The effect of heating on montmorillonites containing exchangeable Na and K has been studied by X-ray photoelectron spectroscopy (XPS). The surface composition of the unheated montmorillonite was consistent with the bulk composition, but after the sample recrystallized at 1100°C, the surface abundance of Na increased, whereas that of K decreased. Because Na and K were not present in the high-temperature crystalline products, this behavior suggests that a noncrystalline material separated from the crystalline products. The Na 1s binding energy and KL23L23 Auger kinetic energy of montmorillonite were comparable with those of Na in typically ionic compound, such as NaCl. These electron energies became smaller and larger, respectively, on heating and approached those of feldspar (albite). The K 2p3/2 binding energy of montmorillonite increased slightly on heating. The K 2p3/2 binding energy of heated sample of montmorillonite was also comparable with that of feldspar (orthoclase). These results suggest that Na and K were incorporated into feldspar-like noncrystalline materials.

Cathodoluminescence (CL) provides a sensitive analytical probe of the near-surface region of insulating materials, and some new examples of the strengths of the technique are presented using recent data from the University of Sussex. Analysis of float glass shows that by spectral and lifetime resolved data it is possible to separate the emission bands from excitonic, intrinsic imperfections, and impurities in various valence states, as a function of their depth beneath the surface. Correlation of the CL data with those from Mössbauer, ion beam and other analyses then provides the basis for models of the defect sites. CL from a second glass, ZBLAN, reveals the presence of microcrystallites and growth defects, and the work underpins confidence in the high purity gas levitation method of ZBLAN production. New results on CL of wavelength shifts with crystal field of Mn in carbonates are presented, and of Nd emission from Nd:YAG. The effects are directly linked to surface damage and dislocations caused by sample preparation steps of cutting and polishing. Methods to minimise the damage, by furnace or pulsed laser annealing, and chemical routes, are mentioned. Such surface preparation damage has a profound effect on all CL monitoring, whether for fundamental studies or mineralogical applications. Finally, a route to eliminate such problems is demonstrated, with consequent improvements in luminescence, transmission and laser performance of surface waveguides. The implications of improved surface quality range widely from mineralogical CL imaging through improved photonic materials and epitaxial growth to elimination of surface damage, and additional information.

Recent observations in visible photometry have provided B, V, R and I high quality colors for more than 130 objects. Color diversity is now a reality in the TNOs population. Relevant statistical analyses have been performed and all possible correlations between optical colors and orbital parameters have been analyzed. A taxonomy scheme based on multivariate statistical analysis of a subsample of 51 objects described by the 4 color indices (B-V, V-R, V-I and V-J) has been obtained. A tentative interpretation of the obtained groups in terms of surface characteristics is given. Moreover, an extension of this taxonomy to the other 84 objects for which only three colors indices (B-V, V-R, and V-I) are available, is also presented.

The faintness of these objects limits the spectroscopic observations. Despite this, our group provided visible and infrared spectra for 18 objects using the Very Large Telescope (ESO, Paranal, Chile). The wavelength region ranging 0.4–2.3 microns encompasses diagnostic spectral features to investigate organic compounds, minerals and ices present on the surface of the TNOs. The investigation of the surface variation can be an identifier of possible composition diversity and/or different evolution with different physical processes affecting the surface.

The current knowledge of the surface properties and composition of the population will be presented, analyzed and interpreted.