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Nonmetal element doped g-C3N4 with enhanced H2 evolution under visible light irradiation

Published online by Cambridge University Press:  08 January 2018

Yidan Luo ,
Jiaming Wang ,
Shuohan Yu ,
Yuan Cao ,
Kaili Ma ,
Yu Pu ,
Weixin Zou ,
Changjin Tang ,
Fei Gao  and
Lin Dong
Yidan Luo
Affiliation:
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People’s Republic of China; and Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210093, People’s Republic of China
Jiaming Wang
Affiliation:
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People’s Republic of China; and Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210093, People’s Republic of China
Shuohan Yu
Affiliation:
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People’s Republic of China; and Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210093, People’s Republic of China
Yuan Cao
Affiliation:
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People’s Republic of China; and Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210093, People’s Republic of China
Kaili Ma
Affiliation:
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People’s Republic of China; and Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210093, People’s Republic of China
Yu Pu
Affiliation:
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People’s Republic of China; and Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210093, People’s Republic of China
Weixin Zou*
Affiliation:
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People’s Republic of China; and Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210093, People’s Republic of China
Changjin Tang
Affiliation:
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People’s Republic of China; and Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210093, People’s Republic of China
Fei Gao
Affiliation:
Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210093, People’s Republic of China; and School of the Environmetal, Nanjing University, Nanjing 210093, People’s Republic of China
Lin Dong*
Affiliation:
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People’s Republic of China; and Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210093, People’s Republic of China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
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Abstract

Graphitic carbon nitride (g-C3N4) is considered as a promising heterogeneous catalyst for photocatalytic H2 evolution from water under visible light illustration, and its photocatalytic performance could be controlled through its texture and optical/electronic properties. Herein, we present a facile one-step heating method for the synthesis of B/P/F doped g-C3N4 photocatalysts (BCN, PCN, and FCN). The prepared photocatalysts were characterized by XRD, SEM, UV-vis absorption, FTIR, BET, XPS, PL, and photocurrent measurement. The results show that the B/P/F doping increased the interplanar stacking distance of g-C3N4, enlarged the optical absorption range, and improved the photocatalytic activity of H2 evolution. FCN exhibits the highest photocatalytic activity, followed by BCN, and PCN that has the lowest performance. This work studies the doping effects of the nonmetal elements on the photocatalytic activities, the electronic structures as well as the band gaps of g-C3N4, to provide a feasible modification pathway to design and synthesize highly efficient photocatalysts.

Keywords

g-C3N4nonmetal element dopantphotochemical H2 evolutionelectronic structure
Type
Invited Article
Information
Journal of Materials Research , Volume 33 , Issue 9: Focus Issue: Porous Carbon and Carbonaceous Materials for Energy Conversion and Storage , 14 May 2018 , pp. 1268 - 1278
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Copyright
Copyright © Materials Research Society 2018 

