Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-30T07:42:51.208Z Has data issue: false hasContentIssue false
  • English
  • Français

PdAg-decorated three-dimensional reduced graphene oxide-multi-walled carbon nanotube hierarchical nanostructures for high-performance hydrogen peroxide sensing

Published online by Cambridge University Press:  11 May 2018

Aytekin Uzunoglu Open the ORCID record for Aytekin Uzunoglu [Opens in a new window] ,
Dursun Ali Kose ,
Kazim Kose ,
Ebru Gokmese  and
Faruk Gokmese
Aytekin Uzunoglu*
Affiliation:
Metallurgical and Materials Engineering, Faculty of Engineering and Architecture, Necmettin Erbakan University, Konya, Turkey Alaca Avni Celik Vocational School, Hitit University, Corum, Turkey
Dursun Ali Kose
Affiliation:
Department of Chemistry, Faculty of Science and Literature, Hitit University, Corum, Turkey
Kazim Kose
Affiliation:
Alaca Avni Celik Vocational School, Hitit University, Corum, Turkey
Ebru Gokmese
Affiliation:
Department of Chemistry, Faculty of Science and Literature, Hitit University, Corum, Turkey
Faruk Gokmese
Affiliation:
Department of Chemistry, Faculty of Science and Literature, Hitit University, Corum, Turkey
*
Address all correspondence to Aytekin Uzunoglu at [email protected], [email protected]
Get access

Abstract

High-performance electrochemical hydrogen peroxide (H2O2) sensors based on PdAg nanoparticle-decorated reduced graphene oxide (rGO) and multi-walled carbon nanotube (MWCNT) hybrids were developed. The nanostructures were characterized using transmission electron microscopy, scanning electron microscopy, energy-dispersive spectroscopy, thermogravimetric analysis, Fourier transform spectroscopy, and x-ray diffraction techniques. It was found that introduction of MWCNT in the catalyst layer improved the sensitivity and widened the linear range. Sensitivities of 393.2, 437.1, and 576.6 µA/mM/cm2 were obtained for PdAg/rGO–MWCNT (2:1), PdAg/rGO–MWCNT (1:1), and PdAg/rGO–MWCNT (1:2), respectively. Furthermore, hierarchical structure of rGO–MWCNT nanohybrids enabled the detection of H2O2 up to 80 mM.

