In a paper communicated to the Royal Irish Academy in 1841, I gave an account of a large number of experiments on the heat disengaged when acids and bases, taken in the state of dilute solution, enter into combination, and when bases, insoluble in water, are dissolved in dilute acids. The following general conclusions or laws were deduced from those experiments:—
Law 1.—The heat developed in the union of acids and bases is determined by the base and not by the acid, the same base producing, when combined with an equivalent of different acids, nearly the same quantity of heat; but different bases, different quantities.
Law 2.—When a neutral is converted into an acid salt, by combining with one or more atoms of acid, no change of temperature occurs.
Law 3.—When a neutral is converted into a basic salt, by combining with an additional proportion of base, the combination is accompanied with the evolution of heat.