Hostname: page-component-cd9895bd7-gvvz8 Total loading time: 0 Render date: 2024-12-27T18:46:35.740Z Has data issue: false hasContentIssue false
  • English
  • Français

In situ synthesis of CsTi2NbO7@g-C3N4 core–shell heterojunction with excellent electrocatalytic performance for the detection of nitrite

Published online by Cambridge University Press:  12 October 2018

Mengjun Wang ,
Chao Liu ,
Xiaobo Zhang ,
Zichun Fan ,
Jiasheng Xu  and
Zhiwei Tong Open the ORCID record for Zhiwei Tong [Opens in a new window]
Mengjun Wang
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
Chao Liu
Affiliation:
School of Materials Engineering, Yancheng Institute of Technology, Yancheng 224051, China
Xiaobo Zhang
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
Zichun Fan
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
Jiasheng Xu
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
Zhiwei Tong*
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China; and SORST, Japan Science and Technology Agency (JST), Kawaguchi-shi, Saitama 332-0012, Japan
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

In this work, a N-doped CsTi2NbO7@g-C3N4 (NTCN) heterojunction nanocomposite was synthesized by a simple one-step calcination method. The as-prepared samples were characterized by means of X-ray diffraction patterns, scanning electron microscopy, high-angle annular dark-field scanning transmission electron microscopy, and Fourier transformed infrared spectroscopy. The results showed that g-C3N4 was formed both on the surface and within the interlayers of CsTi2NbO7, in which CsTi2NbO7 was in situ doped by nitrogen atoms to form N–CsTi2NbO7. The NTCN composite displayed higher electrocatalytic activity toward the detection of nitrite than pure CsTi2NbO7 and g-C3N4. The main reasons could be attributed to the synergistic effects of morphology engineering, N-doping, and layered heterojunction. The NTCN-based electrochemical sensor expressed a good linear relationship range from 0.0999 to 3.15 mmol/L with a detection limit of 2.63 × 10−5 mol/L. The good recovery, stability, and reproducibility of this biosensor showed the potential application in environmental monitoring.

