's contributions faded from view for several generations, his pioneering insights have now been demonstrated to have been basically correct.