Type
2D Nanomaterials for Healthcare and Lab-on-a-Chip Devices Research Letters
Information
MRS Communications , Volume 8 , Issue 3 , September 2018 , pp. 680 - 686
Check for updates
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Chen, X., Wu, G., Cai, Z., Oyama, M., and Chen, X.: Advances in enzyme-free electrochemical sensors for hydrogen peroxide, glucose, and uric acid. Microchim. Acta 181, 689–705 (2014).Google Scholar
2.Liu, W., Hiekel, K., Hubner, R., Sun, H.J., Ferancova, A., and Sillanpaa, M.: Pt and Au bimetallic and monometallic nanostructured amperometric sensors for direct detection of hydrogen peroxide: influences of bimetallic effect and silica support. Sens. Actuators B – Chem. 255, 1325–1334 (2018).Google Scholar
3.Wang, F., Han, R., Liu, G.T., Chen, H.F., Ren, T.R., Yang, H.F., and Wen, Y.: Construction of polydopamine/silver nanoparticles multilayer film for hydrogen peroxide detection. J. Electroanal. Chem. 706, 102–107 (2013).Google Scholar
4.Bae, Y.S., Kang, S.W., Seo, M.S., Baines., I.C, Tekle, E., Chock, P.B., and Rhee, S.G.: Epidermal growth factor (EGF)-induced generation of hydrogen peroxide – role in EGF receptor-mediated tyrosine phosphorylation. J. Biol. Chem. 272, 217–221 (1997).Google Scholar
5.Chung, M.K., Asgar, J., Lee, J., Shim, M.S., Dumler, C., and Ro, J.Y.: The role of trpm2 in hydrogen peroxide-induced expression of inflammatory cytokine and chemokine in rat trigeminal ganglia. Neuroscience 297, 160–169 (2015).Google Scholar
6.Rojkind, M., Dominguez-Rosales, J.A., Nieto, N., and Greenwel, P.: Role of hydrogen peroxide and oxidative stress in healing responses. Cell. Mol. Life Sci. 59, 1872–1891 (2002).Google Scholar
7.Uzer, A, Durmazel, S., Ercag, E., and Apak, R.: Determination of hydrogen peroxide and triacetone triperoxide (TATP) with a silver nanoparticles-based turn-on colorimetric sensor. Sens. Actuators B – Chem. 247, 98–107 (2017).Google Scholar
8.Gimeno, P., Bousquet, C., Lassu, N., Maggio, A.F., Civade, C., Brenier, C., and Lempereur, L.: High-performance liquid chromatography method for the determination of hydrogen peroxide present or released in teeth bleaching kits and hair cosmetic products. J. Pharm. Biomed. Anal. 107, 386–393 (2015).Google Scholar
9.Song, M.R., Wang, J.L., Chen, B.Y., and Wang, L.: A facile, nonreactive hydrogen peroxide (H2O2) detection method enabled by ion chromatography with uv detector. Anal. Chem. 89, 11537–11544 (2017).Google Scholar
10.Pinkernell, U., Luke, H.J., and Karst, U.: Selective photometric determination of peroxycarboxylic acids in the presence of hydrogen peroxide. Analyst 122, 567–571 (1997).Google Scholar
11.Uzunoglu, A., Scherbarth, A.D., and Stanciu, L.: Bimetallic PdCu/SPCE non-enzymatic hydrogen peroxide sensors. Sens. Actuators, B 220, 968–976 (2015).Google Scholar
12.Biswas, C., and Lee, Y.H.: Graphene versus carbon nanotubes in electronic devices. Adv. Funct. Mater. 21, 3806–3826 (2011).Google Scholar
13.Serp, P., Corrias, M., and Kalck, P.: Carbon nanotubes and nanofibers in catalysis. Appl. Catal. a – Gen. 253, 337–358 (2003).Google Scholar
14.Bas, S.Z.: Gold nanoparticle functionalized graphene oxide modified platinum electrode for hydrogen peroxide and glucose sensing. Mater. Lett. 150, 20–23 (2015).Google Scholar
15.Tian, Y., Wang, F., Liu, Y., Pang, F., and Zhang, X.: Green synthesis of silver nanoparticles on nitrogen-doped graphene for hydrogen peroxide detection. Electrochim. Acta 146, 646–653 (2014).Google Scholar
16.Shao, Y.Y., Wang, J., Wu, H., Liu, J., Aksay, I.A., and Lin, Y.H.: graphene based electrochemical sensors and biosensors: a review. Electroanalysis 22, 1027–1036 (2010).Google Scholar
17.Liu, Y.D., Wang, F.Q., Wang, X.M., Wang, X.Z., Flahaut, E., Liu, X.L., Li, Y., Wang, X.R., Xu, Y.B., Shi, Y., and Zhang, R.: Planar carbon nanotube-graphene hybrid films for high-performance broadband photodetectors. Nat. Commun. 6, 8589 (2015).Google Scholar
18.Fan, Z.J., Yan, J., Zhi, L.J., Zhang, Q., Wei, T., Feng, J., Zhang, M.L., Qian, W.Z., and Wei, F.A.: Three-dimensional carbon nanotube/graphene sandwich and its application as electrode in supercapacitors. Adv. Mater. 22, 3723 (2010).Google Scholar
19.Cui, X., Wu, S., Li, Y., and Wan, G.: Sensing hydrogen peroxide using a glassy carbon electrode modified with in-situ electrodeposited platinum-gold bimetallic nanoclusters on a graphene surface. Microchim. Acta 182, 265–272 (2015).Google Scholar
20.Sophia, J. and Muralidharan, G.: Polyvinylpyrrolidone stabilized palladium nanospheres as simple and novel electrochemical sensor for amperometric hydrogen peroxide detection. J. Electroanal. Chem. 739, 115–121 (2015).Google Scholar
21.Campelo, J.M., Luna, D., Luque, R., Marinas, J.M., and Romero, A.A.: Sustainable preparation of supported metal nanoparticles and their applications in catalysis. ChemSusChem. 2, 18–45 (2009).Google Scholar
22.Uzunoglu, A., Song, S., and Stanciu, L.A.: A sensitive electrochemical H2O2 sensor based on pdag-decorated reduced graphene oxide nanocomposites. J. Electrochem. Soc. 163, B379–B384 (2016).Google Scholar
23.Kim, S.H., Jeong, G.H., Choi, D., Yoon, S., Jeon, H.B., Lee, S.M., and Kim, S.W.: Synthesis of noble metal/graphene nanocomposites without surfactants by one-step reduction of metal salt and graphene oxide. J. Colloid Interface Sci. 389, 85–90 (2013).Google Scholar
24.Wang, A.J., Yu., W., Huang, Z.P., Zhou, F., Song, J.B., Song, Y.L., Long, L.L., Cifuentes, M.P., Humphrey, M.G., Zhang, L., Shao, J.D., and Zhang, C.: Covalent functionalization of reduced graphene oxide with porphyrin by means of diazonium chemistry for nonlinear optical performance. Sci. Rep. 6, 23325 (2016).Google Scholar
25.Zhao, J., Liu, L., and Li, F.: Graphene Oxide: Physics and Applications (Springer-Verlag Berlin and Heidelberg GmbH & Co. KG, Berlin, Germany, 2015).Google Scholar
26.Tajabadi, M.T., Basirun, W.J., Lorestani, F., Zakaria, R., Baradaran, S., Amin, Y.M., Mahmoudian, M.R., Rezayi, M., and Sookhakian, M.: Nitrogen-doped graphene-silver nanodendrites for the non-enzymatic detection of hydrogen peroxide. Electrochim. Acta 151, 126–133 (2015).Google Scholar
27.Palanisamy, S., Lee, H.F., Chen, S.M., and Thirumalraj, B.: An electrochemical facile fabrication of platinum nanoparticle decorated reduced graphene oxide; application for enhanced electrochemical sensing of H2O2. RSC Adv. 5, 105567–105573 (2015).Google Scholar
28.Lorestani, F., Shahnavaz, Z., Mn, P., Alias, Y., and Manan, S.A.: One-step hydrothermal green synthesis of silver nanoparticle-carbon nanotube reduced-graphene oxide composite and its application as hydrogen peroxide sensor. Sens. Actuators, B 208, 389–398 (2015).Google Scholar
Supplementary material: File

Uzunoglu et al. supplementary material

Figures S1-S6

Download Uzunoglu et al. supplementary material(File)
File 390.5 KB