Hostname: page-component-586b7cd67f-dlnhk Total loading time: 0 Render date: 2024-11-26T22:59:26.143Z Has data issue: false hasContentIssue false

Microstructure evolution of NiAl–Cr(Mo) planar eutectic lamellar structure during high temperature treatment

Published online by Cambridge University Press:  05 July 2018

Lei Wang*
Affiliation:
School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
Luhan Gao
Affiliation:
School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
Jun Shen*
Affiliation:
State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China
Yunpeng Zhang*
Affiliation:
School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
Tao Wang*
Affiliation:
School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
Zewei Wang*
Affiliation:
School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
Pengfei Qu
Affiliation:
School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
Jianying Zhang*
Affiliation:
School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
Guojun Zhang*
Affiliation:
School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
*
a)Address all correspondence to these authors. e-mail: [email protected]
Get access

Abstract

The microstructure evolution of the directionally solidified NiAl–Cr(Mo) planar eutectic lamellar structure was studied at 1150 °C and times of up to 400 h. The planar eutectic lamellar structure is obtained at the withdrawal rate range of 2.5–7.5 μm/s. The interlamellar spacing decreases gradually with increasing the withdrawal rate. The lamellar termination (like angular or smooth) commonly exists in the as-DS alloy. After high temperature treatment, the lamellar structure at 2.5 μm/s (interlamellar spacing, 3.7 μm) is almost stable, only a little migration of termination occurs at 400 h. When the withdrawal rate increases to 4.5 μm/s, the coarsening and migration of termination occur at 200 h. The adjacently coarsened terminations assemble when the coarsening processes to a certain degree, thus resulting in the formation of the blocky Cr(Mo) phase. Similarly, the above instable phenomenon occurs at 7.5 μm/s. The relevant instability mechanisms are discussed.

