X-ray diffraction has been used to study the sorption of water by multilayer films containing ordered stacks of alternating layers of an organic polyelectrolyte and individual platelets of a smectite. The position and shape of the 001 reflections due to the ordered polyelectrolyte/platelet stacks were essentially the same when in air at low relative humidity (23–25% RH) and under water. These data indicate that swelling occurs exclusively in X-ray amorphous regions within the film, and that the ordered polyelectrolyte/clay domains themselves are not ‘swellable’ by water.

In order to solve the problems of low power transfer efficiency (PTE) and limited distance in magnetic coupling resonant wireless power transfer (MCR-WPT) technology. In this paper, based on the magnetic field control ability of metamaterials (MMs), the way to improve the performance of MCR-WPT systems is studied. First, the influence of MMs on the coupling of MCR-WPT system is theoretically analyzed by establishing an equivalent circuit model. Through a series of simulations and experiments, the relationships between the PTE and the array and placement of the MM slab are investigated. The results demonstrate that when one MM slab is placed in the middle, near the Tx coil or the Rx coil, the optimal PTE can be obtained by inserting one slab with $6 \times 6$, $1 \times 1$, and $6 \times 6$ arrays, respectively. Moreover, the systems with multilayer MM slabs are also studied. The measured PTEs on one, two, and three layers of MM slabs can increase by 20.6%, 29.3%, and 22.6%, respectively. The efficiency improvement capability of one MM slab is better than three slabs but worse than two slabs. This paper discusses the application of MMs in MCR-WPT systems, which has a certain reference significance.

This study presents the optical properties of layered ZnO/Al/ZnO composite thin films that are being explored for potential applications in solar cells and light emitting devices. The composite thin films are explored as alternatives to ZnO thin films. They are produced via radio frequency magnetron sputtering. The study clarifies the role of the aluminum mid-layer in a ZnO (25 nm)/Al/ZnO (25 nm) film structure. Multilayers with low resistivity ∼362 µΩ cm and average transmittances between ∼85 and 90% (in the visible region of the solar spectrum) are produced. The highest Haacke figure of merit of 4.72 × 10−3 Ω−1 was obtained in a multilayer with mid-layer Al thickness of 8 nm. The combined optical band gap energy of the multilayered films increased by ∼0.60 eV for mid-layer Al thicknesses between ∼1 and 10 nm. The observed shifts in the optical absorption edges to shorter wave lengths of the spectrum are shown to be in agreement with the Moss–Burstein effect.

The biaxial stress and thermal expansion of multilayer doped-aluminosilicate environmental barrier coatings were measured in situ during cooling using microfocused high-energy X-rays in transmission. Coating stresses during cooling from 1000 °C were measured for as-sprayed and thermally cycled samples. In the as-sprayed state, tensile stresses as high as 75 MPa were measured in the doped-aluminosilicate topcoat at 375 °C, after which a drop in the stress occurred accompanied by through-thickness cracking of the two outermost layers. After thermally cycling the samples, the stress in the topcoat was reduced to approximately 50 MPa, and there was no drop in stress upon cooling. This stress reduction was attributed to a crystallographic phase transformation of the topcoat and the accompanying change in thermal expansion coefficient. The addition of a doped aluminosilicate to the mullite layer did not lower the stress in the topcoat, but may offer increased durability due to an increased compressive stress.

The study of nonlinear dynamic behavior of laminate composed of steel and rubber layersalso referred as “Shim”, used for vibro-acoustic insulation in brake system, isinvestigated. The simulation of the vibro-acoustic nonlinear behavior of Shim depending onfrequency, taking into account the large deformations and various nonlinearhyper-viscoelastic laws of rubber are considered. This paper presents a solution tocontribute in the identification of the best design of Shim in terms of damping vibrationof brake systems, using analytical and numerical method. The choice of the best structuredepends essentially on the nature of rubber, on the stacking sequence of materials, ontheir thickness, on the number of layers and on volume fraction of rubber. An analyticalstudy, with the use of the transfer matrix method is presented. A model on the finiteelement software ANSYS is constructed. The results lead to conclusions about the beststructure and design of Shim in term of vibro-acoustic insulation.

Magnetic structures of Co/Cu multilayers in cross section are observed by two kinds of electron holography: a Fourier method and a phase-shifting method, which is introduced briefly. The Fourier method can easily reconstruct wave functions and is applied to many specimens, whereas the phase-shifting method requires longer time for processing, but has a higher spatial resolution that permits us to discuss fine structures. Magnetization vectors in Co layers aligning parallel and separating into two blocks with antiparallel alignment are observed. Magnetic blurring on the boundary between Co and Cu in the reconstructed phase images is larger than the estimated atomic roughness.

The depth profile of thin film layers on bulk substrate, avoiding the cross-sectioning of samples, is commonly performed by techniques such as X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES), and secondary ion mass spectroscopy (SIMS). Techniques based on X-ray emission intensity measurements by energy dispersive spectroscopy (EDS), with conventional matrix or ZAF correction, are normally applied to cross-sectioned samples. This article compares XPS with surface X-ray intensity measurements by EDS, carried out with a more realistic X-ray generation and absorption model, known as the ϕ(ρ Z) model. The ϕ(ρ Z) approach has been adopted together with Monte Carlo simulation for the proper selection of SEM accelerating voltages, in conjunction with the analysis of SEM morphological images for thin film density correction. The method discussed hereafter and compared with the XPS technique, has advantages of higher lateral resolution, non-destructive elemental analyses, morphological visualization, low cost, and faster performance. This methodology has been followed to verify the layered structure of SnO2/metal-based gas sensors. X-ray intensities were measured using an EDS ultra-thin window detector. Two different porous layers, 25-nm thick of SnO2 and 10-nm thick of Cu, were detected, showing better agreement with their nominal thickness compared to results obtained using XPS measurements where porosity affects XPS data. If confirmed to be reliable and as effective as XPS depth profiling, this technique may be adopted for process quality control purposes.

A technique has been developed for the interpretation of composition-depth profiles from angleresolved X-ray data using a Monte Carlo electron scattering simulation. This is a nondestructive depth profiling procedure. Software has been developed that uses a Monte Carlo scattering simulation to generate the signal intensity from a multilayer sample for any combination of primary beam angle of incidence and take-off angle to the X-ray detector. An interactive C++ application uses this simulation to interpret measured angle-resolved depth profiles. The method has been tested using a custom-made Ag/Al “staircase” sample containing two layers each of Ag and Al. Using the technique, it is possible to quantify the composition-depth profile for the two- and three-layer “steps” of the sample. Qualitative information may be gained about the four-layer area of the sample.

In order to study the plasticity in Cu-Ni multilayers deposited on single crystals of Cu and etched Si, we have investigated the mechanical properties of the multilayers both by nanoindentation measurements, and by the transmission of well characterized dislocations from the underlying substrate by tensile deformation of Cu single crystals.

Various multilayers were deposited by physical vapor deposition with layer thicknesses varying between 1000 and 20 Angstroms (for a total thickness between 0.8 and 1 μm). Two types of experiments were designed. The first one aimed at injecting, in a controlled way, some dislocations from the substrate into the multilayers; the second type of experiment concerned the structure of the multilayer surface after having plastically pushed the material away from a nanoindenter.

This communication reports the results from the nanoindentation measurements, as well as the observations of slip on the surface. We observed through the injection of dislocations by nanoindentation that the multilayers increase in strength with refinement of the layer structure but at thicknesses below 35Å exhibits a softening behaviour. Also observation of the upheaval around the nanoindent showed an evolution from slip lines to more spread plasticity with refinement of the layer structure.