Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-29T07:29:39.365Z Has data issue: false hasContentIssue false

Atomic Scale Nitridation of Silicon Oxide Surfaces by Remote-Plasma-Excited Nitrogen

Published online by Cambridge University Press:  21 March 2011

Yoji Saito
Affiliation:
Department of Electrical Engineering and Electronics, Seikei University, 3-3-1 Kichijoji-Kitamachi, Musashino, Tokyo 180-8633, Japan
Koichi Tokuda
Affiliation:
Department of Electrical Engineering and Electronics, Seikei University, 3-3-1 Kichijoji-Kitamachi, Musashino, Tokyo 180-8633, Japan
Get access

Abstract

We have incorporated several percent of nitrogen only near the top surfaces of thermally grown oxides by exposure to fluorine gas at room temperature followed by an atomic nitrogen treatment at 550°C. The depth profiles and the bonding of incorporated nitrogen atoms have been studied by angle-resolved x-ray photoelectron spectroscopy.

MOS devices were fabricated using the nitrided oxide with boron doped polycrystalline silicon gate. From the capacitance-voltage measurements we confirmed that the nitrided oxide would prevent the boron penetration in comparison with the conventional oxide films. The proposed technique identifies a unique process for obtaining high quality ultrathin dielectrics.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Huand, G. J. Bruce, R. H., IEEE Trans. Electron Devices ED–32, 584 (1985).Google Scholar
[2] Hillenius, S. J., Liu, R., Georgiou, G. E., Field, R. L., Williams, D. S., Kornblit, A., Boulin, D. M., Johnston, R.L., and Lynch, W.T., IEDM Tech. Digest (1986) p.252.Google Scholar
[3] Kuroi, T., Shirahata, M., Okumura, Y., Kusunoki, S., Inuishi, M., and Tsubouti, N., Jpn. J. Appl. Phys. 34, 771775 (1995).Google Scholar
[4] Yu, B., Ju, D-H., Kepler, N., and Hu, C., IEEE Electron Device Letter EDL–18, 312 (1997).Google Scholar
[5] Hattangady, S. V., Niimi, H., and Lucovsky, G., Appl. Phys. Lett. 66, 3495 (1995).Google Scholar
[6] Saito, Y., Appl. Phys. Lett. 68, 800 (1996).Google Scholar
[7] Saito, Y. and Mori, U., Jpn. J. Appl. Phys. 37, L1172–L1174 (1998).Google Scholar
[8] Saito, Y. and Mori, U., in Ultrathin SiO2 and High-K Materials for ULSI Gate Dielectrics, edited by Huff, H. R.. Richter, C. A., Lucovsky, G., and Hattori, T., Mater. Res. Soc. Proc. 567, San Francisco, 1999) pp.3337.Google Scholar
[9] Hedge, R. I., Tobin, P. J., Reid, K. G., Maiti, B., and Ajuria, S. A., Appl. Phys. Lett. 66, 2882 (1995).Google Scholar
[10] Carr, E.C. and Buhrman, R.A., Appl.Phys.Lett. 63, 5456 (1993).Google Scholar