Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-30T10:54:04.505Z Has data issue: false hasContentIssue false
  • English
  • Français

Structural and luminescence properties of yellow phosphors prepared by a modified sol–gel method

Published online by Cambridge University Press:  12 September 2017

Vasilica Ţucureanu ,
Alina Matei ,
Andrei Avram ,
Marian Cãtalin Popescu ,
Iuliana Mihalache ,
Marioara Avram ,
Cãtalin Valentin Mãrculescu ,
Bianca Cãtãlina Ţîncu ,
Marius Volmer  and
Daniel Munteanu
Vasilica Ţucureanu*
Affiliation:
National Institute for Research and Development in Microtechnologies, IMT-Bucharest, 126A, Erou Iancu Nicolae Street, 077190 Bucharest, Romania, http://www.imt.ro Department of Materials Science, Transilvania University of Brasov, 29 Eroilor Blvd, Brasov 500036, Romania
Alina Matei
Affiliation:
National Institute for Research and Development in Microtechnologies, IMT-Bucharest, 126A, Erou Iancu Nicolae Street, 077190 Bucharest, Romania, http://www.imt.ro
Andrei Avram
Affiliation:
National Institute for Research and Development in Microtechnologies, IMT-Bucharest, 126A, Erou Iancu Nicolae Street, 077190 Bucharest, Romania, http://www.imt.ro
Marian Cãtalin Popescu
Affiliation:
National Institute for Research and Development in Microtechnologies, IMT-Bucharest, 126A, Erou Iancu Nicolae Street, 077190 Bucharest, Romania, http://www.imt.ro
Iuliana Mihalache
Affiliation:
National Institute for Research and Development in Microtechnologies, IMT-Bucharest, 126A, Erou Iancu Nicolae Street, 077190 Bucharest, Romania, http://www.imt.ro
Marioara Avram
Affiliation:
National Institute for Research and Development in Microtechnologies, IMT-Bucharest, 126A, Erou Iancu Nicolae Street, 077190 Bucharest, Romania, http://www.imt.ro
Cãtalin Valentin Mãrculescu
Affiliation:
National Institute for Research and Development in Microtechnologies, IMT-Bucharest, 126A, Erou Iancu Nicolae Street, 077190 Bucharest, Romania, http://www.imt.ro
Bianca Cãtãlina Ţîncu
Affiliation:
National Institute for Research and Development in Microtechnologies, IMT-Bucharest, 126A, Erou Iancu Nicolae Street, 077190 Bucharest, Romania, http://www.imt.ro
Marius Volmer
Affiliation:
Electrical Engineering and Applied Physics Department, Transilvania University of Brasov, 29 Eroilor Blvd, Brasov 500036, Romania, http://www.unitbv.ro
Daniel Munteanu
Affiliation:
Department of Materials Science, Transilvania University of Brasov, 29 Eroilor Blvd, Brasov 500036, Romania
*
Address all correspondence to Vasilica Ţucureanu, at [email protected], [email protected]
Get access

Abstract

In our paper, yttrium aluminum garnet doped with cerium (YAG:Ce) and terbium aluminum garnet doped with cerium (TAG:Ce) yellow garnet phosphors were prepared by a modified sol–gel method, using oxide, nitride as raw materials and acetylacetone, dimethyl sulfoxide, cetrimonium bromide in the hydrolysis and condensation step. The thermal treatment of the phosphors was performed at 1100 °C in order to transform it from amorphous to crystalline garnet phase. Structural, morphological, and luminescence properties were studied by Fourier transform infrared spectrometry, x-ray diffraction, scanning electron microscopy, and fluorescence spectroscopy. The results show that the modified sol–gel method provides a feasible approach to produce YAG:Ce and TAG:Ce yellow phosphors for the optoelectronic applications.

