Article contents
Comparative Study of the Sol-Gel and Metallo-Organic Decomposition (MOD) Processes for the Preparation of Inorganic Materials
Published online by Cambridge University Press: 25 February 2011
Abstract
Sol-Gel processing and Metallo-Organic Decomposition are contrasted from the thermodynamics and chemical reactivity points of view. Differences and similarities on precursor requirements, processing characteristics, processing intermediates, and product formation pathways are outlined. Some specific examples are presented and their reaction thermodynamics are compared. Some conclusions regarding thermo-dynamic versus kinetic control are drawn from these examples.
- Type
- Research Article
- Information
- Copyright
- Copyright © Materials Research Society 1992
References
REFERENCES
1.
Brinker, C. J. and Scherer, G. W., Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (Academic Press, San Diego, CA, 1990).Google Scholar
2.
Mantese, J. V., Micheli, A. L., Hamdi, A. H., and Vest, R. W., MRS Bulletin
14(10), 48 (1989).CrossRefGoogle Scholar
3.
Xu, J. J., Shaikh, A. S., and Vest, R. W., IEEE Trans. UFFC
36, 307 (1989).CrossRefGoogle Scholar
4.
Agostinelli, J. A., Paz-Pujalt, G. R., and Mehrotra, A. K., Physica C
156, 208 (1988).CrossRefGoogle Scholar
6.
Livage, L., Henry, M., and Sanchez, C., Progress in Solid State Chemistry
18, 183 (1988).CrossRefGoogle Scholar
8.
Paz-Pujalt, G. R., in High Tc Superconductor Thin Films, edited by Correra, L. (Elsevier Science Publishers, Amsterdam, 1992).Google Scholar
9.
Paz-Pujalt, G. R., Mehrotra, A. K., Ferranti, S., and Agostinelli, J. A., Solid State Ionics
32/33, 1179 (1989).CrossRefGoogle Scholar
10.
Cotton, F. A. and Wilkinson, G., Advanced Inorganic Chemistry, 5th ed. (Wiley, New York, 1988), p. 545.Google Scholar
11.
Lange's Handbook of Chemistry, 5th ed., edited by Dean, John A. (McGraw-Hill, New York, 1985).Google Scholar
16.
Novrotsky, A., in Solid State Chemistry Techniques, edited by Cheetham, A. K. and Day, P. (Clarendon Press, Oxford, 1987).Google Scholar
- 1
- Cited by