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Ecofriendly synthesis of ultra-small metal-doped SnO2 quantum dots

Published online by Cambridge University Press:  16 March 2015

Antonio Tirado-Guízar*
Affiliation:
Centro de Graduados e Investigación en Química, Instituto Tecnológico de Tijuana, A.P. 1166, Tijuana 22500, BC, México
Georgina Esther Pina-Luis
Affiliation:
Centro de Graduados e Investigación en Química, Instituto Tecnológico de Tijuana, A.P. 1166, Tijuana 22500, BC, México
Francisco Paraguay-Delgado*
Affiliation:
Departamento de Materiales Nanoestructurados, Centro de Investigación en Materiales Avanzados S. C, Av. Miguel de Cervantes 120, Complejo Industrial Chihuahua, CP 31109 Chihuahua, Chih., México
*
*Address all correspondence to Francisco Paraguay-Delgado, Antonio Tirado-Guízar at[email protected]; [email protected]
*Address all correspondence to Francisco Paraguay-Delgado, Antonio Tirado-Guízar at[email protected]; [email protected]
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Abstract

An ecofriendly synthesis is established to obtain ultra-small SnO2 nanoparticles (NPs) doped with metals by a hydrothermal method using only tin tetrachloride, urea, and water as reagents. This synthesis was done in a short period time at low temperature and without surfactants. Microscopy analysis revealed the formation of doped tin oxide NPs with a diameter smaller than 2.8 nm. Un-doped and doped tin oxides were obtained with a tetragonal type rutile structure with an average surface area of 348 m2/g.

