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Influence of heat treatment on microstructure, mechanical behavior, and soft magnetic properties in an fcc-based Fe29Co28Ni29Cu7Ti7 high-entropy alloy

Published online by Cambridge University Press:  01 June 2018

Zhiqiang Fu
Affiliation:
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, California 92697, USA
Benjamin E. MacDonald
Affiliation:
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, California 92697, USA
Todd C. Monson
Affiliation:
Nanoscale Sciences, Sandia National Laboratories, Albuquerque, New Mexico 87185, USA
Baolong Zheng
Affiliation:
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, California 92697, USA
Weiping Chen
Affiliation:
Guangdong Key Laboratory for Advanced Metallic Materials Processing, South China University of Technology, Guangzhou, Guangdong 510640, China
Enrique J. Lavernia*
Affiliation:
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, California 92697, USA
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

The influence of heat treatment (homogenization) on the microstructure, mechanical behavior, and soft magnetic properties of a face-centered cubic (fcc)-based high-entropy alloy (HEA), Fe29Co28Ni29Cu7Ti7, fabricated by casting, was investigated in detail. The as-cast Fe29Co28Ni29Cu7Ti7 HEA was composed of a primary fcc phase containing coherent dispersed L12 nanoprecipitates and trace amounts of a needle-like phase. The tensile yield strength (σ0.2), ultimate strength, and total elongation of the as-cast alloy are 917 MPa, 1060 MPa, and 1.8%, respectively. Following homogenization, the alloy having a single fcc phase shows a decrease of ∼ 55% in yield strength and a decrease of ∼ 36% in ultimate strength; however, the total elongation is increased from 1.8 to 52%. Saturation magnetization (Msat) is decreased from 111.54 to 110.34 Am2/kg, by contrast, coercivity (Hc) is increased from 266.65 to 966.89 A/m. The dissolution of precipitates and grain growth are mainly responsible for the changes in magnetic properties and mechanical behavior.

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Article
Copyright
Copyright © Materials Research Society 2018 

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Footnotes

b)

This author was an editor of this journal during the review and decision stage. For the JMR policy on review and publication of manuscripts authored by editors, please refer to http://www.mrs.org/editor-manuscripts/.

