1. Introduction

The rapid development of device quality GaN, InGaN and AlGaN over the past five years has lead to the commercialization of blue and green light emitting diodes, along with demonstrations of violet laser diodes and a variety of electronic devices Reference Ponce[1] Reference Nakamura, Mukai and Senoh[2] Reference Nakamura, Senoh, Iwasa and Nagahama[3] Reference Nakamura, Senoh, Nagahama, Iwasa, Yamada, Matsushita, Sugimoto and Kiyoku[4] Reference Nakamura and Fasol[5] Reference Edmond, Kong, Leonard, Bulman and Negley[6] Reference Akasaki, Sota, Sakai, Tanaka, Koike and Amano[7] Reference Bulman, Doverspike, Sheppard, Weeks, Kong, Dieringer, Edmond, Brown, Swindell and Schetzina[8] Reference Mack, Abare, Aizcorbe, Kozodoy, Keller, Mishra, Coldren and DenBaars[9] Reference Nakamura, Senoh, Nagahama, Iwasa, Yamada, Matsushita, Kiyoku, Sugimoto, Kozaki, Umemoto, Sano and Chocho[10]. In addition, a number of photodetectors based on photoconductive and junction devices have also recently been reported Reference Wickenden, Huang, Brent Mott and Shu[11] Reference Yang, Novova, Krishnankutty, Torreano, McPherson and Marsh[12] Reference Morkoc[13].

This paper reports the first successful demonstration of an ultraviolet (UV) digital camera based on an array of GaN/AlGaN heterostructure p-i-n photodiodes. This visible-blind (32 × 32 pixel) digital imager is designed to sense radiation only in the 320 - 365 nm wavelength band in the UV spectral region. In this paper, a general discussion of photodiode properties is followed by a description of the experimental procedures employed to synthesize, process and study discrete photodiodes and photodiode arrays. This is followed by a discussion of the experimental results obtained.

When fully developed, this new type of UV digital camera may be expected to be used in many wide-ranging applications including welding imagery, flame sensing, biological agent detection, missile and shellfire detection, and in studies of astronomical objects.

2. Properties of Semiconductor Photodiodes

Let us consider a p-n junction or p-i-n junction photodiode operating in the photovoltaic mode at zero bias Reference Chuang[14]. The detector current responsivity R_λ is defined as the output current i_p produced by the detector divided by the diode illumination power P_λ at a given wavelength λ. That is,

where q is the electronic charge, η is the quantum efficiency, h is Planck's constant and ν is the radiation frequency. Note that the responsivity R_λ varies inversely with the optical frequency ν. As a consequence, maximum responsivities (η = 1) in the UV are small — ranging from R_λ = 0.294 A/W at 365 nm to R_λ = 0.161 A/W at 200 nm.

An important figure of merit for a diode detector is the R₀A product, where R₀ is the dynamic resistance of the diode at zero bias and A is the detector area. A large R₀A product is a necessary requirement for the detector to have a large detectivity D^*, that is, to be able to detect very low light levels. Figure 1 shows the spectral detectivity D^* for a number of different commercially-available detectors [15] that operate at wavelengths ranging from 0.2 μm (UV) to 12 μm (IR). It is seen from the figure that IR detectors have D^* values of 10⁷ − 10¹⁰ (cm Hz^1/2W⁻¹) depending on the type of detector, its operating temperature, and the wavelength region for which it is designed. Detectors operating at shorter wavelengths generally have larger D^* values ranging up to D^* = 4 × 10¹⁴ (cm Hz^1/2W⁻¹) for a photomultiplier tube (PMT) operating at about 300 nm.

Figure 1. Spectral detectivities for selected photodetectors.

Figure 1 also shows the curve for an ideal photovoltaic detector limited by thermal background radiation from a 293K radiation source (the earth!!). A detector displaying D^* values that lie along this line is said to be background limited. A Background LImited Photodetector is often referred to as being a BLIP-limited detector, or as being BLIP-limited Reference Chuang[14]. These detectors have the highest possible D^* values for a given wavelength when exposed to the earth's thermal radiation field. Note from the figure, that D^* values for a BLIP-limited detector become extremely large as the wavelength decreases into the UV. This is because a 293K black body radiation background contains virtually no UV radiation, so an extremely sensitive detector is required to be able to be detect this near-zero thermal background from the earth.

