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Preparation and electrochemical capacitive performance of phenolated calcium lignosulfonate-based phenol formaldehyde resin porous carbon

Published online by Cambridge University Press:  06 March 2018

Junxiu Dai
Affiliation:
School of Materials Science and Engineering, Northeast Forestry University, Haerbin 150040, People’s Republic of China
Yanli Ma*
Affiliation:
School of Materials Science and Engineering, Northeast Forestry University, Haerbin 150040, People’s Republic of China
Shixue Ren
Affiliation:
School of Materials Science and Engineering, Northeast Forestry University, Haerbin 150040, People’s Republic of China
Guizhen Fang*
Affiliation:
School of Materials Science and Engineering, Northeast Forestry University, Haerbin 150040, People’s Republic of China
*
a)Address all correspondence to these authors. e-mail: [email protected]
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Abstract

Lignin-based phenol formaldehyde resin was synthesized using phenolated calcium lignosulfonate, and porous carbon with good wettability was prepared after carbonization and potassium hydroxide (KOH) activation. The results indicated that when the KOH to the carbonized sample mass ratio was 6:1, the prepared carbon had a rich porous structure and higher surface area, with a specific surface area of 1320.13 m2/g. Furthermore, the porous carbon exhibited a maximum specific capacitance of 204.88 F/g at a current density of 0.5 A/g in the potential range −1.0 to 0 V in a 6 M KOH solution and a low equivalent series resistance of 0.64 Ω. The phenolated calcium lignosulfonate-based phenol formaldehyde resin porous carbon demonstrated a favorable electric double-layer performance.

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Article
Copyright
Copyright © Materials Research Society 2018 

