The amount of K fixed in K- and Ca-saturated montmorillonite, vermiculite (trioctahedral), rectorite-type and IMII-ordered mica/montmorillonites was measured as a function of time (1–64 days), temperature (25o-300°C), pH (6.0, 9.7, and 10.7), and K-concentration (0.02 and 1.0 M) in solution. The amount of K fixed by the clays generally increased with increasing temperature, pH, and K-concentration and reached saturation in response to each experimental condition in 5 or 6 days. The K-montmorillonite and K-vermiculite fixed considerable amounts of K even at 25°C. Fixed K in montmorillonite increased with an increase of the layer charge which is also influenced significantly by the interlayer cation. In detail, the behavior in K-fixation was specific to each clay.

The type of structural transformation with K-fixation was different for each clay. In montmorillonite, especially, the type of transformation was related to the cationic composition of the system; in K homoionic system, montmorillonite transformed rapidly into illite/montmorillonite with about 40% expandable layers at 300°C and in a mixed cation system with Ca and K, it reacted gradually to random illite/montmorillonites with increasing temperature. These data indicate that the cation-exchange process of a natural pore solution plays an important role in the gradual transformation of detrital montmorillonite to illite.

Well-characterized American Petroleum Institute clay standards, source clays from The Clay Minerals Society, and other secondary minerals were used to determine the effects of U concentration, temperature, and solution composition on U-sorption properties. Uranium concentrations ranged from about 1.00 × 10−4 M to 4.00 × 10−7 M, temperatures from 5° to 65°C and solution compositions containing 0.01 M NaCl and 0.01 M NaHCO3. Silica gel efficiently sorbed uranyl carbonate anion complexes. The higher cation-exchange capacity materials most readily sorbed uranyl ions from the 0.01 M NaCl solution. Temperature increases tended to affect uranyl ion sorption adversely except when the U was present as carbonate complexes. Noncrystalline ferric oxyhydroxides sorbed uranyl ions much more efficiently than any of the secondary crystalline minerals studied. A method for accurately extrapolating U-sorption efficiencies between experimental points based on the Freundlich equation is presented.

Mineralogical and chemical analyses of fine clay fractions from in and around Lake Abert, Lake County, Oregon, show that the pyroclastic rocks supplying detritus to the lake weather to a suite of layer silicate clay minerals varying from high-charge dioctahedral montmorillonite to montmorillonite/intergrade smectite-chlorite interstratifications. In the lake these clays extract K, Mg, and Si to form authigenic interstratified illite and a trioctahedral, Mg-rich mineral resembling stevensite in composition. Both the neoformed interstratifications contribute little unambiguously to X-ray powder diffraction patterns, which are dominated by the reflections of detrital clays. From limited data it appears that the illite occurs below 0.8 m depth in sediments of a possibly somewhat fresher (brackish) lake and the trioctahedral interstratification between 0.4 and 0.2 m depth in sediments of a lake of about the same size and salinity (about 30–90 g/kg) as that of the present lake.

Saponite crystallizes from amorphous gel having an ideal saponite composition within 7 days at all experimental temperatures between 300° and 550°C at 1 kbar pressure. Reactions subsequent to this initial crystallization vary in type and degree, depending on the temperature of reaction and the type of interlayer cation. Above 450°C, the intitially crystallized K-saponite dissolves, and talc and phlogopite nucleate and grow as discrete phases. At 450°C the initial K-saponite reacts to form talc and phlogopite layers, but the reaction proceeds via intracrystalline layer transformations rather than via dissolution and precipitation, producing a mixture of fully ordered, interstratified talc/saponite and fully ordered saponite/phlogopite. The K-saponite shows subtle signs of reaction at 400°C after 200 days: this temperature is at least 150°C lower than experimental reaction temperatures previously reported for saponites. No reactions beyond the initial crystallization of saponite were observed below 400°C. K-saponite reacts more rapidly than either Na-saponite or Ca-saponite above 400°C, and the Na-saponite and Ca-saponite produce no mica layers during their transformation to mixed-layer clays. Interstratified talc/saponite formed in the Na-saponite system, and the Ca-saponite system produced both talc/saponite and chlorite/saponite.