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Footnotes

Contributing Editor: Tianyu Liu

References

REFERENCES

Fujishima, A. and Honda, K.: Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37–38 (1972).Google Scholar
Luo, Y.D., Yu, S.H., Li, B., Dong, L.H., Wang, F., Fan, M.G., and Zhang, F.Y.: Synthesis of (Ag,F)-modified anatase TiO2 nanosheets and their enhanced photocatalytic activity. New J. Chem. 40, 2135–2144 (2016).CrossRefGoogle Scholar
Sin, J.C., Lam, S.M., Satoshi, I., Lee, K.T., and Mohamed, A.R.: Sunlight photocatalytic activity enhancement and mechanism of novel europium-doped ZnO hierarchical micro/nanospheres for degradation of phenol. Appl. Catal., B 148–149, 258–268 (2014).Google Scholar
Luo, Y., Huang, Q., Li, B., Dong, L., Fan, M., and Zhang, F.: Synthesis and characterization of Cu2O–modified Bi2O3 nanospheres with enhanced visible light photocatalytic activity. Appl. Surf. Sci. 357, 1072–1079 (2015).Google Scholar
Dong, L., Shi, H., Cheng, K., Wang, Q., Weng, W., and Han, W.: Shape-controlled growth of SrTiO3 polyhedral submicro/nanocrystals. Nano Res. 7, 1311–1318 (2014).Google Scholar
Ma, K., Yehezkeli, O., Domaille, D.W., Funke, H.H., and Cha, J.N.: Enhanced hydrogen production from DNA-assembled Z-scheme TiO2-CdS photocatalyst systems. Angew. Chem., Int. Ed. 54, 11490–11494 (2015).CrossRefGoogle ScholarPubMed
Ai, K.L., Ruan, C.P., Shen, M.X., and Lu, L.H.: MoS2 nanosheets with widened interlayer spacing for high-efficiency removal of mercury in aquatic systems. Adv. Funct. Mater. 26, 5542–5549 (2016).Google Scholar
Negishi, R., Naya, S.i., and Tada, H.: Visible light-driven selective aerobic oxidation of benzylalcohols to benzaldehydes by a Cu(acac)2-BiVO4-admicelle three-component heterosupramolecular photocatalyst. J. Phys. Chem. C 119, 11771–11776 (2015).Google Scholar
Su, Q., Sun, J., Wang, J., Yang, Z., Cheng, W., and Zhang, S.: Urea-derived graphitic carbon nitride as an efficient heterogeneous catalyst for CO2 conversion into cyclic carbonates. Catal. Sci. Technol. 4, 1556 (2014).Google Scholar
Zhou, Z., Wang, J., Yu, J., Shen, Y., Li, Y., Liu, A., Liu, S., and Zhang, Y.: Dissolution and liquid crystals phase of 2D polymeric carbon nitride. J. Am. Chem. Soc. 137, 2179–2182 (2015).Google Scholar
Zhang, Y., Liu, J., Wu, G., and Chen, W.: Porous graphitic carbon nitride synthesized via direct polymerization of urea for efficient sunlight-driven photocatalytic hydrogen production. Nanoscale 4, 5300–5303 (2012).Google Scholar
Li, H.J., Sun, B.W., Sui, L., Qian, D.J., and Chen, M.: Preparation of water-dispersible porous g-C3N4 with improved photocatalytic activity by chemical oxidation. Phys. Chem. Chem. Phys. 17, 3309–3315 (2015).Google Scholar
Zhang, M., Jiang, W., Liu, D., Wang, J., Liu, Y., Zhu, Y., and Zhu, Y.: Photodegradation of phenol via C3N4-agar hybrid hydrogel 3D photocatalysts with free separation. Appl. Catal., B 183, 263–268 (2016).CrossRefGoogle Scholar
Qin, J., Huo, J., Zhang, P., Zeng, J., Wang, T., and Zeng, H.: Improving the photocatalytic hydrogen production of Ag/g-C3N4 nanocomposites by dye-sensitization under visible light irradiation. Nanoscale 8, 2249–2259 (2016).Google Scholar
Kuriki, R., Ishitani, O., and Maeda, K.: Unique solvent effects on visible-light CO2 reduction over ruthenium(II)-complex/carbon nitride hybrid photocatalysts. ACS Appl. Mater. Interfaces 8, 6011–6018 (2016).Google Scholar
