The garnet-orthopyroxene Al barometer specifically considers the Al content of orthopyroxene in equilibrium with garnet resulting from Mg-Tschermaks substitution. It is demonstrated that P-T calibrations of this barometer derived solely from experimental data for the MAS system, such as that favoured by Finnerty and Boyd (1984, 1987) based on the data of MacGregor (1974), cannot be expected to yield meaningful pressure estimates for natural garnet lherzolite assemblages. The presence of additional CaO, FeO and Cr2O3 components in natural garnet lherzolites can be expected to influence substantially the Al partitioning between orthopyroxene, garnet and/or spinel at any particular P and T. Thus a more comprehensive barometer formulation is required, such as the one provided by Nickel and Green (1985) that is based on experimental data for the CMAS and SMACCR systems with thermodynamic modelling and addition of an Fe correction term.

It is further emphasised that for orthopyroxenes in natural garnet lherzolites the amount of Al introduced as Mg-Tschermaks substitution cannot be assessed simply as the total Al cation content since such orthopyroxenes frequently contain Al cations linked to Na substitution in M2 sites or to Cr, Ti and possibly Fe3+ in M1 sites. Revised algorithms for the calculation of specific orthopyroxene contents are presented. Application to analytical data sets for garnet lherzolite zenolith suites in the Thaba Putsoa and Mothae kimberlites generates revised upper mantle P-T arrays which refute the widely accepted advocacy by Finnerty and Boyd (1984, 1987) and Finnerty (1989) of an upper-mantle palaeogeotherm beneath northern Lesotho that is markedly inflected to a higher thermal gradient at the depths of derivation of the more chemically fertile, porphyroclastic textured, xenoliths.

Spinel lherzolite xenoliths from two localities in the Massif Central are undepleted in Al2O3, CaO, and Na2O. One suite from Tarreyres, is K2O depleted and amphibole-bearing whereas the other, from Monistrol d'Allier some 18 km away, is amphibole-free and has a higher mean K2O content of 0.035 wt.%. We present bulk major and minor element abundances in a harzburgite and a lherzolite from each locality and microprobe analyses of their constituent phases. Amphibole-bearing lherzolite and its pyroxenes are light-rare earth element (LREE) depleted, whereas amphibole-free lherzolite and its pyroxenes are LREE enriched. Both harzburgites and their pyroxenes are LREE enriched and one rock contains LREE enriched glass. The harzburgites are like harzburgite xenoliths from elsewhere but each lherzolite represents a previously unrecognized type of mantle in terms of the mineralogy and REE content. The implication for basalt genesis are briefly discussed.

We present petrographic and mineralogical data for 21 mantle xenoliths (12 lherzolites, 8 wehrlites and 1 composite) selected from a suite of more than 70 samples collected from the Monticchio Formation, Mt. Vulture volcano, southern Italy. The xenoliths are rounded, coarse- to porphyroclastic-textured, and very fresh, with the following equilibrated mineral assemblages; olivine (Fo90–92), orthopyroxene (∼En89, Wo2.0), clinopyroxene (Mg90–92, 3–6% Al2O3, 1–1.5% Cr2O3), and chrome-spinel (14–20% MgO, ∼30–40% Cr2O3). Many xenoliths contain partial melt glasses and accessory sulphide (pentlandite) Some contain primary mica (phlogopite with ∼4% FeO, 1.8% Cr2O3, 1.4–2.8% TiO2) with slightly zoned rims (Fe-, Ti-, Al-enriched). One contains relics of garnet (pyrope; Mg84). Secondary veins in several xenoliths contain carbonate with significant Sr levels (∼0.5–1.0% SrO), occasional apatite and scarce melanite, all typical of carbonatites and presumably related to the host magma (melilitite/carbonatite). Although amphibole is a common megacryst in the same volcanic units, no primary amphibole was found in the xenoliths themselves. Calculated pressures and temperatures using a range of geothermometers/barometers give values of 14–22 kbar and 1050–1150°C. In particular, the En-Sp and Di-Sp thermo/barometers (Mercier, 1980) show a good positive correlation between P and T. The Monticchio xenoliths lie on the high-T side of an ‘oceanic’ geotherm. The xenolith geotherm is hotter than general heat flow values in this region at the current day (50 mWm−2) but it compares well with the high-pressure end of a typical alkaline continental rift.