References

REFERENCES

Yeh, J.W., Chen, S.K., Lin, S.J., Gan, J.Y., Chin, T.S., Shun, T.T., Tsau, C.H., and Chang, S.Y.: Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes. Adv. Eng. Mater. 6, 299 (2004).CrossRefGoogle Scholar
Miracle, D.B. and Senkov, O.N.: A critical review of high entropy alloys and related concepts. Acta Mater. 122, 448 (2017).CrossRefGoogle Scholar
Choudhuri, D., Gwalani, B., Gorsse, S., Mikler, C.V., Ramanujan, R.V., Gibson, M.A., and Banerjee, R.: Change in the primary solidification phase from fcc to bcc-based B2 in high entropy or complex concentrated alloys. Scr. Mater. 127, 186 (2017).CrossRefGoogle Scholar
Yuan, Y., Wu, Y., Tong, X., Zhang, H., Wang, H., Liu, X.J., Ma, L., Suo, H.L., and Lu, Z.P.: Rare-earth high-entropy alloys with giant magnetocaloric effect. Acta Mater. 125, 481 (2017).CrossRefGoogle Scholar
Zou, Y., Maiti, S., Steurer, W., and Spolenak, R.: Size-dependent plasticity in an Nb25Mo25Ta25W25 refractory high-entropy alloy. Acta Mater. 65, 85 (2014).CrossRefGoogle Scholar
Chuang, M., Tsai, M., Wang, W., Lin, S., and Yeh, J.: Microstructure and wear behavior of AlxCo1.5CrFeNi1.5Tiy high-entropy alloys. Acta Mater. 59, 6308 (2011).CrossRefGoogle Scholar
Lee, D.H., Seok, M.Y., Zhao, Y., Choi, I.C., He, J., Lu, Z., Suh, J.Y., Ramamurty, U., Kawasaki, M., Langdon, T.G., and Jang, J-i.: Spherical nanoindentation creep behavior of nanocrystalline and coarse-grained CoCrFeMnNi high-entropy alloys. Acta Mater. 109, 314 (2016).CrossRefGoogle Scholar
Zhang, Y., Zuo, T., Cheng, Y., and Liaw, P.K.: High-entropy alloys with high saturation magnetization, electrical resistivity, and malleability. Sci. Rep. 3, 1455 (2013).CrossRefGoogle ScholarPubMed
Gómez-Esparza, C.D., Baldenebro-López, F.J., Santillán-Rodríguez, C.R., Estrada-Guel, I., Matutes-Aquino, J.A., Herrera-Ramírez, J.M., and Martínez-Sánchez, R.: Microstructural and magnetic behavior of an equiatomic NiCoAlFe alloy prepared by mechanical alloying. J. Alloys Compd. 615, S317 (2014).CrossRefGoogle Scholar
Li, P., Wang, A., and Liu, C.T.: A ductile high entropy alloy with attractive magnetic properties. J. Alloys Compd. 694, 55 (2017).CrossRefGoogle Scholar
Zuo, T., Gao, M.C., Ouyang, L., Yang, X., Cheng, Y., Feng, R., Chen, S., Liaw, P.K., Hawk, J.A., and Zhang, Y.: Tailoring magnetic behavior of CoFeMnNiX (X = Al, Cr, Ga, and Sn) high entropy alloys by metal doping. Acta Mater. 130, 10 (2017).CrossRefGoogle Scholar
Shang, C., Axinte, E., Ge, W., Zhang, Z., and Wang, Y.: High-entropy alloy coatings with excellent mechanical, corrosion resistance and magnetic properties prepared by mechanical alloying and hot pressing sintering. Surf. Interfaces. 9, 36 (2017).CrossRefGoogle Scholar
Borkar, T., Gwalani, B., Choudhuri, D., Mikler, C.V., Yannetta, C.J., Chen, X., Ramanujan, R.V., Styles, M.J., Gibson, M.A., and Banerjee, R.: A combinatorial assessment of AlxCrCuFeNi2 (0 < x < 1.5) complex concentrated alloys: Microstructure, microhardness, and magnetic properties. Acta Mater. 116, 63 (2016).CrossRefGoogle Scholar
Nadutov, V.M., Makarenko, S.Y., and Svystunov, Y.O.: Effect of Al content on magnetic properties and thermal expansion of as-cast high-entropy alloys AlxFeCoNiCuCr. Metallofiz. Noveishie Tekhnol. 37, 987 (2015).CrossRefGoogle Scholar
Zuo, T.T., Ren, S.B., Liaw, P.K., and Zhang, Y.: Processing effects on the magnetic and mechanical properties of FeCoNiAl0.2Si0.2 high entropy alloy. Int. J. Miner. Metall. Mater. 20, 549 (2013).CrossRefGoogle Scholar
