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Structure of heat-treated sol-gel SiO2 glasses containing silver

Published online by Cambridge University Press:  31 January 2011

M. G. Garníca-Romo ,
J. González-Hernández ,
M. A. Hernández-Landaverde ,
Y. V. Vorobiev ,
F. Ruiz  and
J. R. Martínez
M. G. Garníca-Romo
Affiliation:
División de Estudios de Posgrado, Facultad de Ingeniería, Universidad Autónoma de Querétaro, Querétaro, Qro., México
J. González-Hernández
Affiliation:
Centro de Investigación y de Estudios Avanzados del IPN, Unidad Querétaro, Querétaro, Qro., México
M. A. Hernández-Landaverde
Affiliation:
Centro de Investigación y de Estudios Avanzados del IPN, Unidad Querétaro, Querétaro, Qro., México
Y. V. Vorobiev
Affiliation:
Centro de Investigación y de Estudios Avanzados del IPN, Unidad Querétaro, Querétaro, Qro., México
F. Ruiz*
Affiliation:
Facultad de Ciencias, Universidad Autónoma de San Luis Potosí 78000, San Luis Potosí, S.L.P. México
J. R. Martínez
Affiliation:
Facultad de Ciencias, Universidad Autónoma de San Luis Potosí 78000, San Luis Potosí, S.L.P. México
*
a)Address all correspondence to this author.
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Abstract

The crystallization of bulk amorphous SiO2 samples, prepared by the sol-gel method, was obtained by heat treatments in air at temperatures as low as 500 °C. This occurs when silver is added to the precursor solutions in an amount such that it forms aggregates embedded in the glass. Another requirement to observe the low-temperature glass crystallization is that the bulk samples must be prepared from precursor solutions with specific compositions. These compositions, have a high H2O/TEOS ratio, which produces an amorphous SiO2 structure with some structural similarities to cristobalite, the phase in which the SiO2 glass crystallizes.

Type
Articles
Information
Journal of Materials Research , Volume 16 , Issue 7 , July 2001 , pp. 2007 - 2012
Copyright
Copyright © Materials Research Society 2001

