A systematic study, using ion trap time-of-flight mass spectrometry, is presented for the photo-dissociation processes of Bisanthenquinone (Bq) cations, C28H12O2+, a ketone substituted Polycyclic Aromatic Hydrocarbon (PAH). The Bq cation fragments through sequential loss of the two neutral carbonyl (CO) units upon laser (626nm) irradiation, resulting in a PAH-like derivative C26H12+. Upon further irradiation, C26H12+ exhibits both stepwise dehydrogenation and C2/C2H2 loss fragmentation channels. Quantum chemistry calculations reveal a detailed picture for the first CO-loss, which involves a transition state with a barrier of ∼ 3.4 eV, which is lower than the energy required for the lowest H-loss pathway (∼ 5.0 eV). The barrier for the second CO-loss is higher (∼ 4.9 eV). The subsequent loss of this unit changes the Bq geometry from a planar to a bent one. It is concluded that the photodissociation mechanism of the substituted PAH cations studied here is site selective in the substituted subunit. This work also shows that an acetone substituted PAH cation is not photo-stable upon irradiation.

A ns Nd:Yag laser, at intensity of 1010 W/cm2 is employed to generate carbon and aluminum non-equilibrium plasmas at a temperature of about 33 eV accelerating ions at energies of the order of 130 eV per charge state. The ion emission occurs manly along the normal to the target surface and can be detected using ion collectors employed in time-of-flight configuration. The application of magnetic field along the axe of the ion emission permits to focalize the ion emission enhancing the detected ion current. The formation of electron traps, due to the magnetic force lines, drives the ion acceleration improving their kinetic energy. Different applications can make use of these results to increase the flow of charged particles and their energy employing appropriate static magnetic fields, as it will be presented and discussed.