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Improved MOCVD Growth of GaAs on Si

Published online by Cambridge University Press:  28 February 2011

R.M. Lum
Affiliation:
AT&T Bell Laboratories, Holmdel, N.J. 07733
J.K. Klingert
Affiliation:
AT&T Bell Laboratories, Holmdel, N.J. 07733
B.A. Davidson
Affiliation:
AT&T Bell Laboratories, Murray Hill, N.J. 07974
M.G. Lamont
Affiliation:
AT&T Bell Laboratories, Murray Hill, N.J. 07974
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Abstract

In the direct growth of GaAs on Si by MOCVD the overall quality of the heteroepitaxial film is controlled to a large extent by the growth parameters of the initial GaAs buffer layer. We have investigated the structural properties of this layer using Rutherford Backscattering Spectrometry (RBS) and X-ray double crystal diffractometry. The crystallinity of the buffer layer was observed to improve with increasing layer thickness in the range 10–100nm, and then to rapidly degrade for thicker layers. High temperature (750°C) annealing of the buffer layers resulted in considerable reordering of all but the thicker (>200 nm) layers. Alteration of the usual GaAs/Si growth sequence to include an in-situ anneal of the buffer layer after growth interruption yielded GaAs films with improved structural, optical and electrical properties.

Type
Research Article
Copyright
Copyright © Materials Research Society 1987

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