According to Carnot's postulate heat can give rise to work only by falling to lower temperature. This negation ensures that at each temperature a definite physical system possesses a work-function A, named by W. Thomson its available, energy at that temperature. This aspect of Carnot's postulate was enforced especially in Thomson and Tait's Nat. Phil. (1867). These available energies at different temperatures combine into one more general function, the isothermal available energy, which is a function of temperature θ as well as configuration. (Cf. the Minkowski condensation of personal spaces and times into a single universal space-time.) Thus we are entitled to assert the equation

where Ψ1r is the force exerted by the coordinate ψr of configuration. The final term in δA though regular has not to do with ostensible work: and −η, as yet arbitrary, here equal to A/θ, may be described as the thermal capacity or specific heat of available energy.