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Electrospun carbon nanofiberic coated with ambutan-like NiCo2O4 microspheres as electrode materials

Published online by Cambridge University Press:  01 March 2017

Hua Chen ,
Guohua Jiang ,
Weijiang Yu ,
Depeng Liu ,
Yongkun Liu ,
Lei Li  and
Qin Huang
Hua Chen
Affiliation:
Department of Polymer Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
Guohua Jiang*
Affiliation:
Department of Polymer Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China National Engineering Laboratory for Textile Fiber Materials and Processing Technology (Zhejiang), Hangzhou 310018, People's Republic of China Key Laboratory of Advanced Textile Materials and Manufacturing Technology (ATMT), Ministry of Education, Hangzhou 310018, People's Republic of China
Weijiang Yu
Affiliation:
Department of Polymer Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
Depeng Liu
Affiliation:
Department of Polymer Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
Yongkun Liu
Affiliation:
Department of Polymer Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
Lei Li
Affiliation:
Department of Polymer Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
Qin Huang
Affiliation:
Department of Polymer Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
*
Address all correspondence to Guohua Jiang at [email protected]
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Abstract

The novel Three-dimensional rambutan-like NiCo2O4 microspheres have been successfully coated onto surface of carbon nanofibers (CNFs) to form NiCo2O4–CNFs hybrids. The composition and microstructure of NiCo2O4–CNFs were characterized by the field-emission scanning electronmicroscopy, x-ray photoelectron spectroscopy, transmission electron microscopy, and x-ray diffractometer. The obtained NiCo2O4–CNFs exhibited a specific capacity of 160 mAh/g at 1 mA/cm2 in 2 M potassium hydroxide aqueous solution. The specific capacity gradually increases with the increasing of cycles; and after 3000 cycles, the specific capacity still can be remained over 90%.

Type
Research Letters
Information
MRS Communications , Volume 7 , Issue 1 , March 2017 , pp. 90 - 96
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Copyright
Copyright © Materials Research Society 2017 