The spectral detectivity D^* of a photodiode detector may be expressed as Reference Chuang[14]

The first term in the bracketed quantity above (4kT/R₀A) arises from thermal noise sources within the detector. The second term (2q²ηΦ_b) is due to the background radiation Φ_b to which the detector is exposed. If the detector is limited by thermal noise, that is, if the thermal noise far exceeds the background radiation induced signal, then the detectivity becomes

where k is Boltzmann's constant and T is the absolute temperature. Note that the detectivity D^* is directly proportional to (R₀A)^1/2 when the detector is noise-limited. Thus, to develop very sensitive detectors it is essential that the detector noise sources be minimized so that R₀A is large. In the case of III-V nitrides, the extremely large density of dislocations represents a significant noise source. Therefore, dislocation reduction should have a very positive effect on the detectivity of nitride photodiodes.

If the second term in brackets of equation 2 above dominates, then the background signal determines D*. In this case, the detectivity D^* is BLIP-limited and may be expressed as

The detectivity D^* may also be expressed in terms of the detector noise equivalent power NEP such that Reference Chuang[14]

where A is the detector area and Δf is the detector bandwidth. The noise equivalent power NEP is the power that corresponds to the incident rms optical power required such that the detector signal-to-noise ratio is one in a bandwidth of 1 Hz.

3. Experimental Details

The photodiode structure employed in the present work is shown schematically in Figure 2. It consists of a base layer of n-AlGaN (~20% Al) followed by an undoped GaN layer and a p-GaN layer. The photodiode structure is deposited by MOVPE onto a polished sapphire wafer to permit illumination of the device through the substrate. As shown in the figure, the photodiode responds to UV light in the wavelength band from about 320 nm to 365 nm. At wavelengths shorter than 320 nm, the incoming light is absorbed in the thick AlGaN base layer and the junction is not illuminated. Likewise, the diode does not respond to wavelengths greater than 365 nm, since this corresponds to the optical absorption edge of GaN at 300K. By increasing the Al content of the base layer it is possible to increase the optical bandwidth of the diode's UV responsivity. Likewise, by adding Al to the top layers, it is possible to change the diode UV responsivity band to other wavelength regions in the UV. Thus, UV detectors that sense different UV “colors” are possible.

Figure 2. GaN/AlGaN photodiode structure. At the right, optical absorption spectra obtained for the AlGaN and GaN layers of the device are shown to illustrate the UV responsivity band.

Diode structures of the type shown were prepared by MOVPE both at North Carolina State University (NCSU) and at the Honeywell Technology Center using low-pressure, vertical-flow MOVPE reactors that employ high speed substrate rotation during film growth. The photodiode structures were deposited onto 2 in diameter c-plane sapphire substrates. The growth was initiated by depositing a thin AlN buffer layer at 500-650 °C; all subsequent layers were grown at 1050-1080 °C.

All device processing was completed at NCSU using standard semiconductor processing techniques which included photolithography using appropriately-designed masks, reactive ion etching to define mesa structures, and metallizations to provide ohmic contacts to the n-type and p-type layers of the device.

Spectral responsivity measurements were completed at NCSU on selected discrete photodiodes. In these experiments a xenon lamp was employed as a UV source and the wavelengths were selected by a monochromator. The monocromator output was calibrated using a calibrated UV-enhanced Si photodiode. The 300K dynamic resistance of the photodiode at zero-bias R₀ was measured for selected devices using a shielded low-noise enclosure and shielded probe tips. These measurements were combined with the device area A to obtain the R₀A product. Equation 3 was then used to obtain an estimate of the detector detectivity, D*.

In order to use the GaN/AlGaN photodiodes as the basis for a new visible-blind UV digital camera it is necessary to employ flip-chip bonding techniques to hybridize an appropriately sized photodiode array to a silicon readout integrated circuit (ROIC) as shown in Figure 3. In the present case, NCSU designed and purchased a mask set for a photodiode array that matched a 32 × 32 ROIC chip provided by the Night Vision Laboratory (NVL) at Ft. Belvoir. A fully processed 32 × 32 photodiode array is shown in Figure 4. The array consists of 1024 mesa diodes of area 44 μm × 44 μm on a 53.4 μm pitch. Note from the figure that n-type metal contacts extend between all 32 rows of the array to insure a short current path for each pixel when the photodiode array is illuminated.

Figure 4. Nomarski photographs of a 32 × 32 GaN/AlGaN photodiode array.

Figure 3. Hybridization process for UV digital camera.

