Hostname: page-component-78c5997874-t5tsf Total loading time: 0 Render date: 2024-11-20T01:14:34.491Z Has data issue: false hasContentIssue false
  • English
  • Français

Conductive Nano-brush Synthesized by Physical Grafting of Conducting Polymers on Carbon Nanotube

Published online by Cambridge University Press:  21 March 2011

Kaushalkumar Purohit ,
Maureen Mirville ,
Sze C. Yang ,
Arun Shukla  and
Vijaya B. Chalivendra
Kaushalkumar Purohit
Affiliation:
Chemistry Dept, University of Rhode Island, Kingston, RI 02881, USA
Maureen Mirville
Affiliation:
Chemistry Dept, University of Rhode Island, Kingston, RI 02881, USA
Sze C. Yang
Affiliation:
Chemistry Dept, University of Rhode Island, Kingston, RI 02881, USA
Arun Shukla
Affiliation:
Mechanical Engineering Dept, University of Rhode Island, Kingston, RI 02881, USA
Vijaya B. Chalivendra
Affiliation:
Mechanical Engineering Dept., University of Massachusetts, North Dartmouth, MA 02747
Get access

Abstract

We report a novel method for synthesizing electrically conductive nano-brush (CNB) by physical grafting of organic conducting polymers on carbon nano tubes (CNT). The objective for this synthesis is to produce nano tubes having a CNT stem coated with flexible electronic conducting polymers. The nano-brush is to be blended into common polymers (e.g. epoxy, polyurethane, and poly(vinyl alcohol)) to form electrically conductive composite material. The flexible organic conducting polymer in CNB is a potentially sensitive electronic probe for mechanically induced nano-deformation of the composite because it is molecularly entangled with the host polymers. The electrical networks of CNB embedded in polymeric composites are potentially useful as in situ sensors for monitoring material deformation with an unprecedented level of sensitivity. The composite material is “smart” in the sense that it self-reports the structural “health” before load induced material failure.

Our method for grafting conducting polymer does not require chemical reactions with the surface atoms of the carbon nano tube. We used physical adsorption to graft electronic conducting polymer to CNT. We first synthesized a water-soluble electronic conducting polymer which is a molecular complex between poly(acrylic acid) and polyaniline. The CNT solid were dispersed and un-bundled by sonnication in the conducting polymer solution. Due to the high affinity between CNT and the conducting polymer, the surface of CNT can be fully covered with the conducting polymer. The experimental data is consistent with a structure of nano brush with high density of conducting polymers grafted on the CNT surface.

Keywords

nanostructuresensorpolymer
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1304: Symposium Z – Hierarchical Materials and Composites—Combining Length Scales from Nano to Macro , 2011 , mrsf10-1304-z09-02
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1]Sun, L., Liu, H., Clark, R., Yang, S. C., “Double Strand Polyaniline” Syn Met 85, 67 (1997).CrossRefGoogle Scholar
[2]Li, W., McCarthy, P. A., Liu, D., Huang, J., Yang, S., Wang, H.-L., “Toward understanding and optimizing the template-guided synthesis of chiral polyaniline nanocomposites,” Macromolecules, 35, 9975–9982 (2002).CrossRefGoogle Scholar
[3]Park, J. J., De Paoli Lacerda, S. H., Stanley, S. K., Vogel, B. M., Kim, S., Douglas, J. F., Raghavan, D., Karim, A., “Langmuir Adsorption Study of the Interaction of CdSe/ZnS Quantum Dots with Model Substrates,” Langmuir 2009, 25, 443–450.CrossRefGoogle ScholarPubMed
4.Karpovich, D.S., Blanchard, G. J., “Direct Measurement of the Adsorption Kinetics …” Langmuir, 1994, 10, 3315–3322.CrossRefGoogle Scholar
5.Assume that the carbon-carbon bond length of 1.45 angstrom, and the multi-wall CNT is composed of an average of 10 layers of concentric cylinders.Google Scholar
6.Random coil root mean square end-to-end distance for a polymer with 6250 monomer units with persistence length of 2.5 angstrom per monomer.Google Scholar