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NaA zeolite synthesis from geopolymer precursor

Published online by Cambridge University Press:  10 October 2011

Cui Xuemin*
Affiliation:
Guangxi Key Lab of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, P.R. China
He Yan
Affiliation:
Guangxi Key Lab of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, P.R. China
Liu Leping
Affiliation:
Guangxi Key Lab of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, P.R. China
Chen Jinyu
Affiliation:
Guangxi Key Lab of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, P.R. China
*
Address all correspondence to Cui Xuemin at [email protected]
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Abstract

This study confirms the existence of several nanometer-ordered structures in amorphous Al2O3–2SiO2–Na2O–7H2O geopolymers by high-resolution transmission electron microscopy and selected area electron diffraction. The composition ratio of the geopolymers was designed according to the NaA zeolite composition (Si/Al/Na atom ratio of 1:1:1), and the expected NaA molecular sieve was achieved by the Al2O3–2SiO2–Na2O–7H2O geopolymers through a hydrothermal reaction. This design concept was used to convert geopolymers into zeolite molecular sieves and provides a new preparation method for zeolite membranes or zeolite bulk materials.

Type
Rapid Communications
Copyright
Copyright © Materials Research Society 2011

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References

1.Davidovits, J.: Geopolymers: inorganic polymeric new materials. J. Therm. Anal. 37, 1633 (1991).CrossRefGoogle Scholar
2.van Jaarsveld, J.G.S., van Deventer, J.S.J., and Lukey, G.C.: The effect of composition and temperature on the properties of fly ash- and kaolinite-based geopolymers. Chem. Eng. J. 89, 63 (2002).Google Scholar
3.Provis, J.L., Lukey, G.C., and Deventer, J.: Do geopolymers actually contain nanocrystalline zeolites? A reexamination of existing results. Chem. Mater. 17, 3075 (2005).CrossRefGoogle Scholar
4.van Jaarsveld, J.G.S.: The physical and chemical characteristics of fly ash based geopolymers. Ph.D. Thesis, University of Melbourne, Melbourne, Australia, 2000.Google Scholar
5.Bell, J.L., Sarin, P., Provis, J.L., Haggerty, R.P., Driemeyer, P.E., Chupas, P.J., van Deventer, J.S.J., and Kriven, W.M.: Atomic structure of a cesium aluminosilicate geopolymer: a pair distribution function study. Chem. Mater. 20, 4768 (2008).Google Scholar
6.Cui, X.M., Liu, L.P., Zheng, G.J., Wang, R.P., and Lu, J.P.: Characterization of chemosynthetic Al2O3–2SiO2 geopolymers. J. Non-Crystalline Solids 356, 72 (2010).CrossRefGoogle Scholar
7.Brew, D.R.M. and MacKenzie, K.J.D.: Geopolymer synthesis using silica fume and sodium aluminate. J. Mater. Sci. 42, 3990 (2007).CrossRefGoogle Scholar
8.Xu, R.R. and Pang, W.Q.: Chemistry-Zeolite and Porous Materials (Science Press, Beijing, China, 2004).Google Scholar
9.Thompsom, R.W. and Huber, M.J.: Analysis of the growth of molecular sieve zeolite NaA in a batch precipitation system. J. Cryst. Growth 56, 771 (1982).Google Scholar
10.Stojkovic, S.R. and Adandjevic, B.: Investigation of the NaA zeolite crystallization mechanism by I.R. spectroscopy. Zeolites 8, 523 (1988).Google Scholar
11.Baerlocher, C., Meier, W.M., and Olson, D.H.: Atlas of Zeolite Framework Types, 5th revised ed. (Elsevier, Amsterdam, 2001).Google Scholar