Woolly erionite from the Reese River deposit, Nevada, is identical in appearance to that at the type locality, near Durkee, Oregon. Both of these erionites differ in appearance from all other erionite reported in the past 20 years from diverse rocks throughout the world which are described as prismatic or acicular in habit. The non-woolly erionites are especially common as microscopic crystals in diagenetically altered vitroclastic lacustrine deposits of Cenozoic age. The Reese River woolly erionite fills joints in gray to brownish-gray lacustrine mudstone of probably Pliocene age, in a zone about 1 m thick beneath a conspicuous gray vitric tuff. Compact masses of long, curly, woolly erionite fibers are in the plane of the joint and locally are associated with opal. Indices of refraction are ω = 1.468 and ε = 1.472; hexagonal unit-cell parameters are a = 13.186(2) Å, c = 15.055(1) Å, and V = 2267.1(0.9) Å3. A chemical analysis of woolly erionite yields a unit-cell composition of: Na1.01K2.84Mg0.3Ca1.69Al8.18Si27.84O72·28.51H2O.

Core cuttings from numerous wells traversing Oligocene through Recent sediments of the Texas Gulf Coast were examined with a scanning electron microscope using the back-scattered electron imaging mode (BSE) to ascertain diagenetic changes in clays and associated minerals of mudrocks and of adjacent sandstones. Several occurrences of authigenic kaolinite and chlorite were noted, each characterized by a specific texture and a specific diagenetic microenvironment. In all occurrences kaolinite appears to have formed before chlorite, and in some the kaolinite appears to have precipitated directly from solution. Chlorite, ubiquitously an iron-rich variety, appears to have precipitated in some places directly from solution. It has also been noted pseudomorphous after kaolinite. A progressive decrease in the iron content of mixed-layer illite/smectite with increasing depth is believed to have released the necessary iron and to have driven the kaolinite-to-chlorite reaction.

Quaternary debris flows derived from ophiolite melange in northern Southland, New Zealand, are locally cemented and veined by cross-fiber and fine-grained chrysotile. Chrysotile was identified by optical, X-ray powder diffraction, electron microprobe, differential thermal (DTA), and infrared analysis methods. Microprobe and DTA also suggested the presence of as much as 6% of sub-microscopic, noncrystalline alumina, probably in the form of pseudoboehmite. Cavity fillings and irregular veins containing chrysotile are as thick as 40 cm and commonly contain lizardite clasts. Calcite commonly accompanies chrysotile as a vein mineral. Magnetite and pyrite are found near and adjacent to chrysotile veins. These accessory minerals imply that the chrysotile formed under alkaline, reducing conditions. Surface water seepages have pH = 9. Remnant debris-flow topography, Holocene radiocarbon dates, and the absence of hot spring activity confirms that chrysotile can form under near-surface, low-temperature conditions. Growth of chrysotile fibers on a lizardite substrate suggests that the chrysotile formed by solution of detrital lizardite and subsequent precipitation in cavities within the debris flow.

Euhedral, pseudohexagonal nacrite was discovered as a thin layer coating a carbonaceous shale in the Sherwood Tunnel in Durban, Republic of South Africa. The nacrite apparently formed authigenically within a few weeks at ambient temperature by precipitation from pore solutions, probably as a result of evaporation. This observation suggests that nacrite can no longer be considered to indicate a high-temperature genetic environment. Precipitation from saturated pore solution may have been the mechanism of formation for this kaolin-mineral polymorph.

Trioctahedral smectite is a constituent of Mg-rich carbonate crusts and moonmilks (pasty deposits) in caves of the Guadalupe Mountains of southeastern New Mexico. Energy dispersive X-ray microanalysis of individual crystallites and their aggregates along with the X-ray diffraction analysis indicates that the smectite is probably stevensite. Saponite is likely present in some samples also. The smectite is intimately associated with dolomite crusts and huntite moonmilks in Carlsbad Cavern, Lechu-guilla Cave, and other dolostone caves. Clay particles appear as fibers and films, with aggregates comprising decimicron-sized filamentous masses that envelop crystals of dolomite, huntite, and magnesite. The occurrence of smectite is related to the genesis of the Mg-rich carbonate minerals. In water films, progressive evaporation and carbon dioxide loss results in the sequential precipitation of Mg-rich calcite, aragonite, dolomite, huntite, and magnesite. This sequence of carbonate precipitation removes Ca and greatly increases the Mg/Ca ratio in the solutions. Silica is commonly available probably because of high pH conditions, and consequently, smectite forms in the Mg-rich alkaline environment. Along with the Mg-rich carbonate minerals, opal, quartz, and uranyl vanadates may precipitate with the smectite.