Keywords

CsTi2NbO7g-C3N4heterojunctionelectrocatalysisnitrite
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 23 , 14 December 2018 , pp. 3936 - 3945
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Li, S., Hu, Y., Wang, A., Weng, X., Chen, J., and Feng, J.: Simple synthesis of worm-like Au–Pd nanostructures supported on reduced graphene oxide for highly sensitive detection of nitrite. Sens. Actuators, B 208, 468 (2015).CrossRefGoogle Scholar
Wang, P., Li, F., Huang, X., Li, Y., and Wang, L.: In situ electrodeposition of Pt nanoclusters on glassy carbon surface modified by monolayer choline film and their electrochemical applications. Electrochem. Commun. 10, 195 (2008).CrossRefGoogle Scholar
Zhang, Y., Su, Z., Li, B., Zhang, L., Fan, D., and Ma, H.: Recyclable magnetic mesoporous nanocomposite with improved sensing performance toward nitrite. ACS Appl. Mater. Interfaces 8, 12344 (2016).CrossRefGoogle ScholarPubMed
Lin, Z., Xue, W., Chen, H., and Lin, J.M.: Peroxynitrous-acid-induced chemiluminescence of fluorescent carbon dots for nitrite sensing. Anal. Chem. 83, 8245 (2011).CrossRefGoogle ScholarPubMed
Ferreira, I.M.P.L.V.O. and Silva, S.: Quantification of residual nitrite and nitrate in ham by reverse-phase high performance liquid chromatography/diode array detector. Talanta 74, 1598 (2008).CrossRefGoogle Scholar
Wang, P., Wang, M., Zhou, F., Yang, G., Qu, L., and Miao, X.: Development of a paper-based, inexpensive, and disposable electrochemical sensing platform for nitrite detection. Electrochem. Commun. 81, 74 (2017).CrossRefGoogle Scholar
Wu, H., Fan, S., Jin, X., Zhang, H., Chen, H., Dai, Z., and Zou, X.: Construction of a zinc porphyrin-fullerene-derivative based nonenzymatic electrochemical sensor for sensitive sensing of hydrogen peroxide and nitrite. Anal. Chem. 86, 6285 (2014).CrossRefGoogle ScholarPubMed
Wang, P., Mai, Z., Dai, Z., Li, Y., and Zou, X.: Construction of Au nanoparticles on choline chloride modified glassy carbon electrode for sensitive detection of nitrite. Biosens. Bioelectron. 24, 3242 (2009).CrossRefGoogle ScholarPubMed
Zou, C.E., Yang, B., Bin, D., Wang, J., Li, S., Yang, P., Wang, C., Shiraishi, Y., and Du, Y.: Electrochemical synthesis of gold nanoparticles decorated flower-like graphene for high sensitivity detection of nitrite. J. Colloid Interface Sci. 488, 135 (2017).CrossRefGoogle ScholarPubMed
Li, Y., Wang, P., Wang, L., and Lin, X.: Overoxidized polypyrrole film directed single-walled carbon nanotubes immobilization on glassy carbon electrode and its sensing applications. Biosens. Bioelectron. 22, 3120 (2007).CrossRefGoogle ScholarPubMed
Wang, P., Zhou, F., Wang, Z., Lai, C., and Han, X.: Substrate-induced assembly of PtAu alloy nanostructures at choline functionalized monolayer interface for nitrite sensing. J. Electroanal. Chem. 750, 36 (2015).CrossRefGoogle Scholar
Shibata, T., Takanashi, G., Nakamura, T., Fukuda, K., Ebina, Y., and Sasaki, T.: Titanoniobate and niobate nanosheet photocatalysts: Superior photoinduced hydrophilicity and enhanced thermal stability of unilamellar Nb3O8 nanosheet. Energy Environ. Sci. 4, 535 (2011).CrossRefGoogle Scholar
Takagaki, A., Yoshida, T., Lu, D., Kondo, J.N., Hara, M., Domen, K., and Hayashi, S.: Titanium niobate and titanium tantalate nanosheets as strong solid acid catalysts. J. Phys. Chem. B 108, 11549 (2004).CrossRefGoogle Scholar
Wang, M., Xu, J., Zhang, X., Fan, Z., and Tong, Z.: Fabrication of a new self-assembly compound of CsTi2NbO7 with cationic cobalt porphyrin utilized as an ascorbic acid sensor. Appl. Biochem. Biotechnol. 185, 834 (2018).CrossRefGoogle ScholarPubMed
Zhang, X., Liu, L., Ma, J., Yang, X., Xu, X., and Tong, Z.: A novel metalloporphyrin intercalated layered niobate as an electrode modified material for detection of hydrogen peroxide. Mater. Lett. 95, 21 (2013).CrossRefGoogle Scholar
Pan, B., Xu, J., Zhang, X., Li, J., Wang, M., Ma, J., Liu, L., Zhang, D., and Tong, Z.: Electrostatic self-assembly behaviour of exfoliated Sr2Nb3O10− nanosheets and cobalt porphyrins: Exploration of non-noble electro-catalysts towards hydrazine hydrate oxidation. J. Mater. Sci. 53, 6494 (2018).CrossRefGoogle Scholar
Wang, M., Fan, Z., Yi, L., Xu, J., Zhang, X., and Tong, Z.: Construction of iron porphyrin/titanoniobate nanosheets sensors for the sensitive detection of nitrite. J. Mater. Sci. 53, 11403 (2018).CrossRefGoogle Scholar
Wang, L., Nemoto, Y., and Yamauchi, Y.: Direct synthesis of spatially-controlled Pt-on-Pd bimetallic nanodendrites with superior electrocatalytic activity. J. Am. Chem. Soc. 133, 9674 (2011).CrossRefGoogle ScholarPubMed
