Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-30T10:33:15.687Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and applications of near-infrared absorbing additive copper hydroxyphosphate

Published online by Cambridge University Press:  30 July 2018

Elena Pérez-Barrado ,
Richard J. Darton  and
Dieter Guhl
Elena Pérez-Barrado
Affiliation:
School of Chemical and Physical Sciences, Keele University, Staffordshire ST5 5BG, UK Keeling & Walker Ltd, Whieldon Rd, Stoke-on-Trent ST4 4JA, UK
Richard J. Darton*
Affiliation:
School of Chemical and Physical Sciences, Keele University, Staffordshire ST5 5BG, UK
Dieter Guhl
Affiliation:
Keeling & Walker Ltd, Whieldon Rd, Stoke-on-Trent ST4 4JA, UK
*
Address all correspondence to Richard J. Darton at [email protected]
Get access

Abstract

The use of copper hydroxyphosphate (Cu2PO4OH), also called libethenite, as a near-infrared (NIR) absorbing additive has been investigated. Samples were synthesized by using a hydrothermal treatment or simple wet chemical processing, which was later easily upscaled. All synthesized samples showed a strong absorption in the NIR region. Trials were conducted to produce laser-marked plastic plates and security IR ink printing tests. It was found that when incorporated in plastic and ink formulation, Cu2PO4OH added good NIR absorption properties without influencing other finished product properties too much, which confirms that it is a suitable additive that can be readily manufactured at room temperature and without pressured equipment.

