Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-29T07:35:15.962Z Has data issue: false hasContentIssue false
  • English
  • Français

Novel Conjugated Polymers Containing Ferrocene

Published online by Cambridge University Press:  21 March 2011

Jin-Kyu Lee  and
Sung In Cho
Jin-Kyu Lee
Affiliation:
Dept. of Chemistry, Seoul National University, Seoul 151-742, Korea
Sung In Cho
Affiliation:
Dept. of Chemistry, Seoul National University, Seoul 151-742, Korea
Get access

Abstract

Conjugated inorganic/organic hybrid polymers, poly(phenylene vinylene ferrocenyl vinylene), was prepared by condensation polymerization of bisphosphonate reagent and ferrocenedialdehyde. Conjugated polymers having long alkyl side chains is very soluble in various organic solvents and thin polymer films can be easily produced by spin-coating technique. UV-Vis., NMR, cyclicvoltammetry, and GPC analysis were used to characterize the properties of conjugated polymers, and the averaged molecular weight was in the range of 7,000~25,000 (vs. PS standard). Electrical conductivity measurement of this processible conjugated polymer either in powder or in thin solid film showed very low conductivity probably due to the slow chain-to-chain hopping process. Third order nonlinear optical property of the conjugated polymers was measured as high as ϰ(3) = 1.24×10−8 esu in spin-coated thin film.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 598: Symposium BB – Electrical, Optical, & Magenetic Properties...V , 1999 , BB3.43
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Sheats, J. E.; Carraheer, C. E. Jr.; Pittman, C. V. Jr., Metal-containing Polymeric Systems; Prenum Press: New York, 1985.Google Scholar
2. Laine, R. M. Inorganic and Organometallic Polymers with Special Properties; Kluwer Academic Publisher: Norwell, 1992.Google Scholar
3. Wu, A.; Yoo, D.; Lee, J.-K.; Rubner, M. F. J. Am. Chem. Soc. 1999, 121, 4883.Google Scholar
4. Swager, T. M. Design and Synthesis of Complex Conjugated Polymers, Chapter 2 in Organized Molecular Assemblies in the Solid State, Whitesell, J. K. Ed., John Wiley and Sons Ltd., New York, 1999.Google Scholar
5. Skotheim, T. A.; Elsenbaumer, R. L.; Reynolds, J. R. Eds. Handbook of Conducting Polymers; 2nd Ed., Marcel Dekker, Inc.: New York, 1998.Google Scholar
6. Peng, Z.; Gharavi, A. R.; Yu, L. J. Am. Chem. Soc. 1997, 119, 4622.Google Scholar
7. Kelch, S.; Rehahn, M. Macromolrcules 1998, 31, 4102.Google Scholar
8. Zhu, S. S.; Kingsborough, R. P.; Swager, T. M. J. Mater. Chem. 1999, 9, 2123.Google Scholar
9. Kingsborough, R. P.; Swager, T. M. J. Am. Chem. Soc. 1999, 121, 8825.Google Scholar
10. Craig, G. S. W.; Cohen, R. E.; Schrock, R. R.; Dhenaut, C.; LeDoux, I.; Zyss, J. Macromolecules 1994, 27, 1875.Google Scholar
11. Lee, J.-K.; Schrock, R. R.; Baigent, D. R.; Friend, R. H. Macromolecules 1995, 28, 1966.Google Scholar
12. Singh, B. P.; Prasad, P. N.; Karasz, F. E. Polymer 1988, 29, 1940.Google Scholar
13. Shim, H. K.; Lee, K. S.; Jin, J.–I. Macromol. Chem. Phys. 1996, 197, 3501.Google Scholar