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Controlled synthesis of anganese (oxihydr)oxides in queous olution by hermolysis

Published online by Cambridge University Press:  03 September 2012

S. Cassaignon ,
M. Koelsch  and
J-P. Jolivet
S. Cassaignon
Affiliation:
Laboratoire de Chimie de la matière condensée, CNRS UMR7574 Université Pierre et Marie Curie - Tour 54 - 4, place jussieu - 75252 Paris Cedex 05
M. Koelsch
Affiliation:
Laboratoire de Chimie de la matière condensée, CNRS UMR7574 Université Pierre et Marie Curie - Tour 54 - 4, place jussieu - 75252 Paris Cedex 05
J-P. Jolivet
Affiliation:
Laboratoire de Chimie de la matière condensée, CNRS UMR7574 Université Pierre et Marie Curie - Tour 54 - 4, place jussieu - 75252 Paris Cedex 05
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Abstract

Nanometric particles of manganese (oxihydr)oxides (Hausmannite, Manganite, Nsutite, Pyrolusite and Vernadite) have been synthesized by thermohydrolysis of MnCl2 and/or KMnO4in aqueous medium. The modification of various chemical parameters (pH and precursors concentration, nature of the reducer or oxidizer, temperature and duration of the thermolysis) allow the control of the nature, the size and the morphology of the obtained particles.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 822: Symposium S – Nanostructured Materials in Alternative Energy Devices , 2004 , S3.8
Copyright
Copyright © Materials Research Society 2004

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