Type
Research Letters
Information
MRS Communications , Volume 8 , Issue 3 , September 2018 , pp. 1070 - 1078
Check for updates
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Franke, J.: Three-Dimensional Molded Interconnect Devices (3D-MID), 1st ed. (Hanser Publications, Cincinnati, 2014).Google Scholar
2.KGaA, Merck: Merck presents new laser marking and welding pigment. Add. Polym. 8, 3 (2009).Google Scholar
3.US Patent 8778494 B2, Pigment for laser marking.Google Scholar
4.European Patent 2942378 B1, Infrared-absorbing inkjet ink composition for security document personalization.Google Scholar
5.Wissemborski, R. and Klein, R.: Welding and marking of plastics with lasers. LTJ 7, 19 (2010).Google Scholar
6.Wang, G., Huang, B., Ma, X., Wang, Z., Qin, X., Zhang, X., Dai, Y., and Whangbo, M-H.: Cu2(OH)PO4, a near-infrared-activated photocatalyst. Angew. Chem. Int. Ed. 52, 4810 (2013).Google Scholar
7.Zhao, Y., Teng, F., Xu, J., Liu, Z., Yang, Y., Zhang, Q., and Yao, W.: Facile synthesis of Cu2PO4OH hierarchical nanostructures and their improved catalytic activity by a hydroxyl group. RSC Adv. 5, 100934 (2015).Google Scholar
8.US patent 20080004363A1, Laser-weldable polymers.Google Scholar
9.Zhang, J., Zhou, T., Weng, L., and Zhang, A.: Fabricating metallic circuit patterns on polymer substrates through laser and selective metallization. ACS Appl. Mater. Interfaces 8, 33999 (2016).Google Scholar
10.Cho, I-S., Kim, D. W., Lee, S., Kwak, C. H., Bae, S-T., Noh, J. H., Yoon, S. H., Jung, H. S., Kim, D-W., and Hong, K. S.: Synthesis of Cu2PO4OH hierarchical superstructures with photocatalytic activity in visible light. Adv. Func. Mater. 18, 2154 (2008).Google Scholar
11.Hu, X., Zheng, X-J., Li, Y., Zhang, J., and Ma, D-K.: Cu2PO4OH: Controlled synthesis of various architectures and morphology-dependent 808 nm laser-driven photothermal performance. J. Alloy. Compd. 695, 561 (2017).Google Scholar
12.Klug, H. P. and Alexander, L. E.: X-Ray Diffraction Procedures: for Polycrystalline and Amorphous Materials, 2nd ed. (Wiley-Interscience, New York, 1974).Google Scholar
13.Performance Polymers. Available at: http://www.vestamid.com/sites/lists/RE/DocumentsHP/Polymers-Lasers-EN.pdf (accessed May 2018).Google Scholar
14.CN Patent 101418091A, Laser marked plastic and preparation method thereof.Google Scholar
15.Vasile, C.: Handbook of Polyolefins, 2nd ed. (CRC Press, New York, 2000).Google Scholar
16.Schneider, C. A., Rasband, W. S., and Eliceiri, K. W.: NIH Image to ImageJ: 25 years of image analysis. Nat. Methods 9, 671 (2012).Google Scholar
17.Xu, Y., Jiao, X., and Chen, D.: Hydrothermal synthesis and characterization of copper hydroxyphosphate hierarchical superstructures. J. Disper. Sci. Technol. 32, 591 (2011).Google Scholar
18.Rudolph, P.: Handbook of Crystal Growth, Volume 2A-2B, 2nd ed. (Elsevier, Oxford, 2015).Google Scholar
19.Li, Z., Dai, Y., Ma, X., Zhu, Y., and Huang, B.: Tuning photocatalytic performance of the near-infrared-driven photocatalyst Cu2(OH)PO4 based on effective mass and dipole moment. Phys. Chem. Chem. Phys., 16, 3267 (2014).Google Scholar
20.Gangi Reddy, N. C., Ramasubba Reddy, R., Siva Reddy, G., Lakshmi Reddy, S., and Jagannatha Reddy, B.: EPR, optical absorption, MIR and Raman spectral studies on libethenite mineral. Cryst. Res. Technol. 41, 400 (2006).Google Scholar
21.Xiao, F-S., Sun, J., Meng, X., Yu, R., Yuan, H., Xu, J., Song, T., Jiang, D., and Xu, R.: Synthesis and structure of copper hydroxyphosphate and its high catalytic activity in hydroxylation of phenol by H2O2. J. Catal. 199, 273 (2001).Google Scholar
22.Zhan, Y., Li, H., and Chen, Y.: Copper hydroxyphosphate as catalyst for the wet hydrogen peroxide oxidation of azo dyes. J. Hazard. Mater. 180, 481 (2010).Google Scholar
23.Xu, J., Zhang, J., and Liu, X.: Hydrothermal synthesis of copper hydroxyphosphate hierarchical architectures. Chem. Eng. Technol. 35, 2189 (2012).Google Scholar
24.Fu, W., Wang, R., Wu, L., Wang, H., Wang, X., Wang, A., Zhang, Z., and Qiu, S.: Synthesis of Cu2(OH)PO4 crystals with various morphologies and their catalytic activity in hydroxylation of phenol. Chem. Lett. 42, 772 (2013).Google Scholar
25.Han, J., Li, H., Xu, X., Yuan, L., Wang, N., and Yu, H.: Cu2(OH)PO4 pretreated by composite surfactants for the micro-domino effect: a high-efficiency Fenton catalyst for the total oxidation of dyes. Mater. Lett. 166, 71 (2016).Google Scholar
26.Zhao, G., Pang, H., Li, H., Li, J., Yan, B., Ma, Y., Li, G., Chen, J., Zhang, J., and Zheng, H.: Copper (II) oxide phosphate superstructures: their primary application as effective antimicrobial materials. Int. J. Electrochem. Sci. 8, 490 (2013).Google Scholar
27.Gao, F., Pang, H., Xu, S., and Lu, Q.: Copper-based nanostructures: promising antibacterial agents and photocatalysts. Chem. Commun. 0, 3571 (2009).Google Scholar
28.Zhang, H-p, Tang, P., Li, D., and Tang, Y.: Photocatalytic and antibacterial properties of copper hydroxyphosphate with hierarchical superstructures synthesized by a hydrothermal method. Mater. Chem. Phys. 206, 130 (2018).Google Scholar
29.Mahalik, N. P., and Nambiar, A. N.: Trends in food packaging and manufacturing systems and technology. Trends Food Sci. Tech. 21, 117 (2010).Google Scholar
30.Cloutier, M., Mantovani, D., and Rosei, F.: Antibacterial coatings: challenges, perspectives, and opportunities. Trends Biotechnol. 33, 637 (2015).Google Scholar
31.Han, A. and Gubencu, D.: Analysis of the laser marking technologies. Nonconv. Technol. Rev. 4, 17 (2008).Google Scholar
32.Thermoplastics laser marking. Available at: https://www.lati.com/wp-content/uploads/laser_marking.pdf (accessed May 2018).Google Scholar
33.Zhong, W., Cao, Z., Qiu, P., Wu, D., Liu, C., Li, H., and Zhu, H.: Laser-marking mechanism of thermoplastic polyurethane/Bi2O3 composites. ACS Appl. Mater. Interfaces 7, 24142 (2015).Google Scholar
Supplementary material: File

Pérez-Barrado et al. supplementary material

Pérez-Barrado et al. supplementary material 1

Download Pérez-Barrado et al. supplementary material(File)
File 2.8 MB