Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-30T07:40:38.891Z Has data issue: false hasContentIssue false
  • English
  • Français

Electrocatalytic activity of high-entropy alloys toward oxygen evolution reaction

Published online by Cambridge University Press:  09 July 2018

Xiaodan Cui ,
Boliang Zhang ,
Congyuan Zeng  and
Shengmin Guo Open the ORCID record for Shengmin Guo [Opens in a new window]
Xiaodan Cui
Affiliation:
Department of Mechanical & Industrial Engineering, Louisiana State University, Baton Rouge, Louisiana 70803, USA
Boliang Zhang
Affiliation:
Department of Mechanical & Industrial Engineering, Louisiana State University, Baton Rouge, Louisiana 70803, USA
Congyuan Zeng
Affiliation:
Department of Mechanical & Industrial Engineering, Louisiana State University, Baton Rouge, Louisiana 70803, USA
Shengmin Guo*
Affiliation:
Department of Mechanical & Industrial Engineering, Louisiana State University, Baton Rouge, Louisiana 70803, USA
*
Address all correspondence to Shengmin Guo at [email protected]
Get access

Abstract

Due to the special crystal structures and electron configurations, high-entropy alloys (HEAs) are expected to have favorable activities for electrocatalytic reactions. In this paper, a set of oxygen evolution reaction (OER) criteria are applied for the HEA-based electrocatalyst design. Specifically, FeNiMnCrCu HEA is predicted to have a better OER performance than the baseline FeCoNiCrAl HEA. To demonstrate this design approach, both FeNiMnCrCu and FeCoNiCrAl samples are prepared and tested. Their crystal structures and electrocatalytic performance are examined. This paper demonstrates the potential of using finely tuned HEAs for OER applications.

