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Spray pyrolysis and electrochemical performance of Na0.44MnO2 for sodium-ion battery cathodes

Published online by Cambridge University Press:  07 February 2017

Kuan-Yu Shen
Affiliation:
Department of Energy, Environmental and Chemical Engineering, Washington University in St. Louis, One Brookings Drive, St. Louis, MO 63130, USA
Miklos Lengyel
Affiliation:
Department of Energy, Environmental and Chemical Engineering, Washington University in St. Louis, One Brookings Drive, St. Louis, MO 63130, USA
Louis Wang
Affiliation:
Department of Energy, Environmental and Chemical Engineering, Washington University in St. Louis, One Brookings Drive, St. Louis, MO 63130, USA
Richard L. Axelbaum*
Affiliation:
Department of Energy, Environmental and Chemical Engineering, Washington University in St. Louis, One Brookings Drive, St. Louis, MO 63130, USA
*
Address all correspondence to R.L. Axelbaum at [email protected]
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Abstract

In this study, we investigate spray pyrolysis as an approach to synthesis of tunnel structure sodium manganese oxide, as it is a cost-effective and scalable technology. The powders synthesized with Na/Mn ratio of 0.50 displayed a pure tunnel structure, and demonstrated the best electrochemical performance, with a discharge capacity of 115 mAh/g. The material also showed good cycleability and rate capability. Noticeable decay in performance was seen in materials with Na/Mn ratios other than 0.50, indicating that this material is sensitive to minor compositional deviations. This study has demonstrated that spray pyrolysis is a promising synthesis method for this material.

Type
Research Letters
Copyright
Copyright © Materials Research Society 2017 

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References

1. Ellis, B.L. and Nazar, L.F.: Sodium and sodium-ion energy storage batteries. Curr. Opin. Solid State Mater. Sci. 16, 168 (2012).CrossRefGoogle Scholar
2. Palomares, V., Serras, P., Villaluenga, I., Hueso, K.B., Carretero-Gonzalez, J., and Rojo, T.: Na-ion batteries, recent advances and present challenges to become low cost energy storage systems. Energy Environ. Sci. 5, 5884 (2012).CrossRefGoogle Scholar
3. Kubota, K., Yabuuchi, N., Yoshida, H., Dahbi, M., and Komaba, S.: Layered oxides as positive electrode materials for Na-ion batteries. MRS Bull. 39, 416 (2014).CrossRefGoogle Scholar
4. Slater, M.D., Kim, D., Lee, E., and Johnson, C.S.: Sodium-ion batteries. Adv. Funct. Mater. 23, 947 (2013).Google Scholar
5. Sauvage, F., Laffont, L., Tarascon, J.M., and Baudrin, E.: Study of the insertion/deinsertion mechanism of sodium into Na0.44MnO2 . Inorg. Chem. 46, 3289 (2007).CrossRefGoogle ScholarPubMed
6. Hosono, E., Saito, T., Hoshino, J., Okubo, M., Saito, Y., Nishio-Hamane, D., Kudo, T., and Zhou, H.: High power Na-ion rechargeable battery with single-crystalline Na0.44MnO2 nanowire electrode. J. Power Sources 217, 43 (2012).Google Scholar
7. Zhao, L.W., Ni, J.F., Wang, H.B. and Gao, L.J.: Na0.44MnO2-CNT electrodes for non-aqueous sodium batteries. RSC Adv. 3, 6650 (2013).Google Scholar
8. Wang, Y., Liu, J., Lee, B., Qiao, R., Yang, Z., Xu, S., Yu, X., Gu, L., Hu, Y.-S., Yang, W., Kang, K., Li, H., Yang, X.-Q., Chen, L., and Huang, X.: Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries. Nat. Commun. 6, 6401 (2015).CrossRefGoogle ScholarPubMed
9. Bi, F., Xuan, Z., and Yaping, W.: High-rate performance electrospun Na0.44MnO2 nanofibers as cathode material for sodium-ion batteries. J. Power Sources 310, 102 (2016).Google Scholar
10. Bai, S.L., Song, J.L., Wen, Y.H., Cheng, J., Cao, G.P., Yang, Y.S., and Li, D.Q.: Effects of zinc and manganese ions in aqueous electrolytes on structure and electrochemical performance of Na0.44MnO2 cathode material. RSC Adv. 6, 40793 (2016).CrossRefGoogle Scholar
11. Xu, M.W., Niu, Y.B., Chen, C.J., Song, J., Bao, S.J., and Li, C.M.: Synthesis and application of ultra-long Na0.44MnO2 submicron slabs as a cathode material for Na-ion batteries. RSC Adv. 4, 38140 (2014).Google Scholar
12. Lengyel, M., Elhassid, D., Atlas, G., Moller, W.T., and Axelbaum, R.L.: Development of a scalable spray pyrolysis process for the production of non-hollow battery materials. J. Power Sources 266, 175 (2014).Google Scholar
13. Ogihara, T., Kodera, T., Myoujin, K., and Motohira, S.: Preparation and electrochemical properties of cathode materials for lithium ion battery by aerosol process. Mater. Sci. Eng. B 161, 109 (2009).Google Scholar
14. Hong, Y.J., Kim, J.H., Kim, M.H., and Kang, Y.C.: Electrochemical properties of 0.3Li2MnO3·0.7LiNi0.5Mn0.5O2 composite cathode powders prepared by large-scale spray pyrolysis. Mater. Res. Bull. 47, 2022 (2012).Google Scholar
15. Jung, D.S., Hwang, T.H., Park, S.B., and Choi, J.W.: Spray drying method for large-scale and high-performance silicon negative electrodes in Li-ion batteries. Nano Lett. 13, 2092 (2013).CrossRefGoogle ScholarPubMed
16. Sadeghian, Z.: Large-scale production of multi-walled carbon nanotubes by low-cost spray pyrolysis of hexane. New Carbon Mater. 24, 33 (2009).Google Scholar
17. Jung, K.Y., Lee, J.H., Koo, H.Y., Kang, Y.C., and Bin Park, S.: Preparation of solid nickel nanoparticles by large-scale spray pyrolysis of Ni(NO3)2·6H2O precursor: effect of temperature and nickel acetate on the particle morphology. Mater. Sci. Eng. B 137, 10 (2007).Google Scholar
18. Okuyama, K., Abdullah, M., Lenggoro, I.W., and Iskandar, F.: Preparation of functional nanostructured particles by spray drying. Adv. Powder Technol. 17, 587 (2006).Google Scholar
19. Lengyel, M., Atlas, G., Elhassid, D., Luo, P.Y., Zhang, X., Belharouak, I., and Axelbaum, R.L.: Effects of synthesis conditions on the physical and electrochemical properties of Li1.2Mn0.54Ni0.13Co0.13O2 prepared by spray pyrolysis. J. Power Sources 262, 286 (2014).CrossRefGoogle Scholar
20. Jeong, Y.U. and Manthiram, A.: Synthesis of NaxMnO2+δ by a reduction of aqueous sodium permanganate with sodium iodide. J. Solid State Chem. 156, 331 (2001).CrossRefGoogle Scholar
21. Lengyel, M., Shen, K-Y., Lanigan, D.M., Martin, J.M., Zhang, X., and Axelbaum, R.L.: Trace level doping of lithium-rich cathode materials. J. Mater. Chem. A 4, 3538 (2016).CrossRefGoogle Scholar