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Integration and Characterization of Low Carbon Content SiOxCyHz Low κ Materials for < 0.18μm[ Dual Damascene Application

Published online by Cambridge University Press:  17 March 2011

Ju-Hyung Lee
Affiliation:
Applied Materials Inc., 3320 Scott Blvd., Santa Clara, CA 95054
Nasreen Chopra
Affiliation:
Agilent Inc., 350 Sharon Park Drive #N209, Menlo Park, CA 94025
Jim Ma
Affiliation:
Applied Materials Inc., 3320 Scott Blvd., Santa Clara, CA 95054
Yung-Cheng Lu
Affiliation:
Applied Materials Inc., 3320 Scott Blvd., Santa Clara, CA 95054
Tzu-Fang Huang
Affiliation:
Applied Materials Inc., 3320 Scott Blvd., Santa Clara, CA 95054
Ralf Willecke
Affiliation:
Applied Materials Inc., 3320 Scott Blvd., Santa Clara, CA 95054
Wai-Fan Yau
Affiliation:
Applied Materials Inc., 3320 Scott Blvd., Santa Clara, CA 95054
David Cheung
Affiliation:
Applied Materials Inc., 3320 Scott Blvd., Santa Clara, CA 95054
Ellie Yieh
Affiliation:
Applied Materials Inc., 3320 Scott Blvd., Santa Clara, CA 95054
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Abstract

A CVD-based low κ film was evaluated for inter-metal dielectric in < 0.18 [.proportional]m generation devices. The film was deposited by conventional rf PECVD method using organosilane compound and oxygen. The measured dielectric constant of the film was 2.7∼2.75. The κ value of the film was stable over several weeks and the moisture absorption was minimal. The chemical composition was in the form of SiOxCyHz, where the carbon content was less than 5 atomic %. Blanket film integration study was conducted to find out the manufacturing compatibility. The largest increase in κ value occurred during etching and ashing steps. However, SIMS compositional analysis revealed that the damage from these steps were limited to within top 300 Å, and the initial low κ value was recovered after the top damaged layer was removed by CMP. The final integrated dielectric constant was less than 3.0. The film density was measured as 1.4, compared to 2.3 g/cm3 of conventional SiO2. The low density of the film resulted from the termination of SiO2 network structures by Si-CH3 and Si-H.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

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