Type
Research Letters
Information
MRS Communications , Volume 8 , Issue 3 , September 2018 , pp. 1230 - 1235
Check for updates
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Stojić, D.L., Marčeta, M.P., Sovilj, S.P., and Miljanić, Š.S.: Hydrogen generation from water electrolysis—possibilities of energy saving. J. Power Sources 118, 315 (2003).Google Scholar
2.Lee, Y., Suntivich, J., May, K.J., Perry, E.E., and Shao-Horn, Y.: Synthesis and activities of rutile IrO2 and RuO2 nanoparticles for oxygen evolution in acid and alkaline solutions. J. Phys. Chem. Lett. 3, 399 (2012).Google Scholar
3.Faber, M.S. and Jin, S.: Earth-abundant inorganic electrocatalysts and their nanostructures for energy conversion applications. Energy Environ. Sci. 7, 3519 (2014).Google Scholar
4.Liu, A., Chen, Z., Wei, X., Xiao, W., and Ding, J.: Economical Fe-doped Ta2O5 electrocatalyst toward efficient oxygen evolution: a combined experimental and first-principles study. MRS Commun. 7, 563 (2017).Google Scholar
5.Fei, L., Min, Z., Yuxue, Z., and Xianghua, Z.: First-row transition metal based catalysts for the oxygen evolution reaction under alkaline conditions: basic principles and recent advances. Small 13, 1701931 (2017).Google Scholar
6.Zhang, B., Mu, Y., Gao, M.C., Meng, W.J., and Guo, S.M.: On single-phase status and segregation of an as-solidified septenary refractory high entropy alloy. MRS Commun. 7, 78 (2017).Google Scholar
7.Wang, J., Zhang, Y., Niu, S.Z., Wang, W.Y., Kou, H.C., Li, J.S., Wang, S.Q., and Beaugnon, E.: Formation of a hexagonal closed-packed phase in Al0.5CoCrFeNi high entropy alloy. MRS Commun. 7, 879 (2017).Google Scholar
8.Miracle, D.B. and Senkov, O.N.: A critical review of high entropy alloys and related concepts. Acta Mater. 122, 448 (2017).Google Scholar
9.Wang, Z., Qiu, W., Yang, Y., and Liu, C.T.: Atomic-size and lattice-distortion effects in newly developed high-entropy alloys with multiple principal elements. Intermetallics 64, 63 (2015).Google Scholar
10.Bak, T., Nowotny, J., Sucher, N.J., and Wachsman, E.: Effect of crystal imperfections on reactivity and photoreactivity of TiO2 (rutile) with oxygen, water, and bacteria. J. Phys. Chem. C 115, 15711 (2011).Google Scholar
11.Lv, Z.Y., Liu, X.J., Jia, B., Wang, H., Wu, Y., and Lu, Z.P.: Development of a novel high-entropy alloy with eminent efficiency of degrading azo dye solutions. Sci. Rep. 6, 34213 (2016).Google Scholar
12.Nørskov, J.K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J.R., Bligaard, T., and Jónsson, H.: Origin of the overpotential for oxygen reduction at a fuel-cell cathode. J. Phys. Chem. B 108, 17886 (2004).Google Scholar
13.Thomas, J.M. and Thomas, J.W. (Eds). Principles and Practice of Heterogeneous Catalysis. 2nd ed. 2015. ISBN: 978-3-527-31458-4.Google Scholar
14.Cui, X., Xu, W., Xie, Z., Dorman, J.A., Gutierrez-Wing, M.T., and Wang, Y.: Effect of dopant concentration on visible light driven photocatalytic activity of Sn1-xAgxS2. Dalton Trans. 45, 16290 (2016).Google Scholar
15.Brown, I.D. and Shannon, R.D.: Empirical bond-strength–bond-length curves for oxides. Acta Crystallogr. Sect. A 29, 266 (1973).Google Scholar
16.Mejias, J.A., Staemmler, V., and Freund, H.J.: Electronic states of the Cr 2 O 3 (0001) surface from ab initio embedded cluster calculations. J. Phys. Condens. Matter 11, 7881 (1999).Google Scholar
17.Caputi, L.S., Jiang, S.L., Amoddeo, A., and Tucci, R.: Oxygen-nickel bond length in Ni(111)-O determined by electron-energy-loss fine-structure spectroscopy. Phys. Rev. B 41, 8513 (1990).Google Scholar
18.Cui, X., Zhang, B., Zeng, C., Wen, H., Yao, H., and Guo, S.: Laser processed Ni-Fe alloys as electrocatalyst toward oxygen evolution reaction. Mater. Res. Express 5, 066527 (2018).Google Scholar
19.Chou, H.-P., Chang, Y.-S., Chen, S.-K., and Yeh, J.-W.: Microstructure, thermophysical and electrical properties in AlxCoCrFeNi (0 ≤ x≤2) high-entropy alloys. Mater. Sci. Eng. B 163, 184 (2009).Google Scholar
20.Ye, Y.F., Liu, C.T., and Yang, Y.: A geometric model for intrinsic residual strain and phase stability in high entropy alloys. Prog. Mater. Sci. 94, 152 (2015).Google Scholar
21.Egami, T.: Atomic level stresses. Prog. Mater. Sci. 56, 637 (2011).Google Scholar
22.Ji, W., Fu, Z., Wang, W., Wang, H., Zhang, J., Wang, Y., and Zhang, F.: Mechanical alloying synthesis and spark plasma sintering consolidation of CoCrFeNiAl high-entropy alloy. J. Alloys Compd. 589, 61 (2014).Google Scholar
23.Zhang, K.B., Fu, Z.Y., Zhang, J.Y., Wang, W.M., Wang, H., Wang, Y.C., Zhang, Q.J., and Shi, J.: Microstructure and mechanical properties of CoCrFeNiTiAlx high-entropy alloys. Mater. Sci. Eng. A 508, 214 (2009).Google Scholar
24.Zhou, T., Cao, Z., Zhang, P., Ma, H., Gao, Z., Wang, H., Lu, Y., He, J., and Zhao, Y.: Transition metal ions regulated oxygen evolution reaction performance of Ni-based hydroxides hierarchical nanoarrays. Sci. Rep. 7, 46154 (2017).Google Scholar
25.Fabbri, E., Habereder, A., Waltar, K., Kotz, R., and Schmidt, T.J.: Developments and perspectives of oxide-based catalysts for the oxygen evolution reaction. Catal. Sci. Technol. 4, 3800 (2014).Google Scholar
26.Cui, X., Xu, W., Xie, Z., and Wang, Y.: High-performance dye-sensitized solar cells based on Ag-doped SnS2 counter electrodes. J. Mater. Chem. A 4, 1908 (2016).Google Scholar
27.Cui, X., Xie, Z., and Wang, Y.: Novel CoS2 embedded carbon nanocages by direct sulfurizing metal-organic frameworks for dye-sensitized solar cells. Nanoscale 8, 11984 (2016).Google Scholar
28.Franco, D.V., Da Silva, L.M., Jardim, W.F., and Boodts, J.F.C.: Influence of the electrolyte composition on the kinetics of the oxygen evolution reaction and ozone production processes. J. Braz. Chem. Soc. 17, 746 (2006).Google Scholar