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Footnotes

Contributing Editor: Tianyu Liu

References

REFERENCES

Wang, S.X., Yang, L.P., Stubbs, L.P., Li, X., and He, C.B.: Lignin-derived fused electrospun carbon fibrous mats as high performance anode materials for lithium ion batteries. ACS Appl. Mater. Interfaces 5, 12275 (2013).CrossRefGoogle ScholarPubMed
Zipp, A.: The marketability of variable renewable energy in liberalized electricity markets—An empirical analysis. Renewable Energy 113, 1111 (2017).CrossRefGoogle Scholar
Laslett, D., Carter, C., Creagh, C., and Jennings, P.: A large-scale renewable electricity supply system by 2030: Solar, wind, energy efficiency, storage and inertia for the South West Interconnected System (SWIS) in Western Australia. Renewable Energy 113, 713 (2017).CrossRefGoogle Scholar
Jiang, L.Y., Sui, Y.W., Qi, J.Q., Chang, Y., He, Y.Z., Meng, Q.K., Wei, F.X., Sun, Z., and Jin, Y.X.: Hierarchical Ni–Co layered double hydroxide nanosheets on functionalized 3D-RGO films for high energy density asymmetric supercapacitor. Appl. Surf. Sci. 426, 148 (2017).CrossRefGoogle Scholar
Zhou, J., Zhang, Z.S., Xing, W., Yu, J., Han, G.X., Si, W.J., and Zhuo, S.P.: Nitrogen-doped hierarchical porous carbon materials prepared from meta-aminophenol formaldehyde resin for supercapacitor with high rate performance. Electrochim. Acta 153, 6869 (2015).CrossRefGoogle Scholar
Zhang, L.L. and Zhao, X.S.: Carbon-based materials as supercapacitor electrodes. Chem. Soc. Rev. 38, 2520 (2009).CrossRefGoogle ScholarPubMed
Zhao, Y.F., Ran, W., He, J., Huang, Y.Z., Liu, Z.F., Liu, W., Tang, Y.F., Zhang, L., Gao, D.W., and Gao, F.M.: High-performance asymmetric supercapacitors based on multilayer MnO2/graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability. Small 11, 1310 (2015).CrossRefGoogle ScholarPubMed
Miao, L., Duan, H., Liu, M.X., Lu, W.J., Zhu, D.Z., Chen, T., Li, L.C., and Gan, L.H.: Poly(ionic liquid)-derived, N,S-codoped ultramicroporous carbon nanoparticles for supercapacitors. Chem. Eng. J. 317, 652 (2017).CrossRefGoogle Scholar
Cakici, M., Reddy, K.R., and Alonso-Marroquin, F.: Advanced electrochemical energy storage supercapacitors based on the flexible carbon fiber fabric-coated with uniform coral-like MnO2 structured electrodes. Chem. Eng. J. 309, 151 (2017).CrossRefGoogle Scholar
Xing, B.L., Huang, G.X., Chen, L.J., Zhang, C.X., and Xu, B.: Current situation and prospect of research on electrode materials for supercapacitor (in Chinese). Mater. Rev. 26, 21 (2012).Google Scholar
Xie, L.J., Sun, G.H., Su, F.Y., Guo, X.Q., Kong, Q.Q., Li, X.M., Huang, X.H., Wan, L., Song, W., Li, K.X., Lv, C.X., and Chen, C.M.: Hierarchical porous carbon microtubes derived from willow catkins for supercapacitor applications. J. Mater. Chem. A 4, 16371644 (2016).CrossRefGoogle Scholar
Zheng, Z.J. and Gao, Q.M.: Hierarchical porous carbons prepared by an easy one-step carbonization and activation of phenol–formaldehyde resins with high performance for supercapacitors. J. Power Sources 196, 1615 (2011).CrossRefGoogle Scholar
Szczureka, A., Jurewicz, K., Amaral-Labat, G., Fierro, V., Pizzi, A., and Celzard, A.: Structure and electrochemical capacitance of carbon cryogels derived from phenol–formaldehyde resins. Carbon 48, 3875 (2010).Google Scholar
Zhang, L.J., Jiang, Y.Z., Wang, L.W., Zhang, C., and Liu, S.X.: Hierarchical porous carbon nanofibers as binder-free electrode for high-performance supercapacitor. Electrochim. Acta 196, 189 (2016).CrossRefGoogle Scholar
Zhu, S., Wu, M., Ge, M.H., Zhang, H., Li, S.K., and Li, C.H.: Design and construction of three-dimensional CuO/polyaniline/rGO ternary hierarchical architectures for high performance supercapacitors. J. Power Sources 306, 594 (2016).CrossRefGoogle Scholar
Huang, Y.X., Peng, L.L., Liu, Y., Zhao, G.J., Chen, J.Y., and Yu, G.H.: Biobased nano porous active carbon fibers for high-performance supercapacitors. ACS Appl. Mater. Interfaces 8, 15205 (2016).CrossRefGoogle ScholarPubMed
Li, H., Yuan, D., Tang, C.H., Wang, S.X., Sun, J.T., Li, Z.B., Tang, T., Wang, F.K., Gong, H., and He, C.B.: Lignin-derived interconnected hierarchical porous carbon monolith with large areal/volumetric capacitances for supercapacitor. Carbon 100, 151152 (2016).CrossRefGoogle Scholar
Bleda-Martínez, M.J., Lozano-Castelló, D., Morallón, E., Cazorla-Amorós, D., and Linares-Solano, A.: Chemical and electrochemical characterization of porous carbon materials. Carbon 44, 2642 (2006).CrossRefGoogle Scholar
Wei, L. and Yushin, G.: Nanostructured activated carbons from natural precursors for electrical double layer capacitors. Nano Energy 1, 562 (2012).CrossRefGoogle Scholar
Hayashi, J., Kazehaya, A., Muroyama, K., and Watkinson, A.P.: Preparation of activated carbon from lignin by chemical activation. Carbon 38, 1873 (2000).CrossRefGoogle Scholar
Chang, J.L., Gao, Z.Y., Wang, X.R., Wu, D.P., Xu, F., Wang, X., Guo, Y.M., and Jiang, K.: Activated porous carbon prepared from paulownia flower for high performance supercapacitor electrodes. Electrochim. Acta 157, 290291 (2015).CrossRefGoogle Scholar
Hu, S.X. and Hsieh, Y.: Ultrafine microporous and mesoporous activated carbon fibers from alkali lignin. J. Mater. Chem. A 1, 11279 (2013).CrossRefGoogle Scholar
Chatterjee, S. and Saito, T.: Lignin-derived advanced carbon materials. ChemSusChem 8, 3941 (2015).CrossRefGoogle ScholarPubMed
Aro, T. and Fatehi, P.: Production and application of lignosulfonates and sulfonated lignin. ChemSusChem 10, 1862 (2017).CrossRefGoogle ScholarPubMed
Wang, J., Tang, J., Ding, B., Malgras, V., Chang, Z., Hao, X.D., Wang, Y., Dou, H., Zhang, X.G., and Yamauchi, Y.: Hierarchical porous carbons with layer-by-layer motif architectures from confined soft-template self-assembly in layered materials. Nat. Commun. 8, 5 (2017).Google ScholarPubMed
Largeot, C., Portet, C., Chmiola, J., Taberna, P., Gogotsi, Y., and Simon, P.: Relation between the ion size and pore size for an electric double-layer capacitor. J. Am. Chem. Soc. 130, 2730 (2008).CrossRefGoogle ScholarPubMed
Li, M., Li, W., and Liu, S.X.: Hydrothermal synthesis, characterization, and KOH activation of carbon spheres from glucose. Carbohydr. Res. 346, 999 (2011).CrossRefGoogle ScholarPubMed
Xue, R., Yan, J.W., Liu, X.X., Tian, Y., and Yi, B.L.: Effect of activation on the carbon fibers from phenol–formaldehyde resins for electrochemical supercapacitors. J. Appl. Electrochem. 41, 1357 (2011).CrossRefGoogle Scholar
He, J.C.: Study on preparation of LPF from phenolation modification lignin (in Chinese). Master dissertation, Northeast Forestry University, Haerbin, 2013.Google Scholar
Yu, M., Han, Y.Y., Li, J., and Wang, L.J.: CO2-activated porous carbon derived from cattail biomass for removal of malachite green dye and application as supercapacitors. Chem. Eng. J. 317, 495 (2017).CrossRefGoogle Scholar
Zhao, X., Li, W., and Liu, S.X.: Ordered mesoporous carbon membrane prepared from liquefied larch by a soft method. Mater. Lett. 126, 175 (2014).CrossRefGoogle Scholar
Zhang, L.M., You, T.T., Zhou, T., Zhou, X., and Xu, F.: Interconnected hierarchical porous carbon from lignin-derived byproducts of bioethanol production for ultra-high performance supercapacitors. ACS Appl. Mater. Interfaces 8, 13922 (2016).Google ScholarPubMed
Choi, B.G., Hong, J., Hong, W.H., Hammond, P.T., and Park, H.: Facilitated ion transport in all-solid-state flexible supercapacitors. ACS Nano 5, 7208 (2011).CrossRefGoogle ScholarPubMed