Ma, T.Y., Ran, J.R., Dai, S., Jaroniec, M., and Qiao, S.Z.: Phosphorus-doped graphitic carbon nitrides grown in situ on carbon-fiber paper: Flexible and reversible oxygen electrodes. Angew. Chem., Int. Ed. 54, 4646–4650 (2015).Google Scholar
She, X., Wu, J., Xu, H., Zhong, J., Wang, Y., Song, Y., Nie, K., Liu, Y., Yang, Y., Rodrigues, M.T.F., Vajtai, R., Lou, J., Du, D., Li, H., and Ajayan, P.M.: High efficiency photocatalytic water splitting using 2D α-Fe2O3/g-C3N4 Z-scheme catalysts. Adv. Energy Mater. 7, 1700025 (2017).Google Scholar
Zhang, G., Lan, Z.A., Lin, L., Lin, S., and Wang, X.: Overall water splitting by Pt/g-C3N4 photocatalysts without using sacrificial agents. Chem. Sci. 7, 3062–3066 (2016).Google Scholar
Gu, Q., Liao, Y., Yin, L., Long, J., Wang, X., and Xue, C.: Template-free synthesis of porous graphitic carbon nitride microspheres for enhanced photocatalytic hydrogen generation with high stability. Appl. Catal., B 165, 503–510 (2015).Google Scholar
Yan, S.C., Li, Z.S., and Zou, Z.G.: Photodegradation of rhodamine B and methyl orange over boron-doped g-C3N4 under visible light irradiation. Langmuir 26, 3894–3901 (2010).Google Scholar
Ding, Z., Chen, X., Antonietti, M., and Wang, X.: Synthesis of transition metal-modified carbon nitride polymers for selective hydrocarbon oxidation. ChemSusChem 4, 274–281 (2011).Google Scholar
Yue, B., Li, Q., Iwai, H., Kako, T., and Ye, J.: Hydrogen production using zinc-doped carbon nitride catalyst irradiated with visible light. Sci. Technol. Adv. Mater. 12, 034401 (2011).Google Scholar
Hu, S.Z., Ma, L., Xie, Y., Li, F.Y., Fan, Z.P., Wang, F., Wang, Q., Wang, Y.J., Kang, X.X., and Wu, G.: Hydrothermal synthesis of oxygen functionalized S–P codoped g-C3N4 nanorods with outstanding visible light activity under anoxic conditions. Dalton Trans. 44, 20889–20897 (2015).Google Scholar
Zhu, Y.P., Ren, T.Z., and Yuana, Z.Y.: Mesoporous phosphorus-doped g-C3N4 nanostructured flowers with superior photocatalytic hydrogen evolution performance. ACS Appl. Mater. Interfaces 7, 16850–16856 (2015).Google Scholar
Bu, Y.Y. and Chen, Z.Y.: Effect of oxygen-doped C3N4 on the separation capability of the photoinduced electron-hole pairs generated by O-C3N4@TiO2 with quasi–shell–core nanostructure. Electrochim. Acta 144, 42–49 (2014).CrossRefGoogle Scholar
Lu, C.H., Chen, R.Y., Wu, X., Fan, M.F., Liu, Y.H., Le, Z.G., Jiang, S.J., and Song, S.Q.: Boron doped g-C3N4 with enhanced photocatalytic UO22+ reduction performance. Appl. Surf. Sci. 360, 1016–1022 (2016).CrossRefGoogle Scholar
Kong, H.J., Won, D.H., Kim, J., and Woo, S.I.: Sulfur-doped g-C3N4/BiVO4 composite photocatalyst for water oxidation under visible light. Chem. Mater. 28, 1318–1324 (2016).Google Scholar
Lan, Z.A., Zhang, G., and Wang, X.: A facile synthesis of Br-modified g-C3N4 semiconductors for photoredox water splitting. Appl. Catal., B 192, 116–125 (2016).Google Scholar
Ma, H.Q., Li, Y., Li, S., and Liu, N.: Novel P–O codoped g-C3N4 with large specific surface area: Hydrothermal synthesis assisted by dissolution-precipitation process and their visible light activity under anoxic conditions. Appl. Surf. Sci. 357, 131–138 (2015).Google Scholar
Wang, X., Maeda, K., Thomas, A., Takanabe, K., Xin, G., Carlsson, J.M., Domen, K., and Antonietti, M.: A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat. Mater. 8, 76–80 (2009).CrossRefGoogle ScholarPubMed