The Ypresian phosphatic series of the Gafsa-Metlaoui basin, southwestern Tunisia, is represented by an alternation of phosphatic levels and interbedded facies, which are composed of marly clay and silica-rich rocks. The present work aimed to clarify the genesis of palygorskite and sepiolite of the interbedded facies and to understand the depositional environment of the phosphatic series. The interbedded facies of the Stah and Jellabia mines were investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Energy Dispersive X-ray microanalysis (EDX) of individual constituents and their aggregates. The data obtained indicate that samples are made up of francolite, calcite, dolomite, quartz, feldspars, and clay minerals; the latter consist of palygorskite-sepiolite minerals associated with smectite. Observations by SEM revealed the occurrence of palygorskite and sepiolite as fine and filamentous fibers with thread-like facies and coating dolomite, calcite, and a marly matrix. Such features can be considered as textural evidence of authigenic palygorskite-sepiolite. At the bottom of the Stah section, SEM observations revealed that the fine fibers are more abundant within silica-rich rocks. Silica is commonly available due to bacterial activity saturating its environment with the silicic acid required for the formation of palygorskite-sepiolite. In the interbedded facies of the Jellabia section, the moderate fibrous clay content and the presence of well crystallized dolomite revealed that the shallow-marine water was characterized by high-Mg and low-Si activities.

The terminal Ediacaran Dengying Formation (c. 551.1–538.8 Ma) in South China is one of two successions where Ediacara-type macrofossils are preserved in carbonate facies along with skeletal fossils and bilaterian animal traces. Given the remarkable thickness of carbonate-bearing strata deposited in less than 12.3 million years, the Dengying Formation holds the potential for construction of a relatively continuous chemostratigraphic profile for the terminal Ediacaran Period. In this study, a detailed sedimentological and chemostratigraphic (δ13Ccarb, δ18Ocarb, δ13Corg, δ34Spyrite, and 87Sr/86Sr) investigation was conducted on the Dengying Formation at the Gaojiashan section, Ningqiang County of southern Shaanxi Province, South China. Sedimentological results reveal an overall shallow-marine depositional environment. Carbonate breccia, void-filling botryoidal precipitates and aragonite crystal fans are common in the Algal Dolomite Member of the Dengying Formation, suggesting that peritidal facies were repeatedly karstified. The timing of karstification was likely early, probably soon after the deposition of the dolomite sediments. The presence of authigenic aragonite cements suggests high alkalinity in the terminal Ediacaran ocean. Geochemical analysis of micro-drilled samples shows that distinct compositions are registered in different carbonate phases, which should be considered when constructing chemostratigraphic profiles representative of true temporal variations in seawater chemistry. Integrated chemostratigraphic data suggest enhanced burial of organic carbon and pyrite, and the occurrence of extensive marine anoxia (at least in the Gaojiashan Member). Rapid basinal subsidence and carbonate accumulation during a time of elevated seawater alkalinity and increased rates of pyrite burial may have facilitated the evolutionary innovation of early biomineralizing metazoans.

Quartz-hematite veins in the St. Austell pluton feature an assemblage of authigenic kaolin, illite, chlorite and hematite. Similar assemblages occur in altered granites adjacent to the veins. Complex textures in the veins and altered granites show that kaolin was an initial precipitate from hydrothermal fluids that was subsequently replaced by illite, hematite and chlorite. The sequence of mineral precipitation reflects a kinetic control on crystal growth, with early nonequilibrium precipitation of kaolin from fluids with compositions appropriate for the equilibrium formation of illite. Hematite formed under relatively oxidizing conditions that subsequently became more reducing to permit the late precipitation of chlorite. Illite associated with the quartz-hematite veins differs texturally, mineralogically and chemically from the coarsely crystalline hydrothermal muscovite (sericite or gilbertite) associated with quartz-tourmaline veins and greisen. Quartzhematite veins are thus considered to record a distinct mineralization event that is not related to the early greisenization or the economic kaolinization.