The thermal transformation of a Brazilian antigorite heated dry from 600° to 1300°C, was studied by high resolution electron microscopy and selected area electron diffraction (SAD). Below 600°C, the antigorite particles did not change morphologically or crystallographically, as evidence by the presence of the superlattice in the SAD patterns and lattice images. At 650°C, traces of antigorite remained, although the superlattice structure had disappeared and the first indications of forsterite formation were observed in the same SAD. Diffraction patterns of the transition phases showed various topotactical relationships between antigorite and forsterite. At 800°C, the crystallization to forsterite was much more pronounced. At 900°C, the individual particles retained their original shapes, but they were actually pseudomorphs, for their SAD patterns showed only forsterite. Between 1000° and 1300°C various topotactical relationships were observed. Although the overall transformation to forsterite appears to be similar for both chrysotile and antigorite, the transformation of antigorite took place at a slightly higher temperature (~50°C) with a larger number of topotactical relationships than for chrysotile. Enstatite was formed at 1300°C, but it was impossible to determine the topotactic relations between enstatite and forsterite, which was possible with chrysotile.

A complete conversion series for mica/smectites was found in a hydrothermal alteration envelope around Kuroko-type ore deposits at the Shinzan area, Akita Prefecture, Northeast Japan. The minerals are an alteration product of volcanic glass of Miocene age and are commonly associated with zeolites and silica minerals. Degrees of ordering of interstratification of the minerals change discontinuously from Reichweite g = 0 (100–55% expandable layers) to g = 1 (45–20% expandable layers), and from g = 1 to g = 2 (<20% expandable layers). This pattern of conversion differs from the behavior of mica/smectites during burial diagenesis which undergo a continuous change in ordering type, and from the behavior of rectorite which displays a constant expandability and ordering (45–55%) over a wide range of conditions. Differences between these minerals were also found in the relationships between expandability and total layer charge, and between expandability and number of non-exchangeable interlayer cations. In mica/smectites from the Shinzan area, chemical changes in the interlayers and tetrahedral and octahedral sites are consistent with a reaction in which K-enrichment and K-fixation in the interlayers are controlled by an increase in negative layer charge. This conversion occurred in response to a steep geothermal gradient and migrating hydrothermal solutions.

To test the hypothesis that berthierine in oolitic ironstones formed by diagenetic transformation of detrital kaolinite, laboratory experiments simulating the early diagenetic conditions were conducted. Representative sets of the initial sediment were prepared in distilled water and artificial seawater suspensions by mixing 4–13 g/liter kaolinite with Fe(OH)3 precipitated from 0.1-0.3 M FeCl3 solutions. Na2S2O4 was added to the suspensions as a reducing agent, and inert N2 atmospheres were used to maintain the required Eh between +100 and -400 mV. The pH of the suspensions was controlled between 8 and 5 with dilute HCl. Within 300 days, the iron content of the bulk kaolinite in the seawater suspensions progressively increased from 0.18 to 2.44% at pH = 7 and Eh between -250 and -350 mV. Energy dispersive X-ray analyses of individual clay platelets in the final products showed progressive, temporal increase in Fe, and concomitant decrease in Al and Si. X-ray powder diffractometry revealed small d(001)-d(002) shifts, marked intensity reversals o. (001) an. (002) reflections, and the development of additional characteristic berthierine reflections with time. These data suggest progressive transformation of kaolinite to berthierine. Microprobe analyses of natural berthierine in oolitic ironstones also showed parallel patterns, which substantiate such progressive transformation from the margin toward the core of the ooids. The transformation did not take place in distilled water. The addition of Mg2+ to the distilled water suspensions, however, promoted the transformation.

Radium sorption efficiencies as a function of temperature, Ra concentration, and secondary mineral sorbate were determined in a 0.01 M NaCl solution. Radium sorption on a characterized clinoptilolite, montmorillonite, nontronite, opal, silica gel, illite, kaolinite, and glauconite under comparable experimental conditions allowed determination of Ra sorption efficiency curves for each, through use of Freundlich constants, over the same temperature and initial Ra solution concentration range. Similar sorption data for U on the same secondary minerals over the same temperatures allowed comparison of sorption efficiencies for Ra and U. Clinoptilolite, illite, and nontronite were the most efficient Ra sorbents, while opal and silica gel were the poorest Ra sorbents. Generally, Ra sorption on secondary minerals was much greater than U sorption under the same experimental conditions.