Gracia, J. and Kroll, P.: Corrugated layered heptazine-based carbon nitride: The lowest energy modifications of C3N4 ground state. J. Mater. Chem. 19, 3013–3019 (2009).Google Scholar
Ma, X.G., Lv, Y.H., Xu, J., Liu, Y.F., Zhang, R.Q., and Zhu, Y.F.: A strategy of enhancing the photoactivity of g-C3N4 via doping of nonmetal elements: A first-principles study. J. Phys. Chem. C 116, 23485–23493 (2012).Google Scholar
Li, H., Gan, S., Wang, H., Han, D., and Niu, L.: Intercorrelated superhybrid of AgBr supported on graphitic-C3N4-decorated nitrogen-doped graphene: High engineering photocatalytic activities for water purification and CO2 reduction. Adv. Mater. 27, 6906–6913 (2015).Google Scholar
Christoforidis, K.C., Montini, T., Bontempi, E., Zafeiratos, S., Delgado Jaen, J.J., and Fornasiero, P.: Synthesis and photocatalytic application of visible-light active beta-Fe2O3/g-C3N4 hybrid nanocomposites. Appl. Catal., B 187, 171–180 (2016).Google Scholar
Zhang, G., Zhang, J., Zhang, M., and Wang, X.: Polycondensation of thiourea into carbon nitride semiconductors as visible light photocatalysts. J. Mater. Chem. 22, 8083–8091 (2012).Google Scholar
Lin, Z.Z. and Wang, X.C.: Nanostructure engineering and doping of conjugated carbon nitride semiconductors for hydrogen photosynthesis. Angew. Chem., Int. Ed. 52, 1735–1738 (2013).Google Scholar
Xu, T.G., Zhang, L.W., Cheng, H.Y., and Zhu, Y.F.: Significantly enhanced photocatalytic performance of ZnO via graphene hybridization and the mechanism study. Appl. Catal., B 101, 382–387 (2011).Google Scholar
Hu, S.W., Yang, L.W., Tian, Y., Wei, X.L., Ding, J.W., Zhong, J.X., and Chu, P.K.: Simultaneous nanostructure and heterojunction engineering of graphitic carbon nitride via in situ Ag doping for enhanced photoelectrochemical activity. Appl. Catal., B 163, 611–622 (2015).Google Scholar
Ong, W.J., Putri, L.K., Tan, L.L., Chai, S.P., and Yong, S.T.: Heterostructured AgX/g-C3N4 (X = Cl and Br) nanocomposites via a sonication-assisted deposition-precipitation approach: Emerging role of halide ions in the synergistic photocatalytic reduction of carbon dioxide. Appl. Catal., B 180, 530–543 (2016).Google Scholar
Lu, M., Pei, Z., Weng, S., Feng, W., Fang, Z., Zheng, Z., Huang, M., and Liu, P.: Constructing atomic layer g-C3N4-CdS nanoheterojunctions with efficiently enhanced visible light photocatalytic activity. Phys. Chem. Chem. Phys. 16, 21280–21288 (2014).Google Scholar
Cui, Y., Ding, Z., Fu, X., and Wang, X.: Construction of conjugated carbon nitride nanoarchitectures in solution at low temperatures for photoredox catalysis. Angew. Chem., Int. Ed. 51, 11814–11818 (2012).Google Scholar
Huang, Z.a., Sun, Q., Lv, K., Zhang, Z., Li, M., and Li, B.: Effect of contact interface between TiO2 and g-C3N4 on the photoreactivity of g-C3N4/TiO2 photocatalyst: (0 0 1) versus (1 0 1) facets of TiO2. Appl. Catal., B 164, 420–427 (2015).Google Scholar
Zhao, L., Zhang, L., Lin, H., Nong, Q., Cui, M., Wu, Y., and He, Y.: Fabrication and characterization of hollow CdMoO4 coupled g-C3N4 heterojunction with enhanced photocatalytic activity. J. Hazard. Mater. 299, 333–342 (2015).Google Scholar
Li, C., Du, Y., Wang, D., Yin, S., Tu, W., Chen, Z., Kraft, M., Chen, G., and Xu, R.: Unique P–Co–N surface bonding states constructed on g-C3N4 nanosheets for drastically enhanced photocatalytic activity of H2 evolution. Adv. Funct. Mater. 27, 1304328 (2017).Google Scholar
