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Unique mechanical properties of fullerite derivatives synthesized with a catalytic polymerization reaction

Published online by Cambridge University Press:  25 February 2015

M. Popov Open the ORCID record for M. Popov [Opens in a new window] ,
V. Blank ,
S. Perfilov ,
D. Ovsyannikov ,
B. Kulnitskiy ,
E. Tyukalova ,
V. Prokhorov ,
I. Maslenikov ,
I. Perezhogin  and
E. Skryleva
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M. Popov*
Affiliation:
Technological Institute for Superhard and Novel Carbon Materials, 142190, 7a Centralnaya, Troitsk, Moscow, Russian Federation; National University of Science and Technology MISiS, 119049, 4 Leninskiy prospekt, Moscow, Russian Federation; Moscow Institute of Physics and Technology State University, 141700, Institutskiy per. 9, Dolgoprudny, Moscow Region, Russian Federation
V. Blank
Affiliation:
Technological Institute for Superhard and Novel Carbon Materials, 142190, 7a Centralnaya, Troitsk, Moscow, Russian Federation; National University of Science and Technology MISiS, 119049, 4 Leninskiy prospekt, Moscow, Russian Federation; Moscow Institute of Physics and Technology State University, 141700, Institutskiy per. 9, Dolgoprudny, Moscow Region, Russian Federation
S. Perfilov
Affiliation:
Technological Institute for Superhard and Novel Carbon Materials, 142190, 7a Centralnaya, Troitsk, Moscow, Russian Federation
D. Ovsyannikov
Affiliation:
Technological Institute for Superhard and Novel Carbon Materials, 142190, 7a Centralnaya, Troitsk, Moscow, Russian Federation
B. Kulnitskiy
Affiliation:
Technological Institute for Superhard and Novel Carbon Materials, 142190, 7a Centralnaya, Troitsk, Moscow, Russian Federation; Moscow Institute of Physics and Technology State University, 141700, Institutskiy per. 9, Dolgoprudny, Moscow Region, Russian Federation
E. Tyukalova
Affiliation:
Technological Institute for Superhard and Novel Carbon Materials, 142190, 7a Centralnaya, Troitsk, Moscow, Russian Federation; Moscow Institute of Physics and Technology State University, 141700, Institutskiy per. 9, Dolgoprudny, Moscow Region, Russian Federation
V. Prokhorov
Affiliation:
Technological Institute for Superhard and Novel Carbon Materials, 142190, 7a Centralnaya, Troitsk, Moscow, Russian Federation; Moscow Institute of Physics and Technology State University, 141700, Institutskiy per. 9, Dolgoprudny, Moscow Region, Russian Federation
I. Maslenikov
Affiliation:
Technological Institute for Superhard and Novel Carbon Materials, 142190, 7a Centralnaya, Troitsk, Moscow, Russian Federation; Moscow Institute of Physics and Technology State University, 141700, Institutskiy per. 9, Dolgoprudny, Moscow Region, Russian Federation
I. Perezhogin
Affiliation:
Technological Institute for Superhard and Novel Carbon Materials, 142190, 7a Centralnaya, Troitsk, Moscow, Russian Federation; Lomonosov Moscow State University, 119991, Leninskie Gory, Moscow, Russian Federation
E. Skryleva
Affiliation:
National University of Science and Technology MISiS, 119049, 4 Leninskiy prospekt, Moscow, Russian Federation
Yu Parkhomenko
Affiliation:
National University of Science and Technology MISiS, 119049, 4 Leninskiy prospekt, Moscow, Russian Federation
*
Address all correspondence to M. Popov at [email protected]
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Abstract

Fullerite derivatives synthesized with a catalytic polymerization reaction at a relatively low-pressure range of 0.5–4 GPa show unique mechanical properties: elastic recovery is 98% and hardness possibly approaches 100 GPa. Structure of the samples is also unique: one composes from fragments of C60 molecules linked by the covalent bonds. To obtain the homogeneous crack-free samples, we synthesized B4C–fullerite derivatives composite which show a 550 MPa flexural stress, a 2250 MPa compressive strength, and a 28 GPa hardness and have density of 2.2 g/cm3.

Type
Research Letters
Information
MRS Communications , Volume 5 , Issue 1 , March 2015 , pp. 71 - 75
Copyright
Copyright © Materials Research Society 2015 

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References

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