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Preparation of Mn-doped BiOBr microspheres for efficient visible-light-induced photocatalysis

Published online by Cambridge University Press:  16 August 2013

Zhen Wei ,
Guohua Jiang ,
Liang Shen ,
Xia Li ,
Xiaohong Wang  and
Wenxing Chen
Zhen Wei
Affiliation:
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018, China; Key Laboratory of Advanced Textile Materials and Manufacturing Technology (ATMT), Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
Guohua Jiang*
Affiliation:
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018, China; Key Laboratory of Advanced Textile Materials and Manufacturing Technology (ATMT), Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
Liang Shen
Affiliation:
College of Material Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 310036, China
Xia Li
Affiliation:
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018, China; Key Laboratory of Advanced Textile Materials and Manufacturing Technology (ATMT), Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
Xiaohong Wang
Affiliation:
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018, China; Key Laboratory of Advanced Textile Materials and Manufacturing Technology (ATMT), Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
Wenxing Chen
Affiliation:
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018, China; Key Laboratory of Advanced Textile Materials and Manufacturing Technology (ATMT), Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
*
Address all correspondence to Guohua Jiang at[email protected]
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Abstract

Mn-doped bismuth oxide bromide microspheres have been prepared by the hydrothermal method. The resultant composite microspheres exhibited higher photocatalytic activity under visible light irradiation, attributing to the improvement of the photo-absorption property and the separation efficiency of photogenerated electrons and holes. The holes and O2•− are the main active species in aqueous solution under visible light irradiation, rather than •OH.

Type
Research Letters
Information
MRS Communications , Volume 3 , Issue 3 , September 2013 , pp. 145 - 149
Copyright
Copyright © Materials Research Society 2013 