The Si ROIC device employed in the hybridization process is shown in Figure 5. Prior to hybridization at NVL, In bumps were deposited onto each of the mesas and n-contact layers of the photodiode array and onto the corresponding areas of the ROIC using NCSU facilities. Each 32 × 32 GaN/AlGaN photodiode array was hybridized to the silicon ROIC using facilities at NVL and then cemented onto a leadless chip carrier. Gold wire bonds were then used to link the various input/output channels from the ROIC to the leadless chip carrier. A closeup of a hybridized UV photodiode array is shown in Figure 6 mounted onto a printed circuit board in preparation for testing.

Figure 5. Nomarski photographs of a 32 × 32 silicon ROIC.

Figure 6. Hybridized GaN/AlGaN UV photodiode array mounted on PC board prior to testing .

The experimental setup at NVL that was used for testing the GaN/AlGaN UV FPA is shown in Figure 7. It consists of an alpha-numeric UV source, a quartz focusing lens, the UV digital camera, and a digital camera computerized imaging system. An Oriel model 6035 Hg(Ar) pencil lamp fitted with a 6042 flourescent filter was used as a UV light source. This produced a rectangular (0.5 cm × 3 cm) UV output centered at about 350 nm with a FWHM of ~40 nm. In order to provide an alpha-numeric UV scene, a thin sheet of brass was used to mill out the letters “NCSU”. This brass aperture was then attached to the front of the UV source as shown in Figure 8 to provide a UV back-lighted scene. A fused quartz lens of focal length 25 mm was used to focus the UV scene onto the GaN/AlGaN FPA as shown in Figure 7.

Figure 7. Experimental setup used at NVL to evaluate the visible-blind UV digital camera.

Figure 8. Back-lighted UV alpha-numeric (“NCSU”) source used for nitride FPA testing at NVL.

The output from the visible-blind UV camera was connected to an Amber Proview imaging system. The Proview system contains electronics to support the imaging of FPA devices and to interface FPA devices to digital recording and processing equipment. In addition, it can convert the digital data into an RS-170 NTSC analog video format that can be displayed on any RS-170 compatible monitor.

4. Results and Discussion

5. Summary and Conclusions

A visible-blind UV camera based on a 32 × 32 array of GaN/AlGaN p-i-n photodiodes has been successfully demonstrated at room temperature. Each of the 1024 photodiodes in the array consists of a base n-type layer of AlGaN:Si (~20%), an undoped GaN layer, and a p-type GaN:Mg layer deposited sequentially by MOVPE. Discrete 200 μm × 200 μm photodiodes, processed from the same wafer as the photodiode array, display spectral responsivities of 0.2 A/W at 358 nm, corresponding to an internal quantum efficiency of 82%. A detector figure of merit R₀A = 1.5 × 10⁹ Ω–cm² was obtained from which the detectivity D^* = 6.1 × 10¹³ cm Hz^1/2W⁻¹ was estimated. This is one of the highest D^* values ever obtained for any semiconductor photodetector operating at any temperature and at any wavelength. The 32 × 32 diode array that formed the sensing element in the visible-blind UV camera displayed similar high sensitivity with ~95% pixel activation.

This UV camera demonstration represents another historical advancement in optoelectronic devices based on III-V nitride materials. It is, indeed, remarkable to us that the outstanding characteristics of the GaN/AlGaN heterostructure p-i-n photodiodes and the diode FPA that we are reporting were obtained using samples that contain 10¹⁰ or more dislocations per cm²!! The reason why only nitride devices function in the presence of such large dislocation densities remains a matter of speculation Reference Johnson, Zhonghai, Brown, Koeck, El-Masry, Kong, Edmond, Cook and Schetzina[16]. However, dislocation reduction techniques such as epitaxial lateral overgrowth (ELO) or pendioepitaxy Reference Nam, Bremser, Zheleva and Davis[17] Reference Zheleva, Smith, Thomson, Gehrke, Linthicum, Rajagopal, Carlson, Ashmawi and Davis[18] Reference Yu, Johnson, Brown, El-Masry, Muth, Cook, Schetzina, Haberern, Kong and Edmond[19] Reference Linthicum, Hanser, Zheleva, Nam and Davis[20], if successfully applied to AlGaN layers, hold promise for even more impressive nitride photodiode characteristics in the future.

When fully developed into large-format photodiode arrays, this new type of UV digital camera may be used in many wide-ranging applications including biological agent detection, missile and shellfire detection, atmospheric ozone-level detection, welding imagery, and flame sensing. In addition, large-format UV staring FPAs based on nitride photodiodes may play an important role in obtaining UV images of the stars and other astronomical objects of importance in understanding the creation and evolution of the universe.