Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-25T15:18:25.898Z Has data issue: false hasContentIssue false
  • English
  • Français

Surface Passivation of Bare Aluminum Nanoparticles using Perfluoroalkyl Carboxylic Acids

Published online by Cambridge University Press:  01 February 2011

R. Jason Jouet ,
Andrea D. Warren ,
David M. Rosenberg  and
Victor J. Bellitto
R. Jason Jouet
Affiliation:
Naval Surface Warfare Center – Indian Head Division, Research and Technology Department, 101 Strauss Avenue, Indian Head, MD 20640
Andrea D. Warren
Affiliation:
Naval Surface Warfare Center – Indian Head Division, Research and Technology Department, 101 Strauss Avenue, Indian Head, MD 20640
David M. Rosenberg
Affiliation:
Naval Surface Warfare Center – Indian Head Division, Research and Technology Department, 101 Strauss Avenue, Indian Head, MD 20640
Victor J. Bellitto
Affiliation:
Naval Surface Warfare Center – Indian Head Division, Research and Technology Department, 101 Strauss Avenue, Indian Head, MD 20640
Get access

Abstract

Surface passivation of unpassivated Al nanoparticles has been realized using self assembled monolayers (SAMs). Nanoscale Al particles were prepared in solution by catalytic decomposition of H3Al•NMe3 or H3Al•N(Me)Pyr by Ti(OiPr)4 and coated in situ using a perfluoroalkyl carboxylic acid SAM. Because the Al particles are prepared using wet chemistry techniques and coated in solution, they are free of oxygen passivation. This SAM coating passivates the aluminum and seems to prevent the oxidation of the particles in air and renders the composite material, to some extent, soluble in polar organic solvents such as diethyl ether. Characterization data including SEM, TEM, TGA, and ATR-FTIR of prepared materials is presented.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 800: Symposium AA – Synthesis, Characterization, and Properties of Energetic/Reactive Nanomaterials , 2003 , AA2.4
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Sagiv, J. J. Am. Chem. Soc. 1980, 102, 92.Google Scholar
Netzer, L.; Sagiv, J. J. Am. Chem. Soc. 1983, 105, 674.Google Scholar
Moaz, R.; Sagiv, J. J. Colloid Interface Sci. 1984, 100, 465.Google Scholar
Houssiau, L.; Bertrand, P. App. Surf. Sci. 2001, 175, 351.Google Scholar
2. Folkers, J. P.; Gorman, C.B.; Laibinis, P.E.; Buchholz, S.; Whitesides, G.M. Langmuir, 1995, 11, 813.Google Scholar
3. Karaman, M. E.; Antelmi, D. A.; Pashley, R. M. Colloids Surf. A: Physicochem. Eng. Aspects 2001, 182, 285.Google Scholar
Allara, D. L.; Nuzzo, R. G. Langmuir 1985, 1, 45 and 52.Google Scholar
Tao., Y. J. Am. Chem. Soc. 1993, 115, 4350.Google Scholar
Tao, Y.; Hietpas, G. D.; Allara, D. L.; J. Am. Chem. Soc. 1996, 118, 6724 and references contained therein.Google Scholar
For reviews, see: Bain, C. D.; Whitesides, G. M. Angew. Chem.,Int. Ed. Engl. 1989, 28, 506–512.Google Scholar
Whitesides, G. M.; Laibinis, P. E. Langmuir 1990, 6, 87–96.Google Scholar
Ulman, A. An. Introduction to Ultrathin Organic Films From Langmuir-Blodgett to Self-Assembly; Academic Press: San Diego, CA, 1991; Chapter 3.Google Scholar
4. Sardar, S. A.; Duschek, R.;. Blyth, R. I. R; Netzer, F. P.; Ramsey, M. G. Surf. Sci., 2000, 468, 10. → Aldehyde on bare Al(111)Google Scholar
5. Crowell, J. E.; Chen, J. G.; Yates, J. T. Jr J. Chem. Phys. 1986, 85, 3111.Google Scholar
6. Fisher, G. L.; Hooper, A. E.; Opila, R. L.; Allara, D. L.; Winograd, N. J. Phys. Chem. B 2000, 104, 3267.Google Scholar
7. Higa, K. T.; Johnson, C. E.; Hollins, R. A. U. S. Patent No. 5,885,321, 1999.Google Scholar
8. Socrates, G Infrared Characteristic Frequencies, 2nd ed.; John Wiley & Sons: New York, 1994; p 155.Google Scholar
9. Kim, C. S., Mowrey, R.C., Butler, J.E., Russell, J.N. Jr., J. Phys. Chem. B 1998, 102, 9290.Google Scholar
10. Deacon, G. B.; Phillips, R. J. Coord. Chem. Rev. 1980, 33, 227.Google Scholar
11. Crowell, J. E.; Chen, J. G.; Yates, J. T. Jr J. Elect. Spect. Rel. Phenom. 1986, 39, 97.Google Scholar
12. Zhukov, V.; Popova, I.; Fomenko, V.; Yates, J.T. Jr Surf Sci. 1999, 441, 240.Google Scholar
13. Haber, J. A., Buhro, W. E. J. Am. Chem. Soc. 2003, 120, 10847.Google Scholar