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Stable near-infrared photoluminescence from silicon quantum dot–bovine serum albumin composites

Published online by Cambridge University Press:  11 November 2020

Asuka Inoue ,
Hiroshi Sugimoto Open the ORCID record for Hiroshi Sugimoto [Opens in a new window] ,
Yozo Sugimoto ,
Kensuke Akamatsu Open the ORCID record for Kensuke Akamatsu [Opens in a new window] ,
Marie Hubalek Kalbacova Open the ORCID record for Marie Hubalek Kalbacova [Opens in a new window] ,
Chiaki Ogino Open the ORCID record for Chiaki Ogino [Opens in a new window]  and
Minoru Fujii Open the ORCID record for Minoru Fujii [Opens in a new window]
Asuka Inoue
Affiliation:
Department of Electrical and Electronic Engineering, Graduate School of Engineering, Kobe University, Rokkodai, Nada, Kobe, Japan
Hiroshi Sugimoto
Affiliation:
Department of Electrical and Electronic Engineering, Graduate School of Engineering, Kobe University, Rokkodai, Nada, Kobe, Japan
Yozo Sugimoto
Affiliation:
Department of Electrical and Electronic Engineering, Graduate School of Engineering, Kobe University, Rokkodai, Nada, Kobe, Japan
Kensuke Akamatsu
Affiliation:
Department of Nanobiochemistry, Frontiers of Innovative Research in Science and Technology (FIRST), Konan University, Minatojimaminami, Chuo-ku, Kobe, Japan
Marie Hubalek Kalbacova
Affiliation:
Institute of Pathological Physiology, 1st Faculty of Medicine, Charles University, Prague, Czech Republic
Chiaki Ogino
Affiliation:
Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University, Rokkodai, Nada, Kobe, Japan
Minoru Fujii*
Affiliation:
Department of Electrical and Electronic Engineering, Graduate School of Engineering, Kobe University, Rokkodai, Nada, Kobe, Japan
*
Address all correspondence to Minoru Fujii at [email protected]
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Abstract

The interaction between negatively charged all-inorganic silicon quantum dots (Si QDs) and bovine serum albumin (BSA) is studied. It is shown that a small difference in the size of Si QDs affects the structure of Si QD–BSA composites significantly. When the diameter of Si QDs is 4 nm, a heterodimer (~20 nm) composed of one Si QD and one BSA molecule is a preferable and stable structure. On the other hand, when the diameter is 7 nm, the size of the composites increases to ~50 nm. The Si QD–BSA composites exhibit stable photoluminescence in the near-infrared range in phosphate-buffered saline.

Type
Research Letters
Information
MRS Communications , Volume 10 , Issue 4 , December 2020 , pp. 680 - 686
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Copyright
Copyright © The Author(s), 2020, published on behalf of Materials Research Society by Cambridge University Press

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