Hostname: page-component-cd9895bd7-gvvz8 Total loading time: 0 Render date: 2024-12-27T01:30:30.205Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation, Characterization and Electrochemical Property of ZnCl2-doped Carbon Nanometer Material as the Anode of Lithium-ion Battery

Published online by Cambridge University Press:  03 September 2012

D.F. Zhou ,
Y.L. Zhao ,
Y.G. Chen ,
X.Y. Zhang  and
R.S. Wang
D.F. Zhou
Affiliation:
Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China School of Biological Engineering, Changchun University of Technology, Changchun 130012, China
Y.L. Zhao
Affiliation:
Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China
Y.G. Chen
Affiliation:
Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China
X.Y. Zhang
Affiliation:
Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China
R.S. Wang
Affiliation:
Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China
Get access

Abstract

Phenolic resin-based nanoscopic carbonaceous materials have been prepared by doping different proportions of ZnCl2 into phenolic resin (PR) precursor at various heat-treatment temperatures and characterized by means of Brunner-Emmett-Teller method (BET), X-ray diffraction (XRD), transmission electron microscopy (TEM) and Raman spectroscopy analyses. The results show that as the ratio of PR to ZnCl2 is 1:3, the average size of grains and apertures are about from 40 to 60 nm and 3.86 nm, respectively, reaching nanometer level. When this material is used as electrode material of lithium ion battery, the reversible capacity the battery could be kept at 370 mA•h•g−1 after 10 charge/discharge cycles.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 822: Symposium S – Nanostructured Materials in Alternative Energy Devices , 2004 , S3.4
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Fong, R., Sacken, U. Von, Dahn, J. R., J. Electrochem. Soc. 137, 2009 (1990).Google Scholar
2. Tatsumi, K., Zaghib, K., Sawada, Y., Abe, H., Ohsaki, T., J. Electrochem. Soc. 142, 1090 (1995).Google Scholar
3. Imanishi, N., Ohashi, S., Ichikawa, T., Takeda, Y., Yamamoto, O., Kanno, R., J. Power Sources 39, 185 (1992).Google Scholar
4. Funabiki, A., Inaba, M., Ogumi, Z., Yuasa, S., Otsuji, J., Tasaka, A., J. Electrochem. Soc. 145, 172 (1998).Google Scholar
5. Tokumitsu, K., Mabuchi, A., Fujimoto, H., Kasuh, T., J. Electrochem. Soc. 143, 2235 (1996).Google Scholar
6. Xiang, H. Q., Fang, S. B., Jiang, Y. Y., J. Power Sources 94, 85 (2001).Google Scholar
7. Dahn, J. R., Zheng, T., Liu, Y., Xue, J. S., Science 270, 590 (1995).Google Scholar
8. Yazami, R., Deschamps, M., J. Power Sources 54, 411 (1995).Google Scholar
9. Novak, P., Scheifele, W., Winter, M., Haas, O., J. Power Sources 68, 267 (1997)Google Scholar
10. Yue, Z. R., Christian, L. M., James, E., Carbon 40, 1181 (2002).Google Scholar
11. Raun, D., Cherdron, H., Kern, W., Translated by Bao-Tong, Huang. “Techniques of polymer synthesis and characterization”(University of Science and Technolgy of China Press, Beijing,1981) pp.258–264.Google Scholar
12. Yamashita, Y., Ouchi, K., Carbon 19, 89 (1981).Google Scholar
13. Fang, R. C., “Solid State Spectroscopy”(University of Science and Technolgy of China Press, Hefei, 2001) pp.319–322.Google Scholar
14. Tuinstra, F., Koenig, J. L., J. Phys. Chem. 53, 1126 (1970).Google Scholar
15. Peled, E., Eshkenazi, V., Rosenbreg, Y., J. Power Sources 76, 153 (1998).Google Scholar