Type
Research Letters
Information
MRS Communications , Volume 7 , Issue 3 , September 2017 , pp. 721 - 727
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Chiang, C.C., Tsai, M.S., and Hon, M.H.: Synthesis and photoluminescent properties of Ce3+ doped terbium aluminum garnet phosphors. J. Alloys Compd. 431, 298–302 (2007). doi: 10.1016/j.jallcom.2006.05.068.Google Scholar
2.Akasaki, I., Amano, H., Nakamura, S., and Nakamura, S.: The Nobel Prize in Physics 2014. Nobelprize.org. Nobel Media AB 2014. <http://www.nobelprize.org/nobel_prizes/physics/laureates/2014/>..>Google Scholar
3.Ryu, H.Y.: Analysis on the luminous efficiency of phosphor-conversion white light-emitting diode. J. Opt. Soc. Korea 17, 22–26 (2013). doi: 10.3807/JOSK.2013.17.1.022.Google Scholar
4.Haaheim, J. and DenBaars, S.: A history of solid state white lighting, the evolution of GaN nanowires, and new potentials for white light generation using InGaN nanowires, in Department of Electrical and Computer Engineering at the University of California, St. Barbar, 2002; 1–15.Google Scholar
5.Jang, M.S., Choi, Y.H., Wu, S., Lim, T.G., and Yoo, J.S.: Material properties of the Ce3+ – doped garnet phosphor for a white LED application. J. Inf. Disp. 17, 117–123 (2016). doi: 10.1080/15980316.2016.1205527.Google Scholar
6.Tsukamoto, A. and Isobe, T.: Characterization and biological application of YAG:Ce3+ nanophosphor modified with mercaptopropyl trimethoxy silane. J. Mater. Sci. 44, 1344–1350 (2009). doi: 10.1007/s10853-008-3012-4.Google Scholar
7.Tucureanu, V., Matei, A., and Avram, A.M.: Synthesis and characterization of YAG:Ce phosphors for white LEDs. Opto-Electron. Rev. 23, 239–251 (2015). doi: 10.1515/oere-2015-0038.Google Scholar
8.Wang, J., Han, T., Lang, T., Tu, M., and Peng, L.: Synthesis and photoluminescence properties of cerium-doped terbium–yttrium aluminum garnet phosphor for white light-emitting diodes applications. Opt. Eng. 54, 117106 (2015). doi: 10.1117/1.OE.54.11.117106.Google Scholar
9.Zorenko, Y., Gorbenko, V., Voznyak, T., Zorenko, T., Kuklinski, B., Turos-Matysyak, R., and Grinberg, M.: Luminescence properties of phosphors based on Tb3Al5O12 (TbAG) terbium-aluminum garnet. Opt. Spectrosc. 106, 365–374 (2009). doi: 10.1134/S0030400X09030102.Google Scholar
10.Guo, D., Ma, B., Zhao, L., Qiu, J., Liu, W., Sang, Y., Claverie, J., and Liu, H.: Bright YAG:Ce nanorod phosphors prepared via a partial wet chemical route and biolabeling applications. ACS Appl. Mater. Interfaces 8, 11990–11997 (2016). doi: 10.1021/acsami.6b01460.Google Scholar
11.Lin, C.C., Meijerink, A., and Liu, R.S.: Critical red components for next-generation white LEDs. J. Phys. Chem. Lett. 7, 495–503 (2016). doi: 10.1021/acs.jpclett.5b02433.Google Scholar
12.Kim, K.M., Chung, J.H., and Ryu, J.H.: Thin film deposition of Tb3Al5O12:Ce by pulsed laser ablation and effects of low-temperature post-annealing. J. Opt. Soc. Korea 16, 76–79 (2012). doi: 10.1016/j.jallcom.2013.04.134.Google Scholar
13.Nazaraov, M.: Luminescence mechanism of highly efficient YAG and TAG. Mold. J. Phys. Sci. 4, 347–356 (2005).Google Scholar
14.Tsai, M.S., Liu, G.M., and Chung, S.L.: Fabrication of cerium active terbium aluminum garnet (TAG:Ce) phosphor powder via the solid-state reaction method. Mater. Res. Bull. 43, 1218–1222 (2008). doi: 10.1016/j.materresbull.2007.05.027.Google Scholar
15.Kim, H.T., Kim, J.H., Hong, Y.J., Lee, J.-K., and Kang, Y.C.: Fine-sized Tb3Al5O12:Ce phosphor powders prepared by spray pyrolysis from spray solution with ethylenediaminetetraacetic acid. Electron. Mater. Lett. 8, 283–287 (2012). doi: 10.1007/s13391-012-2014-1.Google Scholar