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References

1.Shen, X., Zhang, Z., Zhou, B., Peng, J., Xie, M., Zhang, M., and Pang, D.: Visible light-induced plasmid DNA damage catalyzed by a CdSe/ZnS-photosensitized nano-TiO2 film. Environ. Sci. Technol. 42, 5049 (2008).CrossRefGoogle ScholarPubMed
2.Turkar, S.S., Bharti, D.B., and Gaikwad, G.S.: Various methods involved in waste water treatment to control water pollution. J. Chem. Pharm. Res. 3, 58 (2011).Google Scholar
3.Gustavo, P. and Damià, B.: Photosensitized degradation of organic pollutants in water: processes and analytical applications. TrAC, Trends Anal. Chem. 17, 605 (1998).Google Scholar
4.He, C., Asi, M.A., Xiong, Y., Shu, D., and Li, X.: Photoelectrocatalytic degradation of organic pollutants in aqueous solution using a Pt-TiO2 Film. Int. J. Photoenergy 2009, 634369 (2009).Google Scholar
5.Galindo, C., Jacques, P., and Kalt, A.: Photochemical and photocatalytic degradation of an indigoid dye: a case study of acid blue 74 (AB74). J. Photochem. Photobiol., A 141, 47 (2001).CrossRefGoogle Scholar
6.Chatterjee, D. and Mahata, A.: Visible light induced photodegradation of organic pollutants on dye adsorbed TiO2 surface. J. Photochem. Photobiol., A 153, 199 (2002).Google Scholar
7.Wang, R., Jiang, G., Ding, Y., Wang, Y., Sun, X., Wang, X., and Chen, W.: Photocatalytic activity of heterostructures based on TiO2 and halloysite nanotubes. ACS Appl. Mater. Interfaces 3, 4154 (2011).Google Scholar
8.Zainal, Z., Hui, L.K., Hussein, M.Z., Abdullah, A.H., and Hamadneh, I.R.: Characterization of TiO2-chitosan/glass photocatalyst for the removal of a monoazo dye via photodegradation-adsorption process. J. Hazard. Mater. 164, 138 (2009).Google Scholar
9.Jiang, G., Wang, X., Zhou, Y., Wang, R., Hu, R., Xi, X., and Chen, W.: Hollow TiO2 nanocages with rubik-like structure for high-performance photocatalysts. Mater. Lett. 89, 59 (2012).Google Scholar
10.Jiang, G. and Zeng, J.: Preparation of nano-TiO2/polystyrene hybrid microspheres and their antibacterial properties. J. Appl. Polym. Sci. 116, 779 (2010).Google Scholar
11.Xie, Y. and Yuan, C.: Photocatalysis of neodymium ion modified TiO2 sol under visible light irradiation. Appl. Surf. Sci. 221, 17 (2004).Google Scholar
12.Chen, L., Chen, F., Shi, Y., and Zhang, J.: Preparation and visible light photocatalytic activity of a graphite-like carbonaceous surface modified TiO2 photocatalyst. J. Phys. Chem. C 116, 8579 (2012).Google Scholar
13.Kalyanasundaram, K. and Grätzel, M.: Applications of functionalized transition metal complexes in photonic and optoelectronic devices. Coord. Chem. Rev. 77, 347 (1998).Google Scholar
14.Li, Z., Luo, W., Zhang, M., Feng, J., and Zou, Z.: Photoelectrochemical cells for solar hydrogen production: current state of promising photoelectrodes, methods to improve their properties, and outlook. Energy Environ. Sci. 6, 347 (2013).Google Scholar
15.Primo, A., Corma, A., and García, H.: Titania supported gold nanoparticles as photocatalyst. Phys. Chem. Chem. Phys. 13, 886 (2011).Google Scholar
16.Zhao, Y., Wei, M., Lu, J., Wang, Z., and Duan, X.: Biotemplated hierarchical nanostructure of layered double hydroxides with improved photocatalysis performance. ACS Nano 3, 4009 (2009).CrossRefGoogle ScholarPubMed
17.Yu, C., Yang, K., Xie, Y., Fan, Q., Yu, J., Shu, Q., and Wang, C.: Novel hollow Pt-ZnO nanocomposite microspheres with hierarchical structure and enhanced photocatalytic activity and stability. Nanoscale 5, 2142 (2013).Google Scholar
18.Zhu, J., Cao, Y., Bian, Z., Wang, S., Huo, Y., Li, H., and Lu, Y.: Synthesis of photocatalytic TiO2 with controlled hierarchical structure by alcohol-induced assembly. Sci. Sin. Chim. 42, 1627 (2012).CrossRefGoogle Scholar
19.Li, Y., Liu, J., and Huang, X.: Synthesis and visible-light photocatalytic property of Bi2WO6 hierarchical octahedron-like structures. Nanoscale Res. Lett. 3, 365 (2008).Google Scholar
20.Zhang, H., Liu, L., and Zhou, Z.: First-principles studies on facet-dependent photocatalytic properties of bismuth oxyhalides (BiOXs). RSC Adv. 2, 9224 (2012).CrossRefGoogle Scholar
21.Zhang, H., Liu, L., and Zhou, Z.: Towards better photocatalysts: first-principles studies of the alloying effects on the photocatalytic activities of bismuth oxyhalides under visible light. Phys. Chem. Chem. Phys. 4, 1286 (2012).Google Scholar
22.Jiang, G., Wang, R., Wang, X., Hu, R., Xi, X., Zhou, Y., Wang, S., Wang, T., and Chen, W.: Novel highly active visible-light-induced photocatalysts based on BiOBr with Ti doping and Ag decorating. ACS Appl. Mater. Interfaces 4, 4440 (2012).Google Scholar
23.Wang, R., Jiang, G., Wang, X., Hu, R., Xi, X., Zhou, Y., Bao, S., Tong, T., Wang, S., Wang, T., and Chen, W.: Efficient visible-light-induced photocatalytic activity over the novel Ti-doped BiOBr Microspheres. Powder Technol. 228, 258 (2012).CrossRefGoogle Scholar
24.Jiang, G., Wang, X., Wei, Z., Li, X., Xi, X., Hu, R., Tang, B., Wang, R., Wang, S., Wang, T., and Chen, W.: Photocatalytic property of hierarchical structure based on Fe-doped BiOBr hollow microspheres. J. Mater. Chem. A 1, 2406 (2013).Google Scholar
25.Yao, W. and Yu, S.: Recent advances in hydrothermal syntheses of low dimensional nanoarchitectures. Int. J. Nanotechnol. 4, 129 (2007).CrossRefGoogle Scholar
26.Deng, H., Wang, J., Peng, Q., Wang, X., and Li, Y.: Controlled hydrothermal synthesis of bismuth oxyhalide nanobelts and nanotubes. Chem. Eur. J. 11, 6519 (2005).Google Scholar
27.Jiang, Z., Yang, F., Yang, G., Kong, L., Jones, M.O., Xiao, T., and Edwards, P.P.: The hydrothermal synthesis of BiOBr flakes for visible-light-responsive photocatalytic degradation of methyl orange. J. Photochem. Photobiol. A 212, 8 (2010).Google Scholar
28.Song, S., Gao, W., Wang, X., Li, X., Liu, D., Xing, Y., and Zhang, H.: Microwave-assisted synthesis of BiOBr/graphene nanocomposites and their enhanced photocatalytic activity. Dalton Trans. 41, 10472 (2012).Google Scholar
29.Cao, J., Xu, B., Lin, H., Luo, B., and Chen, S.: Chemical etching preparation of BiOI/BiOBr heterostructures with enhanced photocatalytic properties for organic dye removal. Chem. Eng. J. 91, 185 (2012).Google Scholar
30.Rao, J.L., Raju, B.D.P., Gopal, N.O., and Narasimhulu, K.V.: Electron paramagnetic resonance and optical absorption studies on Mn2+ ions doped in KZnClSO4·3H2O single crystals. Phys. B 355, 207 (2012).Google Scholar
31.Ye, L., Liu, J., Gong, C., Tian, L., Peng, T., and Zan, L.: Two different roles of metallic Ag on Ag/AgX/BiOX (X = Cl, Br) visible light photocatalysts: surface plasmon resonance and Z-scheme bridge. ACS Catal. 2, 1677 (2012).Google Scholar
32.Abdollahi, Y., Abdullah, A.H., Zainal, Z., and Yusof, N.A.: Synthesis and characterization of Manganese doped ZnO nanoparticles. Inter. J. Basic Appl. Sci. 11, 62 (2011).Google Scholar
33.Liu, L., Zuo, R., Sun, Q., and Liang, Q.: Structure and electrical properties of Mn doped Bi(Mg1/2Ti1/2)O3-PbTiO3 ferroelectric thin films. Appl. Surf Sci. 268, 327 (2013).CrossRefGoogle Scholar
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