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Monitoring of Heteropolysiloxane Thin film Properties Using Rheological and Acoustic Characterization Methods

Published online by Cambridge University Press:  25 February 2011

C. Guizard
Affiliation:
Laboratoire de Physicochimie des Matériaux CNRS-URA 1312 ENSC - 8, rue de l'Ecole Normale. 34053 Monpellier Cedex 1 (France).
P. Lacan
Affiliation:
Kodak-Pathe, Centre de Recherches et de Technologie, Zone Industrielle, 71102 Chalón sur Saône Cedex (France).
J. M. Saurel
Affiliation:
Laboratoire de Microacoustique, Université de Montpellier II, Place Eugène Bataillon, 34060 Montpellier Cedex (France).
F. Hajoub
Affiliation:
Laboratoire de Microacoustique, Université de Montpellier II, Place Eugène Bataillon, 34060 Montpellier Cedex (France).
L. Cot
Affiliation:
Laboratoire de Physicochimie des Matériaux CNRS-URA 1312 ENSC - 8, rue de l'Ecole Normale. 34053 Monpellier Cedex 1 (France).
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Abstract

This paper emphasizes on the mechanical characterization of heteropolysiloxane (HPS) derived materials using rheology and acoustic microscopy methods. Dynamic rheological measurements have been performed at the sol and the gel stages with two different precursors. An organic gel-like behaviour has been brought into evidence related to the fact that several microns thick coated layers can be obtained with these materials. On the contrary acoustic analysis revealed a glass-like behaviour for the cured layers. These results confirm the interest of organic/inorganic polymers to design new materials with tailored properties.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

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