Published online by Cambridge University Press: 24 October 2008
The phenomena which limit saturation in a high pressure ionisation chamber are examined with particular reference to the rôle played by preferential recombination. The complexity of the phenomena is discussed in detail in order to bring out the scope and limitations of the simple theory of preferential recombination and the conditions which a more complete theory would have to satisfy. It is pointed out that in a number of recent papers on the subject fundamental aspects of the problem have been overlooked, and the significance of these omissions is discussed.
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∥ Ordinary recombination is here defined as the recombination that occurs when the ions have become distributed at random.
¶ Preferential recombination is here defined as recombination between an ejected electron (or negative ion if it has become one) and its parent positive ion.
** Initial recombination is the recombination that occurs when the ions are still distributed in a more or less columnar form, i.e. when there are localised regions of ionic concentration greater than the mean for a large volume of the gas. Initial recombination will, however, henceforward be taken to exclude that form of it which is preferential recombination.
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‡ It should be mentioned that the interpretation of experimental results is often rendered unnecessarily difficult by authors neglecting to mention either the applied field or the magnitude of the ionisation—or sometimes even both. The ratio of ionisation to ionisation current does not of course depend on the magnitude of the ionisation when only preferential and initial recombination limit the ionisation current (unless the ionisation is very large), but when ordinary recombination plays a part the ratio does depend on the magnitude of the ionisation.
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