Some twenty kimberlite pipes outcrop along the eastern and western borders of the Kundelungu plateau, Shaba Province, Zaire. They are arranged roughly along two north-south trending alignments. The pipes probably intruded the Bangweulu Block, which stabilized around 1800 Ma. The exceptionally fresh kimberlites contain mantle-derived nodules (peridotites and eclogites), as well as megacrysts which may reach up to several cm in diameter. The most important megacrysts are garnets, ilmenites, clinopyroxenes, orthopyroxenes and olivines. Micas and diamonds are rarely observed. The clinopyroxenes can be subdivided in two groups: (1) a Ca-rich, low-T type, similar to the Cr-rich diopsides found in ‘depleted’ (granular) peridotites; and (2) subcalcic clinopyroxene comparable to the megacrysts and to the clinopyroxenes of ‘fertile’ (sheared) peridotites. The orthopyroxenes are less frequent and are Ca-poor enstatites (0.07–0.42 wt.% CaO) and Ti-bronzites (CaO <1.3 wt.%). All the analysed garnets are Ca-rich (>4.5 wt.% CaO) and all fall in the lherzolite field defined by Sobolev et al., 1973. The low-Ca garnets which appear in many diamond-bearing kimberlites have never been observed in Zaire, neither in the diamond-poor Kundelungu pipes nor in the diamond-rich Mbuji-Mayi pipes. The ilmenites define a trend close to the ‘magmatic Mg-enrichment trend';. The olivine macrocrysts have Fo contents comparable to those of peridotites (Fo90–93). The ultramafic nodules comprise lherzolites, harzburgites, pyroxenites, wehrlites and dunites. The granular textures and P-T equilibrium conditions (770–1380°C and 28–61 kbar) deduced from their mineral compositions, show clearly that they were derived from a mantle zone on the continental geotherm (90–190 km depth). The eclogite nodules, which are less frequent, contain only two mineral phases (pyrope-almandine-grossular and omphacite), and the texture and the mineral compositions are similar to those of Roberts Victor eclogites. Our findings support the conclusion of Nixon and Condliffe (1989) that low-T peridotites, eclogites and pyroxenites derived from ‘depleted’ lithosphere, while Cr-poor garnet, subcalcic diopside and bronzite megacrysts cristallized from fertile asthenosphere.

Major and trace element, including REE, analytical data are used as bases for interpreting the petrogenesis of the major igneous components of the northern part of the Ballantrae complex which occurs in the southwestern part of the Midland Valley of Scotland. Most of the peridotite, now serpentinised, is similar to ultramafic rocks in other ophiolite complexes. Mean crystallisation conditions, determined on the basis of co-existing orthopy-roxenes and clinopyroxenes for the dominant peridotite and minor pyroxenite were 1060 (±60)°C—20 (±2) kb and 1240 (±89)°C—25 (±25) kb, respectively. These rocks, of mantle provenance, have compositions consistent with being residues after the extraction of 20–30% of tholeiitic material from the mantle. The presence among them of a rock whose REE contents indicate that it is a plagioclase peridotite, point to the tectonic incorporation of the products of a high level magma chamber.

The mafic parts of the complex have tholeiitic characteristics and developed between 1300° and 1100°C. They do not represent primary mantle melt but fractionated material. Clinopyroxene was the main fractionating phase and more than 10% fractional crystallisation is indicated with increase from gabbros, through beerbachites (metadolerites) of a sheeted dyke complex and pillow lavas, to microgabbros and pyroxene diorites. Biotite diorites and trondhjemites represent the most fractionated products, the latter having affinities with ophiolitic plagiogranites.

The beerbachites of the sheeted dyke complex do not all represent the same stage of fractionation. The pillow lavas have REE patterns similar to rocks found in marginal basins but are markedly different from pillow lavas from the Highland Border Complex in Arran, near the northern margin of the Midland Valley.

