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Time and temperature dependent formation of hollow gold nanoparticles via galvanic replacement reaction of As(0) and its catalytic application

Published online by Cambridge University Press:  08 November 2018

Imon Kalyan ,
Tarasankar Pal  and
Anjali Pal
Imon Kalyan
Affiliation:
School of Nanoscience and Nanotechnology, Indian Institute of Technology Kharagpur, West Bengal-721302, India
Tarasankar Pal
Affiliation:
Department of Chemistry, Indian Institute of Technology Kharagpur, West Bengal-721302, India
Anjali Pal*
Affiliation:
Department of Civil Engineering, Indian Institute of Technology Kharagpur, West Bengal-721302, India
*
Address all correspondence to Anjali Pal at [email protected]
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Abstract

Two different sized As(0) nanoparticles As1 (50 ± 7 nm) and As2 (70 ± 10 nm) are prepared by reducing arsenite with NaBH4 in the pH range 7–9, at controlled temperature (10 and 40 °C). Further, galvanic replacement reaction is used exploiting the reducing nature of As(0) to prepare two different sized hollow gold nanoparticles (HGNPs) AuNP1 (55 ± 7 nm) and AuNP2 (72 ± 7 nm). These HGNPs exhibit high catalytic activity towards 4-nitrophenol reduction under various conditions following first-order kinetics. AuNP1 shows ~6.6 time higher turnover frequency compared with that of AuNP2 due to its smaller size. Both catalysts are recycle able.

Type
Research Letters
Information
MRS Communications , Volume 9 , Issue 1 , March 2019 , pp. 270 - 279
Copyright
Copyright © Materials Research Society 2018 

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