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References

1. Chang, J., Sun, J., Xu, C., Xu, H., and Gao, L.: Template-free approach to synthesize hierarchical porous nickel cobalt oxides for supercapacitors. Nanoscale 4, 6786 (2012).CrossRefGoogle ScholarPubMed
2. Zhang, G., and Lou, X.: General solution growth of mesoporous NiCo2O4 nanosheets on various conductive substrates as high-performance electrodes for supercapacitors. Adv. Mater. 25, 976 (2013).CrossRefGoogle ScholarPubMed
3. Gong, Y., Yang, S., Zhan, L., Ma, L., Vajtai, R., and Ajayan, P.: Bottom-up approach to build 3D architectures from nanosheets for superior lithium storage. Adv. Funct. Mater. 24, 125 (2014).CrossRefGoogle Scholar
4. Yu, M., Qiu, W., Wang, F., and Tong, Y.: Three dimensional architectures: design, assembly and application in electrochemical capacitors. J. Mater. Chem. A 3, 15792 (2015).CrossRefGoogle Scholar
5. Wang, Y., Pan, A., Zhu, Q., Nie, Z., Zhang, Y., Tang, Y., Liang, S., and Cao, G.: Facile synthesis of nanorod-assembled multi-shelled Co3O4 hollow microspheres for high-performance supercapacitors. J. Power Sources 272, 107 (2014).CrossRefGoogle Scholar
6. Alenezi, M.R., Henley, S.J., Emerson, N.G., and Silva, S.R.P.: From 1D and 2D ZnO nanostructures to 3D hierarchical structures with enhanced gas sensing properties. Nanoscale 6, 235 (2014).CrossRefGoogle ScholarPubMed
7. Wang, J., Xin, H.L., Zhu, J., Liu, S., Wu, Z., and Wang, D.: 3D hollow structured Co2FeO4/MWCNT as an efficient non-precious metal electrocatalyst for oxygen reduction reaction. J. Mater. Chem. A 3, 1601 (2015).CrossRefGoogle Scholar
8. Yang, M. and Jin, X.: Facile synthesis of Zn2GeO4 nanorods toward improved photocatalytic reduction of CO2 into renewable hydrocarbon fuel. J. Cent. South Univ. 7, 2837 (2014).CrossRefGoogle Scholar
9. Jiang, G., Wei, Z., Chen, H., Du, X., Li, L., Liu, Y., Huang, Q., and Chen, W.: Preparation of novel carbon nanofibers with BiOBr and AgBr decorating for photocatalytic degradation of rhodamine B. RSC Adv. 5, 30433 (2015).CrossRefGoogle Scholar
10. Jiang, G., Tang, B., Chen, H., Liu, Y., Li, L., Huang, Q., and Chen, W.: Controlled growth of hexagonal Zn2GeO4 nanorods on carbon fibers for photocatalytic oxidation of p-toluidine. RSC Adv. 2015 5, 25801 (2015).Google Scholar
11. Jiang, G., Li, X., Wei, Z., Jiang, T., Du, X., and Chen, W.: Growth of N-doped BiOBr nanosheets on carbon fibers for high efficient photocatalytic degradation of organic pollutants under visible light irradiation. Powder. Technol. 260, 84 (2014).CrossRefGoogle Scholar
12. Chen, H., Jiang, G., Yu, W., Liu, D., Liu, Y., Li, L., Huang, Q., and Tong, Z.: Electrospun carbon nanofibers coated with urchinlike ZnCo2O4 nanosheets as a flexible electrode material. J. Mater. Chem. A 4, 5958 (2016).CrossRefGoogle Scholar
13. Zhang, L. and Gong, H.: A cheap and non-destructive approach to increase coverage/loading of hydrophilic hydroxide on hydrophobic carbon for lightweight and high-performance supercapacitors. Sci. Rep. 5, 18108 (2015).CrossRefGoogle ScholarPubMed
14. Yu, M., Ma, Y., Liu, J., and Li, S.: Polyaniline nanocone arrays synthesized on three-dimensional graphene network by electrodeposition for supercapacitor electrodes. Carbon 87, 98 (2015).CrossRefGoogle Scholar
15. Wu, F., Ma, X., Feng, J., Qian, Y., and Xiong, S.: 3D Co3O4 and CoO@C wall arrays: morphology control, formation mechanism, and lithium-storage properties. J. Mater. Chem. A 2, 11597 (2014).CrossRefGoogle Scholar
16. Mohamed, S.G., Chen, C.-J., Chen, C.K., Hu, S.-F., and Liu, R.-S.: High-performance lithium-ion battery and symmetric supercapacitors based on FeCo2O4 nanoflakes electrodes. ACS Appl. Mater. Interfaces 6, 22701 (2014).CrossRefGoogle ScholarPubMed
17. Wang, B., Li, X., Luo, B., Hao, L., Zhou, M., Zhang, X., Fan, Z., and Zhi, L.: Approaching the downsizing limit of silicon for surface-controlled lithium storage. Adv. Mater. 27, 1526 (2015).CrossRefGoogle ScholarPubMed
18. Liu, X., Zhang, J., Si, W., Xi, L., Eichler, B., Yan, C., and Schmidt, O.G.: Sandwich nanoarchitecture of Si/reduced graphene oxide bilayer nanomembranes for Li-ion batteries with long cycle life. ACS Nano 9, 1198 (2015).CrossRefGoogle ScholarPubMed
19. Li, D., Ding, L., Wang, S., Cai, D., and Wang, H.: Ultrathin and highly-ordered CoO nanosheet arrays for lithium-ion batteries with high cycle stability and rate capability. J. Mater. Chem. A 2, 5625 (2014).CrossRefGoogle Scholar