Type
Article
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Noebe, R.D., Bowman, R.R., and Nathal, M.V.: Physical and mechanical properties of the B2 compound NiAl. Int. Mater. Rev. 38, 193 (1993).CrossRefGoogle Scholar
Johnson, D.R., Chen, X.F., Oliver, B.F., Noebe, R.D., and Whittenberger, J.D.: Processing and mechanical properties of in situ composites from the NiAl–Cr and the NiAl–(Cr,Mo) eutectic systems. Intermetallics 3, 99 (1995).CrossRefGoogle Scholar
Amritesh, K., Charlotte, E., Antje, K., Michael, K., Oliver, K., and Ruth, S.: Micromechanical study on the deformation behavior of directionally solidified NiAl–Cr eutectic composites. J. Mater. Res. 32, 2127 (2017).Google Scholar
Misra, A. and Gibala, R.: Plasticity in multiphase intermetallics. Intermetallics 8, 1025 (2000).CrossRefGoogle Scholar
Zhang, J.F., Ma, X.W., Ren, H.P., Chen, L., Jin, Z.L., Li, Z.L., and Shen, J.: Influence of growth rate on microstructural length scales in directionally solidified NiAl–Mo hypo-eutectic alloy. JOM 68, 178 (2016).CrossRefGoogle Scholar
Bei, H. and George, E.P.: Microstructures and mechanical properties of a directionally solidified NiAl–Mo eutectic alloy. Acta Mater. 53, 69 (2005).CrossRefGoogle Scholar
Wang, L. and Shen, J.: Effect of withdrawal rate on the microstructure and room temperature mechanical properties of directionally solidified NiAl–Cr(Mo)–(Hf, Dy)–4Fe alloy. J. Alloys Compd. 663, 187 (2016).CrossRefGoogle Scholar
Sheng, L.Y., Guo, J.T., Tian, Y.X., Zhou, L.Z., and Ye, H.Q.: Microstructure and mechanical properties of rapidly solidified NiAl–Cr(Mo) eutectic alloy doped with trace Dy. J. Alloys Compd. 475, 730 (2009).CrossRefGoogle Scholar
Wang, L., Shen, J., Zhang, Y.P., Xu, H.X., and Fu, H.Z.: Microstructure and mechanical properties of NiAl-based hypereutectic alloy obtained by liquid metal cooling and zone melted liquid metal cooling directional solidification techniques. J. Mater. Res. 31, 646 (2016).CrossRefGoogle Scholar
Wang, L., Shen, J., Shang, Z., and Fu, H.Z.: Microstructure evolution and enhancement of fracture toughness of NiAl–Cr(Mo)–(Hf,Dy) alloy with a small addition of Fe during heat treatment. Scr. Mater. 89, 1 (2014).CrossRefGoogle Scholar
Wang, L., Zhang, G.J., Shen, J., Zhang, Y.P., Xu, H.X., Ge, Y.H., and Fu, H.Z.: A true change of NiAl–Cr(Mo) eutectic lamellar structure during high temperature treatment. J. Alloys Compd. 732, 124 (2018).CrossRefGoogle Scholar
Sheng, L.Y., Guo, J.T., Zhang, W., Xie, Y., Zhou, L.Z., and Ye, H.Q.: Effect of HIP and heat treatment on microstructure and compressive properties of rapidly solidified NiAl–Cr(Mo)–Hf eutectic alloy. Acta Metall. Sin. 45, 1025 (2009).Google Scholar
Chen, X.F., Johnson, D.R., Noebe, R.D., and Oliver, B.F.: Deformation and fracture of a directionally solidified NiAl–28Cr–6Mo eutectic alloy. J. Mater. Res. 10, 1159 (1995).CrossRefGoogle Scholar
Yang, J.M., Jeng, S.M., Bain, K., and Amato, R.A.: Microstructure and mechanical behavior of in situ directional solidified NiAl/Cr(Mo) eutectic composite. Acta Mater. 45, 295 (1997).CrossRefGoogle Scholar
Wang, L., Shen, J., Shang, Z., Zhang, J.F., Chen, J.H., and Fu, H.Z.: Effect of Dy on the microstructures of directionally solidified NiAl–Cr(Mo) hypereutectic alloy at different withdrawal rates. Intermetallics 44, 44 (2014).CrossRefGoogle Scholar
Wang, L., Shen, J., Shang, Z., Zhang, J.F., Du, Y.J., and Fu, H.Z.: Microstructure and mechanical property of directionally solidified NiAl–Cr(Mo)–(Hf,Dy) alloy at different withdrawal rates. Mater. Sci. Eng., A 607, 113 (2014).CrossRefGoogle Scholar
Wang, L., Shen, J., Zhang, Y.P., and Fu, H.Z.: Microstructure, fracture toughness and compressive property of as-cast and directionally solidified NiAl-based eutectic composite. Mater. Sci. Eng., A 664, 188 (2016).CrossRefGoogle Scholar
Sheng, L.Y., Zhang, W., Guo, J.T., and Ye, H.Q.: Microstructure and mechanical properties of Hf and Ho doped NiAl–Cr(Mo) near eutectic alloy prepared by suction casting. Mater. Charact. 60, 1311 (2009).CrossRefGoogle Scholar
Lin, L.Y. and Courtney, T.H.: Direct observations of lamellar fault migration in the Pb–Sn eutectic. Metall. Trans. 5, 513 (1974).CrossRefGoogle Scholar
Graham, L.D. and Kraft, R.W.: Coarsening of eutectic microstructures at elevated temperatures. Trans. Metall. Soc. AIME 236, 94 (1966).Google Scholar
Eady, J.A. and Winegard, W.C.: Microstructural stability of the Pb–Sn eutectic. Can. Metall. Q. 10, 213 (1971).CrossRefGoogle Scholar
Lin, L.Y., Courtney, T.H., and Ralls, K.M.: Deformation induced microstructural instability in the Pb–Sn eutectic. Acta Metall. 25, 99 (1977).CrossRefGoogle Scholar
Racek, R. and Lesoult, G.: Ripening of Sn–Cd eutecticmicrostructures. J. Cryst. Growth 16, 223 (1972).CrossRefGoogle Scholar
Kampe, J.C.M., Courtney, T.H., and Leng, Y.: Shape instabilities of plate-like structures—I. Experimental observations in heavily cold worked in situ composites. Acta Metall. 37, 1735 (1989).CrossRefGoogle Scholar
Courtney, T.H. and Kampe, J.C.M.: Shape instabilities of plate-like structures—II. Analysis. Acta. Metall. 37, 1747 (1989).CrossRefGoogle Scholar
Gali, A., Bei, H., and George, E.P.: Thermal stability of Cr–Cr3Si eutectic microstructures. Acta Mater. 57, 3823 (2009).CrossRefGoogle Scholar
Livingston, J.D. and Cahn, J.W.: Discontinuous coarsening of aligned eutectoids. Acta. Acta Metall. 22, 495 (1974).CrossRefGoogle Scholar
Sharma, G., Ramanujan, R.V., and Tiwari, G.P.: Instability mechanisms in lamellar microstructures. Acta Mater. 48, 875 (2000).CrossRefGoogle Scholar
Wang, L., Shen, J., Zhang, G.J., Zhang, Y.P., Guo, L.L., Ge, Y.H., Gao, L.H., and Fu, H.Z.: Stability of lamellar structure of directionally solidified NiAl–28Cr–6Mo eutectic alloy at different withdrawal rates and temperatures. Intermetallics 94, 83 (2018).CrossRefGoogle Scholar
Walter, J.L. and Cline, H.E.: Stability of the directionally solidified eutectics NiAl–Cr and NiAl–Mo. Metall. Trans. 4, 33 (1973).CrossRefGoogle Scholar
Gali, A., Bei, H., and George, E.P.: Effects of boron on the microstructure and thermal stabilityof directionally solidified NiAl–Mo eutectic. Acta Mater. 58, 421 (2010).CrossRefGoogle Scholar