Yan, J., Wu, H., Chen, H., Zhang, Y., Zhang, F., and Liu, S.F.: Fabrication of TiO2/C3N4 heterostructure for enhanced photocatalytic Z-scheme overall water splitting. Appl. Catal., B 191, 130–137 (2016).Google Scholar
Tian, N., Zhang, Y., Liu, C., Yu, S., Li, M., and Huang, H.: g-C3N4/Bi4O5I2 2D–2D heterojunctional nanosheets with enhanced visible-light photocatalytic activity. RSC Adv. 6, 10895–10903 (2016).Google Scholar
Dai, K., Lu, L., Liang, C., Zhu, G., Liu, Q., Geng, L., and He, J.: A high efficient graphitic-C3N4/BiOI/graphene oxide ternary nanocomposite heterostructured photocatalyst with graphene oxide as electron transport buffer material. Dalton Trans. 44, 7903–7910 (2015).Google Scholar
Wang, Y., Di, Y., Antonietti, M., Li, H., Chen, X., and Wang, X.: Excellent visible-light photocatalysis of fluorinated polymeric carbon nitride solids. Chem. Mater. 22, 5119–5121 (2010).Google Scholar
Li, J.H., Shen, B.A., Hong, Z.H., Lin, B.Z., Gao, B.F., and Chen, Y.L.: A facile approach to synthesize novel oxygen-doped g-C3N4 with superior visible-light photoreactivity. Chem. Commun. 48, 12017–12019 (2012).Google Scholar
Lan, D.H., Wang, H.T., Chen, L., Au, C.T., and Yin, S.F.: Phosphorous-modified bulk graphitic carbon nitride: Facile preparation and application as an acid-base bifunctional and efficient catalyst for CO2 cycloaddition with epoxides. Carbon 100, 81–89 (2016).Google Scholar
Cao, Q., Che, R., and Chen, N.: Scalable synthesis of Cu2S double-superlattice nanoparticle systems with enhanced UV/visible-light-driven photocatalytic activity. Appl. Catal., B 162, 187–195 (2015).Google Scholar
Liang, J., Zhu, G., Liu, P., Luo, X., Tan, C., Jin, L., and Zhou, J.: Synthesis and characterization of Fe-doped β-Bi2O3 porous microspheres with enhanced visible light photocatalytic activity. Superlattices Microstruct. 72, 272–282 (2014).CrossRefGoogle Scholar
Ma, J., Tan, X., Jiang, F., and Yu, T.: Graphitic C3N4 nanosheet-sensitized brookite TiO2 to achieve photocatalytic hydrogen evolution under visible light. Catal. Sci. Technol. 7, 3275–3282 (2017).Google Scholar
Xing, X., Liu, R., Yu, X., Zhang, G., Cao, H., Yao, J., Ren, B., Jiang, Z., and Zhao, H.: Self-assembly of CdS quantum dots with polyoxometalate encapsulated gold nanoparticles: Enhanced photocatalytic activities. J. Mater. Chem. A 1, 1488–1494 (2013).Google Scholar
Zou, W.X., Zhang, L., Liu, L.C., Wang, X.B., Sun, J.F., Wu, S.G., Deng, Y., Tang, C.J., Gao, F., and Dong, L.: Engineering the Cu2O-reduced graphene oxide interface to enhance photocatalytic degradation of organic pollutants under visible light. Appl. Catal., B 181, 495–503 (2016).CrossRefGoogle Scholar
Wang, X., Maeda, K., Chen, X., Takanabe, K., Domen, K., Hou, Y., Fu, X., and Antonietti, M.: Polymer semiconductors for artificial photosynthesis: Hydrogen evolution by mesoporous graphitic carbon nitride with visible light. J. Am. Chem. Soc. 131, 1680–1681 (2009).Google Scholar
White, A., Williams, E., Porteous, P., and Hilsum, C.: Applications of photoluminescence excitation spectroscopy to the study of indium gallium phosphide alloys. J. Phys. D: Appl. Phys. 3, 1322–1328 (1970).Google Scholar
Yu, W., Jiang, K., Wu, J., Gan, J., Zhu, M., Hu, Z., and Chu, J.: Electronic structures and excitonic transitions in nanocrystalline iron-doped tin dioxide diluted magnetic semiconductor films: An optical spectroscopic study. Phys. Chem. Chem. Phys. 13, 6211–6222 (2011).Google Scholar