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References

REFERENCES

1.Uhlmann, D.R., in Advances in Nucleation and Crystallization of Glasses, edited by Hench, L.L. and Freiman, S.W. (Am. Ceram. Soc., Westerville, OH, 1971), p. 91.Google Scholar
2.Wagstoff, F.E. and Richards, K.J., J. Am. Ceram. Soc. 67, 549 (1984).Google Scholar
3.Johnson, D.W. Jr., Rabinowich, E.M., MacChesney, J.B., and Vogel, E.M., J. Am. Ceram. Soc. 66, 688 (1983).CrossRefGoogle Scholar
4.Hinsch, A. and Zastrow, A., J. Non-Cryst. Solids 147, 579 (1992).CrossRefGoogle Scholar
5.Menning, M., Spanhel, J., Schmidt, H., and Betzholz, S., J. Non-Cryst. Solids 147, 326 (1992).CrossRefGoogle Scholar
6.De, G., Licciulli, A., Massaro, C., Tapfer, L., Catalano, M., Battaglin, G., Meneghini, C., and Mazzoldi, P., J. Non-Cryst. Solids 194, 225 (1996).CrossRefGoogle Scholar
7.Breitscheild, B., Zieder, J., and Schubert, U., Chem. Mater 3, 559 (1991).CrossRefGoogle Scholar
8.Brusilowsky, D., Eyal, M., and Reisfeld, R., Chem. Phys. Lett. 153, 203 (1998).CrossRefGoogle Scholar
9.Hinsch, A., Zastrow, A. and Wittwer, V., Solar Energy Mater. 21, 151 (1990).CrossRefGoogle Scholar
10.Cai, W. and Zhang, L., J. Phys.: Condens Matter 8, L591 (1996).Google Scholar
11.Magruder, R.H. III, Wittig, J.E., and Zuhr, R.A., J. Non-Cryst. Solids 163, 162 (1993).CrossRefGoogle Scholar
12.Pérez-Robles, J.F., Garcia-Cerda, L.A., Espinoza-Beltrán, F.J., Yañez-Limón, M., González-Hernández, J., Vorobiev, Y.V., Parga-Torres, J.R., Ruiz, F., and Méndez-Nonell, J., Phys. Status Solidi 172, 49 (1999).3.0.CO;2-I>CrossRefGoogle Scholar
13.Mie, G., Ann. Phys. 25, 377 (1908).CrossRefGoogle Scholar
14.Van der Hulst, H.C., in Light Scattering by Small Particles (Dover Publications, 1982).Google Scholar
15.Bates, J.B., J. Chem. Phys. 56, 1910 (1972).CrossRefGoogle Scholar
16.Bell, R.J. and Hibbins-Butler, D.C., J. Phys. C 3, 2111 (1970).CrossRefGoogle Scholar
17.Martínez-Mendoza, R., Ruiz, F., Vorobiev, Y.V., Pérez-Robles, F., and González-Hernández, J., J. Chem. Phys. 109, 751 (1998).Google Scholar
18.Pérez-Robles, J.F., Jiménez-Sandoval, S., González-Hernández, J., Vorobiev, Y.V., Parga-Torres, J.R., and Hernández-Landaverde, M.A., Rev. Mex. de Física 45, 150 (1999).Google Scholar
19.Phillips, J.C., Phys. Rev. B 33, 4443 (1986).CrossRefGoogle Scholar
20.Riegel, B., Hartmann, I., Kiefer, W., Grob, J., and Fricke, J., J. Non-Cryst. Solids 211, 294 (1997).CrossRefGoogle Scholar
21.Glaser, P.M. and Pantano, C.G., J. Non-Cryst. Solids 63, 209 (1984).CrossRefGoogle Scholar
22.Hietala, S.L., Smith, D.M., Golden, J.L. and Brinker, C.J., J. Am. Ceram. Soc. 72, 2354 (1989).CrossRefGoogle Scholar
23.Martínez-Mendoza, J.R., Ruiz, F., González-Hernández, J., González-Chávez, M.M., and Valle-Aguilera, L., Rev. Mex. de Física 44, 1757 (1998).Google Scholar
24.Pérez-Robles, J.F., García-Rodríguez, F.J., Yañez-Limón, J.M., Espinoza-Beltrán, F.J., Vorobiev, Y.V., and González-Hernández, J., J. Phys. Chem. Solids 60, 1729 (1999).CrossRefGoogle Scholar
25.Jean, J-H., Gupta, T.K., J. Mater. Res. 8, 2393 (1993).CrossRefGoogle Scholar
26.Majling, J., Znasik, P., Agrawal, D., Cheng, J., and Roy, R., J. Mater. Res. 10, 2411 (1995).CrossRefGoogle Scholar
27.Isobe, H., Tokunaga, I., Nagai, N., and Kaneko, K., J. Mater. Res. 11, 2908 (1996).CrossRefGoogle Scholar
28.Tsai, C.C., Nemanich, R.J., and Thompson, M.J., J. Vac. Sci. Technol. 21, 632 (1982).CrossRefGoogle Scholar
29.Seibt, M., Buschbaum, S., Gnauert, U., Schroter, W., and Oelgeschlager, D., Phys. Rev. Lett. 80, 774 (1998).CrossRefGoogle Scholar
30.Huang, O., Pietzonka, S., and Ulbrich, R.G., Solid State Commun. 111, 415 (1999).CrossRefGoogle Scholar
31.García-Rodriguez, F.J., González-Hernández, J., Pérez-Robles, F., Vorobiev, Y.V., Manzáno-Ramírez, A., Jiménez-Sandoval, S., and Chao, B.S., J. Raman Spectroscopy 29, 763 (1998).3.0.CO;2-I>CrossRefGoogle Scholar