Spherical kaolinite has been synthesized for the first time from noncrystalline aluminosilicate material in hydrothermal experiments conducted between 150° and 250°C and under autogenous vapor pressure. Spherules, whose mean diameters depended on growth conditions (0.1–0.6 μm), were formed surrounding the noncrystalline aluminosilicate in all products of 150° and 200°C runs and coexisted with platy or lath-shaped kaolinite in the products of 250°C runs. The estimated percentages of spherules in the products increased from about 1% in the 150°C-15 days product to about 74% in 200°C-8 days product, and decreased from about 21% in 250°C-2 days product to 0% in 250°C-8 days product. Lattice images by high-resolution electron microscope indicated that the spherules consisted of nearly concentric stackings of layers with a unit spacing of 7Å, which were sectored by radiating boundaries. The mean chemical composition of the spherules (Al2O3/SiO2 = 0.58) analyzed by the analytical electron microscope is similar to that of kaolinite (Al2O3/SiO2 = 0.5). Even in the case of the product abundant in spherule (200°C-8 days), X-ray powder diffraction patterns of the wetted products, e.g., of the 200°C-8 day run, showed the 7.14-Å (001) reflection of kaolinite. The 020 reflection was broad, indicating the existence of abundant (001) layer displacements. The b axis (8.94 Å) were within the kaolinite range (8.93–8.94 Å). No infrared absorption peaks were observed at 3550 cm−1 which would correspond to halloysite. The differential thermal analysis slope ratios of the endothermic peak at about 550°C (1.4–2.3) were in the kaolinite range (0.78–2.39).

Infrared (IR) spectra in the fundamental and near-IR regions were obtained for Na-saturated Wyoming montmorillonite and reduced-charge Na/Li-saturated Wyoming montmorillonites hydrated under water vapor at 50% RH and dehydrated under vacuum. For the Na-montmorillonite, changes in the intensities of the structural OH-bending modes, particularly that of the MgAlOH group, were observed as the clay was dehydrated. This result was interpreted as evidence that exchangeable Na ions lose solvation water and settle into the ditrigonal cavities on the clay surface as it becomes desiccated. For the Na/Li-montmorillonites, the structural OH-bending modes also decreased in IR intensity because of Li+ migration into the octahedral sheet. The fundamental IR spectra of D2O adsorbed by the montmorillonites showed characteristic absorptions at 2685, 2510, 2400, and 1205 cm-1 that decreased in intensity proportionally to the cation-exchange capacity. This result, along with corroborating data from X-ray powder diffractograms and from near-IR diffuse reflectance spectra of H2O adsorbed by the clays, suggest that the exchangeable cations on Na-montmorillonite dissociated from the clay surface as it hydrated and played a significant role in organizing the structure of adsorbed water at low water contents.

Twenty-nine chlorites, seventeen lithium-free micas, and twenty-two lithium-bearing micas from diverse localities have been studied by X-ray diffraction, microprobe, and optical second harmonic generation (SHG) techniques to determine which are noncentric and the cause of acentricity. Manandonite (B-rich chlorite) and cookeite, both crystallizing in the Ia form, are acentric. Sudoite-IIb gave a questionable SHG signal, possibly indicating acentricity. All other chlorites gave null signals. Bityite, a Li, Be mica similar to margarite, was determined from the positive SHG response to be acentric. It crystallizes in the 2M1 form and, by analogy to margarite, is ordered tetrahedrally in subgroup symmetry, Cc. Masutomilite-1M and “cryophyllite“-1M (a zinnwaldite high in Al and Si, but low in Fe) are acentric and most probably crystallize in space group C2, thus allowing a noncentric octahedral ordering pattern. Lepidolites showed a diversity in SHG response with only a few being acentric; a lepidolite-1M from Mesagrande, California, a lepidolite-3T from Windhuk, South West Africa, and a lepidolite-2M2 from Nagatare, Japan, gave positive SHG responses. The Japanese material is complexly intergrown and twinned, and intergrain reflection or refraction may have produced spurious signals.

Most lithium-free micas showed diversity in SHG response and, although most were non-emitters, clintonite from Amity, New York, showed a positive response, but this sample is twinned and shows stacking disorder. A “manganophyllite”-1M (manganoan phlogopite) from Langban, Sweden, showed a very weak positive response; however, the presence of Mn alone is not suffcient to produce octahedral cation ordering in noncentric subgroup symmetry. Two manganoan phlogopites from Japan were refined in subgroup symmetry, and the higher order and ideal symmetry of C2/m was confirmed.

Clays may catalyze chemical reactions by acting as Brönsted acids, Lewis acids, and/or Lewis bases. The changes occurring when limonene (p-menthadiene) is heated in the presence of montmorillonite illustrate how Brönsted and Lewis acidity may operate competitively, the nature of the interlayer cations determining which reaction dominates. The rate at which the starting material disappears increases with the acidity of the clay, which depends upon the interlayer cations (Na < Mg < Al < H). The concentration of disproportionation and isomerization products reaches a maximum after reaction times which decrease with increasing surface acidity of the clay, p-cymene is produced by oxidation in concentrations inversely related to the surface acidity of the clay. The course of the chemical reaction can thus be steered in the preferred direction by an appropriate choice of interlayer cations.

