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Material Characterization and Chemical-Mechanical Polishing of Low-Dielectric Constant Fluorinated Silicon Dioxide Films

Published online by Cambridge University Press:  15 February 2011

Wei-Tsu Tseng
Affiliation:
National Nano Device Laboratory, 1001-1 Ta-Hsueh Road, Hsinchu 300, TAIWAN
Charles C.F. Lin
Affiliation:
Winbond Electronics Corporation, Science-Based Industrial Park, Hsinchu, TAIWAN Institute of Materials Science and Engineering, National Chiao-Tung University, TAIWAN
Yuan-Tsu Hsieh
Affiliation:
Institute of Materials Science and Engineering, National Chiao-Tung University, TAIWAN
M.-S. Feng
Affiliation:
Institute of Materials Science and Engineering, National Chiao-Tung University, TAIWAN
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Abstract

Nanohardness, modulus, and bonding structure of fluorinated silicon dioxides are characterized in order to evaluate their correlations with chemical-mechanical polishing (CM[P) performance. Alkaline-based slurry with adjusted pH is used for polishing in an attempt to delineate the chemical erosion from mechanical abrasion effects during CMIP of fluorinated oxides. The increase in CMIP removal rate and the reduction in refractive index with increasing fluorine content in the fluorinated oxides are related to the change in bonding configuration. The enhanced moisture absorption is due to the presence of fluorine in the oxide network.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

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