20. Guan, B., Guo, D., Hu, L., Zhang, G., Fu, T., Ren, W., Li, J., and Li, Q.: Facile synthesis of ZnCo2O4 nanowire cluster arrays on Ni foam for high-performance asymmetric supercapacitors. J. Mater. Chem. A 2, 16116 (2014).CrossRefGoogle Scholar
21. Shen, L., Yu, L., Yu, X., Zhang, X., and Lou, X.W.: Self-templated formation of uniform NiCo2O4 hollow spheres with complex interior structures for lithium-ion batteries and supercapacitors. Angew. Chem. Int. Ed. 54, 1868 (2015).CrossRefGoogle ScholarPubMed
22. Yuan, C., Li, J., Hou, L., Zhang, X., Shen, L., and Lou, X.W.: Ultrathin mesoporous NiCo2O4 nanosheets supported on Ni foam as advanced electrodes for supercapacitors. Adv. Funct. Mater. 22, 4592 (2012).CrossRefGoogle Scholar
23. Van, H., Lamiel, C., and Shim, J.-J.: Mesoporous 3D graphene@NiCo2O4 arrays on nickel foam as electrodes for high-performance supercapacitors. Mater. Lett. 170, 105 (2016).Google Scholar
24. Xiong, W., Gao, Y., Wu, X., Hu, X., Lan, D., Chen, Y., Pu, X., Zeng, Y., Su, J., and Zhu, Z.: Composite of macroporous carbon with honeycomb-like structure from mollusc shell and NiCo2O4 nanowires for high-performance supercapacitor. ACS Appl. Mater. Interfaces 6, 19416 (2014).CrossRefGoogle ScholarPubMed
25. Li, L., Chai, S.-H., Dai, S., and Manthiram, A.: Advanced hybrid Li–air batteries with high-performance mesoporous nanocatalysts. Energy Environ. Sci. 7, 2630 (2014).CrossRefGoogle Scholar
26. Li, B., Feng, J., Qian, Y., and Xiong, S.: Mesoporous quasi-single-crystalline NiCo2O4 superlattice nanoribbons with optimizable lithium storage properties. J. Mater. Chem. A 3, 10336 (2015).CrossRefGoogle Scholar
27. Pu, J., Wang, T., Wang, H., Tong, Y., Lu, C., Kong, W., and Wang, Z.: Direct growth of NiCo2S4 nanotube arrays on nickel foam as high-performance binder-free electrodes for supercapacitors. ChemPlusChem 79, 577 (2014).CrossRefGoogle Scholar
28. Li, J., Xiong, S., Liu, Y., Ju, Z., and Qian, Y.: High electrochemical performance of monodisperse NiCo2O4 mesoporous microspheres as an anode material for Li-ion batteries. ACS Appl. Mater. Interfaces 5, 981 (2013).CrossRefGoogle ScholarPubMed
29. Zhu, Y., Pu, X., Song, W., Wu, Z., Zhou, Z., He, X., Lu, F., Jing, M., Tang, B., and Ji, X.: High capacity NiCo2O4 nanorods as electrode materials for supercapacitor. J. Alloys Compd. 617, 988 (2014).CrossRefGoogle Scholar
30. Gu, L., Qian, L., Lei, Y., Wang, Y., Li, J., Yuan, H., and Xiao, D.: Microwave-assisted synthesis of nanosphere-like NiCo2O4 consisting of porous nanosheets and its application in electro-catalytic oxidation of methanol. J. Power Sources 261, 317 (2014).CrossRefGoogle Scholar
31. Yang, J., Yu, C., Fan, X., Ling, Z., Qiu, J., and Gogotsi, Y.: Facile fabrication of MWCNT doped NiCoAl-layered double hydroxide nanosheets with enhanced electrochemical performances. J. Mater. Chem. A 1, 1963 (2013).CrossRefGoogle Scholar
32. Liu, B., Zhang, Y., and Tang, L.: X-ray photoelectron spectroscopic studies of Ba0.5Sr0.5Co0.8Fe0.2O3−d cathode for solid oxide fuel cells. Int. J. Hydrog. Energy 34, 435 (2009).CrossRefGoogle Scholar
33. Zhou, X., Chen, G., Tang, J., Ren, Y., and Yang, J.: One-dimensional NiCo2O4 nanowire arrays grown on nickel foam for high-performance lithium-ion batteries. J. Power Sources 299, 97 (2015).CrossRefGoogle Scholar
34. Marco, J.F., Gancedo, J.R., Gracia, M., Gautier, J.L., Rios, E., and Berry, F.J.: Characterization of the nickel cobaltite, NiCo2O4, prepared by several methods: an XRD, XANES, EXAFS, and XPS study. J. Solid State Chem. 153, 74 (2000).CrossRefGoogle Scholar
35. Dupin, J.-C., Gonbeau, D., Vinatier, P., and Levasseur, A.: Systematic XPS studies of metal oxides, hydroxides and peroxides. Phys. Chem. Chem. Phys. 2, 1319 (2000).CrossRefGoogle Scholar
36. Chen, H., Jiang, G., Yu, W., Liu, D., Liu, Y., Li, L., Huang, Q., Tong, Z., and Chen, W.: Preparation of electrospun ZnS-loaded hybrid carbon nanofibericmembranes for photocatalytic applications. Powder Technol. 298, 1 (2016).CrossRefGoogle Scholar
37. Brousse, T., Bélanger, D., and Long, J.: To be or not to be pseudocapacitive? batteries and energy storage. J. Electrochem. Soc. 162, A5185 (2015).CrossRefGoogle Scholar
38. Huang, T., Zhao, C., Wu, L., Lang, X., Liu, K., and Hu, Z.: 3D network-like porous MnCo2O4 by the sucrose-assisted combustion method for high-performance supercapacitors. Ceram. Int. 43, 1968 (2017).CrossRefGoogle Scholar
39. Yu, M., Sun, H., Sun, X., Lu, F., Wang, G., Hu, T., Qiu, H., and Lian, J.: Hierarchical Al-doped and hydrogenated ZnO nanowire@MnO2 ultra thin nanosheet core/shell arrays for high performance supercapacitor electrode. Int. J. Electrochem. Sci. 8, 2313 (2013).CrossRefGoogle Scholar