A 14-Å mineral coexisting with kaolin minerals, mica, and gibbsite in a Korean Ultisol and showing X-ray powder diffraction features of “chloritized” vermiculite was studied by a combination of methods. The 14-Å mineral collapsed on saturation with K+ after extraction with hot 1/3 M sodium citrate, but the Si/Al ratio of the extracted material was close to 1.0 and kaolin minerals dissolved, as indicated by difference infrared spectroscopy. The 14-Å mineral was also collapsed by heating at or above 350°C. The difference infrared spectra and the X-ray powder diffraction patterns indicated that two forms of kaolin mineral are present that differ in thermal stability; one decomposed by heating at or below 375°C and the other by heating above 375°C. The former kaolin mineral is probably associated with vermiculite and the latter is present as a discrete form. The 14-Å mineral was inferred to be an intergradient vermiculite-kaolin mineral, in which most vermiculite layers each partially transform into double kaolin layers, and to represent an intermediate phase during the transformation of 2:1 to 1:1 layer silicates in acid soils.

The sorption of U and Ra on finely ground biotite, muscovite, and phlogopite was adequately described by the Freundlich adsorption equation, (x/m) = KCn, at low U and Ra concentrations despite Ra precipitation at the higher temperature. Radium and U sorption-efficiency curves derived from the Freundlich constants generally showed decreased distribution coefficients in response to increasing temperature and increasing Ra or U concentrations. Temperatures investigated were 5°C, 25°C, and 65°C. Solution compositions used were 0.1 M NaCl and 0.01 M NaHCO, for U, and 0.01 M NaCl for Ra. Uranium initial solution concentrations ranged from 1.00 × 10−4 M to 4.00 × 10−7 M; the Ra initial solution concentration range was 6.80 × 10−7 M to 8.60 × 10−9 M.

In 0.01 M NaHCO3 solutions, anionic uranyl carbonate complexes were prevalent, and because they are weakly sorbed relative to free uranyl ion and uranyl hydroxy complexes, the result was a relatively low U sorption efficiency on biotite and phlogopite and excellent sorption efficiency on muscovite. Uranyl carbonate complexes decreased in solubility with increasing temperature, so that U sorption efficiency on biotite increased with increasing temperature. Sorption of uranyl ion and uranyl hydroxy cations on biotite decreased with incresaing temperature.

X-ray diffraction, infrared, and cation-exchange capacity measurements of the reaction products of montmorillonites with YbCl3.6H2O show that at 1 atm irreversible sorption of Yb3+ increases with increasing temperature in the range 20° to 280°C, whereas at 110 atm it decreases with increasing temperature. Above 100°C, less irreversible sorption occurs at 110 atm than at 1 atm. The decreased sorption at high pressure is attributed to reduced cation hydrolytic fixation and to rapid expulsion of interlayer Yb3+ by interlayer water at higher temperatures, with a concomitant decrease in Yb3+ migration to octahedral sites. At 110 atm, 160° and 200°C treatments cause changes in infrared absorption bands (884 cm-1, 848 cm-1) suggesting that sorbed Yb3+ is charge compensated by the deprotonation of Fe3+- and Mg2+-hydroxyl groups. At 290°C deprotonation is restricted to Fe3+-hydroxyl groups.

The crystal structure of a magnesian cronstedtite-2H2 from Pribram, Czechoslovakia, was refined in space group C1 to a residual of 5.4% with 1832 independent reflections. Tetrahedral ordering between Fe3+ and Si is judged to be complete on the basis of electron density maps, the first confirmation of such ordering in a layer silicate. Octahedral cations are disordered on the M sites. Mean T-O bond lengths do not confirm the tetrahedral ordering, perhaps due to tetrahedral distortion in order to relieve the extreme corrugation of the sheet that would arise from ordering of such different size cations.