Type
Research Letters
Copyright
Copyright © Materials Research Society 2015 

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References

1.Bruchez, M., Moronne, M., Gin, P., Weiss, S., and Alivisatos, A.P.: Semiconductor nanocrystals as fluorescent biological labels. Science 281, 2013 (1998).Google Scholar
2.Hu, W., Gao, S., Prasad, P.N., Wang, J., and Xu, J.: Emploing photoassisted ligand exchange technique in layered quantum dot LEDs. J. Nanomater. 1 15 (2012).Google Scholar
3.Subramaniam, P., Lee, S.J., Shah, S., Patel, S., Starovoytov, V., and Lee, K-B.: Generation of a library of non-toxic quantum dots for cellular imaging and siRNA delivery. Adv. Mater. 24, 4014 (2012).Google Scholar
4.Tirado-Guizar, A., Pina-Luis, G., Paraguay-Delgado, F., and Ramirez-Herrera, D.: Size-dependent enhanced energy transfer from tryptophan to CdSe/mercaptopropionic acid quantum dots: a new fluorescence resonance energy transfer nanosensor. Sci. Adv. Mater. 6, 492 (2014).CrossRefGoogle Scholar
5.Lee, E.J.H., Ribeiro, C., Giraldi, T.R., Longo, E., and Leite, E.R.: Photoluminescence in quantum-confined SnO2 nanocrystals: evidence of free exciton decay. Appl. Phys. Lett. 84, 1745 (2004).CrossRefGoogle Scholar
6.Kolmakov, A. and Moskovits, M.: Chemical sensing and catalysis by one-dimensional metal-oxide nanostructures. Annu. Rev. Mater. Res. 34, 151 (2004).CrossRefGoogle Scholar
7.Jia, T., Wang, W., Long, F., Fu, Z., Wang, H., and Zhang, Q.: Synthesis, characterization, and photocatalytic activity of Zn-doped SnO2 hierarchical architectures assembled by nanocones. J. Phys. Chem. C 113, 9071 (2009).Google Scholar
8.Rani, S., Roy, S.C., Karar, N., and Bhatnagar, M.C.: Structure, microstructure and photoluminescence properties of Fe doped SnO2 thin films. Solid State Commun. 141, 214 (2007).CrossRefGoogle Scholar
9.Fitzgerald, C.B., Venkatesan, M., Douvalis, A.P., Huber, S., and Coey, J.M.D.: SnO2 doped with Mn, Fe or Co: room temperature dilute magnetic semiconductors. J. Appl. Phys. 95, 7390 (2004).CrossRefGoogle Scholar
10.Liu, J., Chen, H., Lin, Z., and Lin, J-M.: Preparation of surface imprinting polymer capped Mn-doped ZnS quantum dots and their application for chemiluminescence detection of 4-nitrophenol in tap water. Anal. Chem. 82, 7380 (2010).CrossRefGoogle ScholarPubMed
11.Azam, A., Ahmed, A.S., Habib, S.S., and Naqvi, A.H.: Effect of Mn doping on the structural and optical properties of SnO2 nanoparticles. J. Alloys Compd. 523, 83 (2012).Google Scholar
12.Kiani, M.J., Samadi, J., and Yaghoubyan, S.H.: High sensitivity of tin oxide sensor by sol-gel method. IJ-Nano. 1, 46 (2012).Google Scholar
13.Singh, A.K. and Nakate, U.T.: Microwave synthesis, characterization and photocatalytic properties of SnO2 Nanoparticles. Adv. Nanopart. 2, 66 (2013).Google Scholar
14.Paraguay-Delgado, F., Antúnez-Flores, W., Miki-Yoshida, M., Aguilar-Elguezabal, A., Santiago, P., Diaz, R., and Ascencio, J.A.: Structural analysis and growing mechanisms for long SnO2 nanorods synthesized by spray pyrolysis. Nanotechnology 16, 688 (2005).Google Scholar
15.Tan, L., Wang, L., and Wang, Y.: Hydrothermal synthesis of SnO2 nanostructures with different morphologies and their optical propertie. J. Nanomater. 1, 1 (2011).CrossRefGoogle Scholar
16.Zhou, Z., Wu, J., Li, H., and Wang, Z.: Field emission from in situ-grown vertically aligned SnO2 nanowire arrays. Nanoscale Res. Lett. 7, 7 (2012).Google Scholar
17.Prasittichai, C. and Hupp, J.T.: Surface modification of SnO2 photoelectrodes in dye-sensitized solar cells: significant improvements in photovoltage via Al2O3 atomic layer deposition. J. Phys. Chem. Lett. 1, 1611 (2010).Google Scholar
18.Ye, J., Zhang, H., Yang, R., Li, X., and Qi, L.: Morphology-controlled synthesis of SnO2 nanotubes by using 1d silica mesostructures as sacrificial templates and their applications in lithium-ion batteries. Small 6, 296 (2010).Google Scholar
19.Lou, Z., Wang, L., Fei, T., and Zhang, T.: Enhanced ethanol sensing properties of NiO-doped SnO2 polyhedra. New J. Chem. 36, 1003 (2012).Google Scholar
20.Ji, X., Huang, X., Liu, J., Jiang, J., Li, X., Ding, R., Hu, Y., Wu, F., and Li, Q.: Carbon-coated SnO2 nanorod array for lithium-ion battery anode material. Nanoscale Res. Lett. 5, 649 (2010).Google Scholar
21.Zhu, H., Yang, D., Yu, G., Zhang, H., and Yao, K.: A simple hydrothermal route for synthesizing SnO2 quantum dots. Nanotechnology 17, 2386 (2006).Google Scholar
22.Xi, G. and Ye, J.: Ultrathin SnO2 nanorods: template- and surfactant-free solution phase synthesis, growth mechanism, optical, gas-sensing, and surface adsorption properties. Inorg. Chem. 49, 2302 (2007).CrossRefGoogle Scholar
23.Birkel, A., Loges, N., Mugnaioli, E., Branscheid, R., Frank, D.K.S., Panthöfer, M., and Tremel, W.: Interaction of alkaline metal cations with oxidic surfaces: effect on the morphology of SnO2 nanoparticles. Langmuir 26, 3590 (2010).Google Scholar
24.Huheey, J.E., Keiter, E.A., and Keiter, R.L.: Inorganic Chemistry: Principles of Structure and Reactivity (Harper Collins Collag Publishers, New York, 1993), pp. 344358.Google Scholar
25.Rietveld, H.M.: Line profiles of neutrón powder-diffraction peaks for structure refinement. Acta Crystallogr. 22, 151 (1967).CrossRefGoogle Scholar
26.Fullprof Suite Home Page: https://www.ill.eu/sites/fullprof/index.html (accessed February 2015).Google Scholar
27.Elumalai, N.K., Jose, R., Archana, P.S., Chellappan, V., and Ramakrishna, S.: Charge transport through electrospun SnO2 nanoflowers and nanofibers: role of surface trap density on electron transport dynamics. J. Phys. Chem. C 116, 22112 (2012).Google Scholar
28.Lou, X.W., Yuan, C., and Archer, L.A.: Double-walled SnO2 nano-cocoons with movable magnetic cores. Adv. Mater. 19, 3328 (2007).Google Scholar
29.Wang, C., Zhou, Y., Ge, M., Xu, X., Zhang, Z., and Jiang, J.Z.: Large-scale synthesis of SnO2 nanosheets with high lithium storage capacity. J. Am. Chem. Soc. 132, 46 (2010).Google Scholar
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