16.Nazarov, M.: Rare earth double activated phosphors for different applications, in 2nd International Conference on Nanotechnologies and Biomedical Engineering, 2013, 376–382. doi: 10.1016/S1002-0721(10)60390-0.Google Scholar
17.Berezovskaya, I.V., Zadneprovski, B.I., Poletaev, N.I., Doroshenko, Y.A., Efryushina, N.P., Zubar, E.V., and Dotsenko, V.P.: Luminescence properties of Ce3+-doped terbium aluminum garnet phosphor prepared with use of nanostructured reagents. J. Nano-Electron. Phys. 5, 01007 (2013).Google Scholar
18.Park, B.J., Seo, H.S., Ahn, J.T., Oh, D.K., Chung, W.J., Han, J.Y., Jang, H.S., and Jeon, D.Y.: White ACPEL device with ZnS:Cu,Cl, Tb3Al5O12:Ce3+, and CaS:Eu2+ phosphors using a layered structure. ETRI J. 31, 803–805 (2009). doi: 10.4218/etrij.09.0209.0235.Google Scholar
19.Chen, Y.C. and Nien, Y.T.: Microstructure and photoluminescence properties of laser sintered YAG:Ce phosphor ceramics. J. Eur. Ceram. Soc. 37, 223–227 (2017). doi: 10.1016/j.jeurceramsoc.2016.07.032.Google Scholar
20.Cho, Y.S., Huh, Y.D., Park, C.R., and Do, Y.R.: Preparation with laser ablation and photoluminescence of Y3Al5O12:Ce nanophosphors. Electron. Mater. Lett. 10, 461–465 (2014). doi: 10.1007/s13391-014-4024-7.Google Scholar
21.Kim, V.K., Zakharov, A.I., and Chashchin, V.A.: Luminophores based on aluminum yttrium garnet (review). Glas. Ceram. 71, 64–67 (2014). doi: 10.1007/s10717-014-9618-x.Google Scholar
22.Dotsenko, V., Berezovskaya, I.V., Poletaev, N.I., Doroshenko, Y.A., Zadneprovski, B.I., Efryushina, N.P., and Zubar, E.V.: Synthesis of Ce3+-doped terbium aluminum garnet phosphors from nanostructured oxides. Proc. Int. Conf. Nano.: Appl. Prop. 1, 01PCN08 (2012). doi: 10.1007/s10971-013-2977-x.Google Scholar
23.Kamiyama, Y., Hiroshima, T., Isobe, T., Koizuka, T., and Takashima, S.: Photostability of YAG:Ce3+ nanophosphors synthesized by glycothermal method. J. Electrochem. Soc. 157, J149–J154 (2010). doi: 10.1149/1.3327907.Google Scholar
24.Chung, D.N., Hieu, D.N., Thao, T.T., Truong, V.-V., and Dinh, N.N.: Synthesis and characterization of Ce-doped Y3Al5O12 (YAG:Ce) nanopowders used for solid-state lighting. J. Nanomater. 2014, 1–7 (2014). doi: 10.1155/2014/571920.Google Scholar
25.Palmero, P. and Traverso, R.: Co-precipitation of YAG powders for transparent materials: Effect of the synthesis parameters on processing and microstructure. Materials (Basel). 7, 7145–7156 (2014). doi: 10.3390/ma7107145.Google Scholar
26.Wang, L., Zhao, F., Yang, X., Pan, C., and Huang, H.: Property of YAG:Ce 3+ nanophosphors prepared by solvothermal method using triethylene-tetramine as a reaction solvent. RSC Adv. 5, 26339–26345 (2015). doi: 10.1039/C5RA00580A.Google Scholar
27.Xu, M.M., Zhang, Z.J., Zhu, J.J., Zhao, J.T., and Chen, X.Y.: Solvothermal synthesis and luminescence properties of yttrium aluminum garnet monodispersed crystallites with well-developed faces. J. Phys. Chem. C 118, 27000–27009 (2014). doi: 10.1021/jp508507s.Google Scholar
28.Yixuan, R., Li, G., and Junguo, R.: Effect of PEG Addition on the Properties of YAG:Ce Phosphor Synthesized via a Homogeneous Precipitation Method. Rare Met. Mater. Eng. 44, 2100–2104 (2015). doi: 10.1016/S1875-5372(16)30005-4.Google Scholar
29.Schiopu, V., Matei, A., Dinescu, A., Danila, M., and Cernica, I.: Ce, Gd codoped YAG nanopowder for white light emitting device. J. Nanosci. Nanotechnol. 12, 8836–8840 (2012). doi: 10.1166/jnn.2012.6829.Google Scholar
30.Tucureanu, V., Matei, A., Mihalache, I., Danila, M., Popescu, M., and Bita, B.: Synthesis and characterization of YAG:Ce,Gd and YAG:Ce,Gd/PMMA nanocomposites for optoelectronic applications. J. Mater. Sci. 50, 1883–1890 (2015). doi: 10.1007/s10853-014-8751-9.Google Scholar