In the initial stages of refinement the structure of the crystal under study could not be described adequately on the basis of a single 2H2 polytype. The structure contains two kinds of 2H2 domains that appear shifted by b/3 relative to one another due to a mistake in the interlayer stacking sequence. This mistake of zero shift (the normal 2H2 polytype consists of alternating —b/3 and +b/3 shifts) affects only the tetrahedral sheets. It creates adjacent enantiomorphic domains of 2H2 packets such that domains with small Si tetrahedra sit above larger Fe3+-rich tetrahedra and vice versa. This mechanism to relieve strain may indeed be the cause of the stacking mistakes. A third kind of domain contains regions in which the sense of tetrahedral rotation is reversed, giving rise to split basal oxygens on electron density maps. This multiple domain model best explains extra atomic positions observed on Fourier maps, lack of streaking of k ≠ 3n reflections, and possible nonintegral “satellitic” reflections observed on Weissenberg films.

Sedimentologic zones that are differentiated by changes in lithology, mineralogy, chemical composition, and crystal morphology observable in scanning electron micrographs occur in Missouri high-alumina clay deposits. These properties and changes suggest that the high-alumina materials originated from Pennsylvanian-age, paludal sediments deposited in depressions underlying Paleozoic carbonate rocks. Alumina was relatively enriched in zones of the deposits by leaching of silica and of alkali and alkaline earth metals from the sediments. The most intense leaching occurred on the highest parts of the Ozark Dome.

Diaspore is the predominant high-alumina mineral. Boehmite, although far less abundant than diapsore, may have paragenetically preceded diaspore in some deposits. Chlorite, presumably an Al-rich variety because the content of MgO is typically <0.5%, is also present. Li, which is sporadically present, is inferred to have accumulated in the chlorite which may be a proto-variety of cookeite. Because Li+ and Al3+ are similar in size, Li is inferred to have accompanied Al as a resistate element in contrast to K and Na which were leached from parent phyllosilicates.

Smectites exchanged to various degrees with mono- or biprotonated 1,4-diazobicyclo(2,2,2)-octane (Dabco) have a porous structure in which the organic molecule acts as a “pillar.” Less Dabco2+ than Dabco1+ was necessary both to initiate and to complete expansion, whereas for both Dabco1+ and Dabco2+ the threshold for expansion increased with the charge density of the clay. Interstratification of 9.7-Å and 14.5-Å (Dabco1+) or 14.1-Å (Dabco2+) layers was observed before full expansion occurred.

Nitrogen sorption isotherms on partially exchanged Dabco1+- and Dabco2+-clays are of the BET II and Langmuir type respectively, whereas n-butane adsorbed according to BET type II for both cationic forms. The specific surface area was governed by the number of Dabcoz+ pillars, irrespective of the inorganic cation, and increased with Dabcoz+ content even beyond the composition where full expansion was reached and notwithstanding the increasing number of silicate layers in the c direction of the crystal units. This relationship is explained by an enhanced random interleaving of clay platelets in the stacking units containing Dabcoz+.

Mineralogical and 57Fe Mössbauer spectroscopic analyses were made on seven terrae rossae and two terrae fuscae samples of Pliocene to Early Pleistocene age from Slovakia and limestone residues from their parent materials. In most of the samples, no mineral weathering or clay mineral formation could be detected by optical or X-ray powder diffraction investigation, compared with their parent limestone residues; only one terra rossa showed a strong weathering of primary feldspar and phyllosilicates and a high rate of clay formation, especially kaolinite. Mössbauer measurements between 5° and 300°K showed that hematite and goethite are the dominant color pigments in the rubified terrae rossae and their corresponding limestone residues. The mean particle size of hematite and goethite was estimated from Mössbauer effects and X-ray powder diffraction data to be 95 and 250 Å, respectively. Reduced values of the hyperfine fields at 5°K of the soil iron oxides, as compared with those of the pure oxides, indicate a partial substitution of Fe(III) by Al. The hematite content correlates with the Munsell color notation of 5 of the 7 terrae rossae samples and their corresponding limestone residues. All terrae rossae samples showed higher hematite contents than their corresponding limestone residues, indicating that the rubification of such materials is independent of the degree of weathering.

Smectite with polyvalent cations on the exchange complex readily absorbed riboflavin from aqueous solution to a limit of about 0.5 mmole/g. The shape of the adsorption isotherms was of the Langmuir type. An exception was Na+-smectite which provided an S-shaped isotherm and smaller amounts of adsorption. Ca2+-vermiculite had no interlamellar adsorption of riboflavin, suggesting that this mineral does not swell sufficiently to permit such adsorption. Adsorption isotherms, X-ray powder diffraction data, and UV-visible spectroscopic data suggest that the mechanisms of interaction between smectite and riboflavin may involve a combination of ion-dipole, charge transfer, hydrogen bonding, and physical effects.