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Hydrolysis-Condensation of Alkyltin-Trialkoxides
Published online by Cambridge University Press: 25 February 2011
Abstract
BuSn(OPri)3 and BuSn(OAmt)3 have been synthesized according to a literature procedure. Their hydrolysis have been studied by 119Sn and 1H NMR spectroscopy. The former precursor yields only a closo-type oxo-hydroxo cation of formula [(BuSn)12O14(OH)6]2+. Investigation of the hydrolysis-condensation products of BuSn(OAmt)3 reveals expanded coordinenceabout the tin atoms from 4 to 5 and 6 when H2O/Sn>l. For butyltin tri-tert-amyloxide, condensation also promotes the formation of a cluster whose structure is as yet unknown.
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- Copyright © Materials Research Society 1992
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