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Electronic charge transfer properties of COF-5 solutions and films with intercalated metal ions

Published online by Cambridge University Press:  20 January 2020

William S. Owen ,
Michael S. Bible ,
Emma F. Dohmeier ,
Lindsey R. Guthrie ,
Michael J. Parsons ,
Justin W. Hendrix ,
Joseph R. Hunt  and
Michael S. Lowry
William S. Owen
Affiliation:
Naval Surface Warfare Center – Dahlgren Division, Dahlgren, VA22448, USA
Michael S. Bible
Affiliation:
Naval Surface Warfare Center – Dahlgren Division, Dahlgren, VA22448, USA
Emma F. Dohmeier
Affiliation:
Naval Surface Warfare Center – Dahlgren Division, Dahlgren, VA22448, USA
Lindsey R. Guthrie
Affiliation:
Naval Surface Warfare Center – Dahlgren Division, Dahlgren, VA22448, USA
Michael J. Parsons
Affiliation:
Naval Surface Warfare Center – Dahlgren Division, Dahlgren, VA22448, USA
Justin W. Hendrix
Affiliation:
Naval Surface Warfare Center – Dahlgren Division, Dahlgren, VA22448, USA
Joseph R. Hunt
Affiliation:
Naval Surface Warfare Center – Dahlgren Division, Dahlgren, VA22448, USA
Michael S. Lowry*
Affiliation:
Naval Surface Warfare Center – Dahlgren Division, Dahlgren, VA22448, USA
*
Address all correspondence to Michael S. Lowry at [email protected]
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Abstract

To investigate the manipulation of electromagnetic properties of two-dimensional materials, this effort characterizes charge transfer behavior of colloidal COF-5 (covalent organic framework) in the presence of various metal ions. A series of metal chloride compounds was introduced to COF-5 in solution and solid film phases and the interaction of the material with electromagnetic radiation was monitored across the visible region using electronic absorption spectroscopy. Notable changes were observed, quantified, and discussed for copper (II) chloride (CuCl2), chromium (III) chloride (CrCl3), and iron (III) chloride (FeCl3) with COF-5. Ligand-to-metal and metal-to-ligand charge transfer are explored as a possible mechanism for the observed electronic behaviors.

Type
Research Letters
Information
MRS Communications , Volume 10 , Issue 1 , March 2020 , pp. 91 - 97
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Copyright
Copyright © Materials Research Society 2020

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