Ultramafic xenolith lithologies representative of the mantle beneath the Midland Valley of Scotland comprise magnesian peridotite (predominantly spinel lherzolite) and cumulate wehrlites and clinopyroxenites. The lherzolites are typical of the worldwide type I (Cr-diopside) xenolith suite; their textures and mineral chemistry record a complex thermal and deformational history. The petrographical and mineralogical features of the wehrlite-clinopyroxenite suite can be interpreted within the context of a sequence of cpx + ol ± sp cumulates that have undergone a protracted period of subsoli dus re-equilibration. Mineral compositions are similar to those of type II (Al-augite) ultramafic xenolith suites.

Although xenolith populations imply widespread lower crustal heterogeneity, meta-igneous basic granulites form a major component of this region beneath the Midland Valley. They are principally composed of pi + cpx + mt ± opx ± ap; a modal continuum exists from clinopyroxenite to anorthosite, skewed towards plagioclase-rich lithologies. Garnet is rare. Locally, evidence indicates re-equilibration from garnet granulite precursors. Rock densities range from c. 2·8 to c. 3·2 gm . cm−3, implying P-wave velocities in the range 6·5–7·5 km . s−1 consistent with the known seismic properties of the lower crustal layer beneath the Midland Valley. Phase relations are also consistent with equilibration of primary assemblages at depths of 20–35 km. Retrograde reactions indicate that portions of the crust may have had a complex pressure-temperature-time evolution. Major element compositions of the granulites are broadly basaltic, ranging from ne to hy normative with the mean corresponding to alkali olivine basalt. They are distinct, chemically, from basic granulites of the Lewisian complex of NW Scotland.

Late Palaeozoic alkalic basalts in and around the Midland Valley of Scotland contain a wide variety of ‘plutonic’ xenoliths. Pyroxene-rich ultramark xenoliths (wehrlites, clinopyroxenites and garnet pyroxenites) may be representative of younger components within a dominantly peridotitic upper mantle represented by ubiquitous magnesian peridotite xenoliths. Glimmerites and other biotite-rich ultramafic xenoliths are probable samples of metasomatised upper mantle facies.

Xenoliths composed mainly of plagioclase, clinopyroxene ± orthopyroxene ± magnetite are widespread. These pyroxene granulites may typify the lower crustal layers. Garnet granulites are rare; such rocks may formerly have been important with loss of garnet occurring through retrograde metamorphism. Anorthositic xenoliths are relatively common. The lower crust may consist largely of anhydrous rocks, of gabbroic to anorthositic composition, ccurring as stratiform bodies of metacumulates.

Other xenoliths of igneous origin include tonalitic and trondhjemitic gneisses. Although these may play some role in the lower crust, they may be more abundant in the mid-crustal domains underlying the deformed upper Precambrian and lower Palaeozoic supracrustal strata. Xenoliths of quartzofeldspathic, granulitic gneisses containing garnet ± sillimanite ± rutile are also of widespread occurrence; many of these are of metasedimentary provenance and are regarded as being derived from the mid-crustal layers beneath the Southern Highlands, Midland Valley and Southern Uplands and their Irish counterparts.

Garnet-bearing xenoliths from Letseng-la-Terae display a range of textures from coarse to granuloblastic. Equilibration temperatures and pressures of primary phases are in the ranges 950-1400°C and 27-50 kb, respectively. Deformed lherzolites equilibrated throughout this temperature range but coarse xenoliths are restricted to low temperature equilibration.

All garnets display coronas developed during the reaction:

In some rocks, reaction has completely eliminated garnet.

In rocks where garnet is disrupted, the corona minerals are strung out in the fluidal texture indicating that reaction occurred before deformation. Rocks transitional to, and of granuloblastic texture, contain garnet and aluminous spinel; in addition ‘pools’ of minerals originating by dynamic separation of corona fragments are observed.

Chemical comparison between the corona minerals and minerals in a garnet-spinel rock and two spinel granuloblastites, suggests that these spinel-bearing rocks may be derived from normal garnet peridotite by a complex sequence of reaction, followed by deformation, annealing and chemical homogenisation. The conclusion that reaction and deformation took place at high levels in the upper mantle is contrary to some earlier hypotheses of shearing within the low velocity zone in response to continental plate movement, but is consistent with mantle diapir models.