Lin, P.C., Cheng, C.Y., Yeh, J.W., and Chin, T.S.: Soft magnetic properties of high-entropy Fe–Co–Ni–Cr–Al–Si thin films. Entropy. 18, 1 (2016).CrossRefGoogle Scholar
Yu, P.F., Zhang, L.J., Cheng, H., Zhang, H., Ma, M.Z., Li, Y.C., Li, G., Liaw, P.K., and Liu, R.P.: The high-entropy alloys with high hardness and soft magnetic property prepared by mechanical alloying and high-pressure sintering. Intermetallics. 70, 82 (2016).CrossRefGoogle Scholar
Zuo, T., Yang, X., Liaw, P.K., and Zhang, Y.: Influence of bridgman solidification on microstructures and magnetic behaviors of a non-equiatomic FeCoNiAlSi high-entropy alloy. Intermetallics 67, 171 (2015).CrossRefGoogle Scholar
Singh, S., Wanderka, N., Kiefer, K., Siemensmeyer, K., and Banhart, J.: Effect of decomposition of the Cr–Fe–Co rich phase of AlCoCrCuFeNi high entropy alloy on magnetic properties. Ultramicroscopy 111, 619 (2011).CrossRefGoogle ScholarPubMed
Guo, S. and Liu, C.T.: Phase stability in high entropy alloys: Formation of solid-solution phase or amorphous phase. Prog. Nat. Sci.: Mater. Int. 21, 433 (2011).CrossRefGoogle Scholar
Yang, X. and Zhang, Y.: Prediction of high-entropy stabilized solid-solution in multi-component alloys. Mater. Chem. Phys. 132, 233 (2012).CrossRefGoogle Scholar
Fu, Z., Chen, W., Wen, H., Zhang, D., Chen, Z., Zheng, B., Zhou, Y., and Lavernia, E.J.: Microstructure and strengthening mechanisms in an fcc structured single-phase nanocrystalline Co25Ni25Fe25Al7.5Cu17.5 high-entropy alloy. Acta Mater. 107, 59 (2016).CrossRefGoogle Scholar
Fu, Z., MacDonald, B.E., Zhang, D., Wu, B., Chen, W., Ivanisenko, J., Hahn, H., and Lavernia, E.J.: Fcc nanostructured TiFeCoNi alloy with multi-scale grains and enhanced plasticity. Scr. Mater. 143, 108 (2018).CrossRefGoogle Scholar
Kim, I.S., Choi, B.G., Hong, H.U., Do, J., and Jo, C.Y.: Influence of thermal exposure on the microstructural evolution and mechanical properties of a wrought Ni-base superalloy. Mater. Sci. Eng. A. 593, 55 (2014).CrossRefGoogle Scholar
Xu, L., Cui, C., and Sun, X.: The effects of Co and Ti additions on microstructures and compressive strength of Udimet710. Mater. Sci. Eng. A. 528, 7851 (2011).CrossRefGoogle Scholar
Takeuchi, A. and Inoue, A.: Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element. Mater. Trans. 46, 2817 (2005).CrossRefGoogle Scholar
Liu, W.H., Lu, Z.P., He, J.Y., Luan, J.H., Wang, Z.J., Liu, B., Liu, Y., Chen, M.W., and Liu, C.T.: Ductile CoCrFeNiMox high entropy alloys strengthened by hard intermetallic phases. Acta Mater. 116, 332 (2016).CrossRefGoogle Scholar
He, J.Y., Liu, W.H., Wang, H., Wu, Y., Liu, X.J., Nieh, T.G., and Lu, Z.P.: Effects of Al addition on structural evolution and tensile properties of the FeCoNiCrMn high-entropy alloy system. Acta Mater. 62, 105 (2014).CrossRefGoogle Scholar
Wei, R., Sun, H., Chen, C., Han, Z., and Li, F.: Effect of cooling rate on the phase structure and magnetic properties of Fe26.7Co28.5Ni28.5Si4.6B8.7P3 high entropy alloy. J. Magn. Magn. Mater. 435, 184 (2017).CrossRefGoogle Scholar
Yu, R.H., Basu, S., Li, Y.F., Zhang, Y., Hadjipanayis, G.C., Lorenz, B.E., and Xiao, Q.: Microstructural effect of magnetic properties of FeCo-based soft magnetic alloys. J. Magn. Soc. Jpn. 23, 397 (1999).CrossRefGoogle Scholar
Hou, C., Shan, Y., Wu, H., and Bi, X.: Effect of a small addition of Cr on soft magnetic and mechanical properties of Fe–49Co–2V alloy. J. Alloys Compd. 556, 51 (2013).CrossRefGoogle Scholar