Sun, Y., Jiang, J., Liu, Y., Wu, S., and Zou, J.: A facile one-pot preparation of Co3O4/g-C3N4 heterojunctions with excellent electrocatalytic activity for the detection of environmental phenolic hormones. Appl. Surf. Sci. 430, 362 (2018).CrossRefGoogle Scholar
Wen, J., Xie, J., Chen, X., and Li, X.: A review on g-C3N4-based photocatalysts. Appl. Surf. Sci. 391, 72 (2017).CrossRefGoogle Scholar
Yuan, J., Wen, J., Zhong, Y., Li, X., Fang, Y., Zhang, S., and Liu, W.: Enhanced photocatalytic H2 evolution over noble-metal-free NiS cocatalyst modified CdS nanorods/g-C3N4 heterojunctions. J. Mater. Chem. A 3, 18244 (2015).CrossRefGoogle Scholar
Zhou, M., Hou, Z., Zhang, L., Liu, Y., Gao, Q., and Chen, X.: n/n junctioned g-C3N4 for enhanced photocatalytic H2 generation. Sustainable Energy Fuels 1, 317 (2017).CrossRefGoogle Scholar
Yu, T., Liu, L., and Yang, F.: Heterojunction between anodic TiO2/g-C3N4 and cathodic WO3/W nano-catalysts for coupled pollutant removal in a self-biased system. Chin. J. Catal. 38, 270 (2017).CrossRefGoogle Scholar
Li, Y., Lv, K., Ho, W., Zhao, Z., and Huang, Y.: Enhanced visible-light photo-oxidation of nitric oxide using bismuth-coupled graphitic carbon nitride composite heterostructures. Chin. J. Catal. 38, 321 (2017).CrossRefGoogle Scholar
Hao, R., Wang, G., Jiang, C., Tang, H., and Xu, Q.: In situ hydrothermal synthesis of g-C3N4/TiO2 heterojunction photocatalysts with high specific surface area for Rhodamine B degradation. Appl. Surf. Sci. 411, 400 (2017).CrossRefGoogle Scholar
Wang, B., Zhang, J., and Huang, F.: Enhanced visible light photocatalytic H2 evolution of metal-free g-C3N4/SiC heterostructured photocatalysts. Appl. Surf. Sci. 391, 449 (2017).CrossRefGoogle Scholar
Wang, M., Fang, M., Tang, C., Zhang, L., Huang, Z., Liu, Y., and Wu, X.: A C3N4/Bi2WO6 organic-inorganic hybrid photocatalyst with a high visible-light-driven photocatalytic activity. J. Mater. Res. 31, 713 (2016).CrossRefGoogle Scholar
Feng, Z., Zeng, L., Chen, Y., Ma, Y., Zhao, C., Jin, R., Lu, Y., Wu, Y., and He, Y.: In situ preparation of Z-scheme MoO3/g-C3N4 composite with high performance in photocatalytic CO2 reduction and RhB degradation. J. Mater. Res. 32, 3660 (2017).CrossRefGoogle Scholar
Chen, J., Shen, S., Guo, P., Wang, M., Su, J., Zhao, D., and Guo, L.: Plasmonic Ag@SiO2 core/shell structure modified g-C3N4 with enhanced visible light photocatalytic activity. J. Mater. Res. 29, 64 (2014).CrossRefGoogle Scholar
Wang, L., Liu, H., Fu, H., Wang, Y., Yu, K., and Wang, S.: Polymer g-C3N4 wrapping bundle-like ZnO nanorod heterostructures with enhanced gas sensing properties. J. Mater. Res. 33, 1401 (2018).CrossRefGoogle Scholar
, X.L., Shen, J., Wu, Z., Wang, J., and Xie, J.: Deposition of Ag nanoparticles on g-C3N4 nanosheet by N, N-dimethylformamide: Soft synthesis and enhanced photocatalytic activity. J. Mater. Res. 29, 2170 (2014).CrossRefGoogle Scholar
Fu, S., He, Y., Wu, Q., Wu, Y., and Wu, T.: Visible-light responsive plasmonic Ag2O/Ag/g-C3N4 nanosheets with enhanced photocatalytic degradation of Rhodamine B. J. Mater. Res. 31, 2252 (2016).CrossRefGoogle Scholar
Liang, Y., Wu, W., Wang, P., Liou, S.C., Liu, D., and Ehrman, S.H.: Scalable fabrication of SnO2/eo-GO nanocomposites for the photoreduction of CO2 to CH4. Nano Res. 11, 4049 (2018).CrossRefGoogle Scholar
Su, F., Mathew, S.C., Lipner, G., Fu, X., Antonietti, M., Blechert, S., and Wang, X.: mpg-C3N4-catalyzed selective oxidation of alcohols using O2 and visible light. J. Am. Chem. Soc. 132, 16299 (2010).CrossRefGoogle Scholar
Schwinghammer, K., Mesch, M.B., Duppel, V., Ziegler, C., Senkerand, J., and Lotsch, B.V.: Crystalline carbon nitride nanosheets for improved visible-lighthydrogen evolution. J. Am. Chem. Soc. 136, 1730 (2014).CrossRefGoogle ScholarPubMed
Liu, C., Zhu, H., Zhu, Y., Dong, P., Hou, H., Xu, Q., Chen, X., Xi, X., and Hou, W.: Ordered layered N-doped KTiNbO5/g-C3N4 heterojunction with enhanced visible light photocatalytic activity. Appl. Catal., B 228, 54 (2018).CrossRefGoogle Scholar
Zeng, B., Zhang, L., Wan, X., Song, H., and Lv, Y.: Fabrication of α-Fe2O3/g-C3N4 composites for cataluminescence sensing of H2S. Sens. Actuators, B 211, 370 (2015).CrossRefGoogle Scholar
Hu, Y., Li, L., Zhang, L., and Lv, Y.: Dielectric barrier discharge plasma-assisted fabrication of g-C3N4-Mn3O4 composite for high-performance cataluminescence H2S gas sensor. Sens. Actuators, B 239, 1177 (2017).CrossRefGoogle Scholar
Hang, N.T., Zhang, S., and Yang, W.: Efficient exfoliation of g-C3N4 and NO2 sensing behavior of graphene/g-C3N4 nanocomposite. Sens. Actuators, B 248, 940 (2017).CrossRefGoogle Scholar
Yang, C., Wang, X., Liu, H., Ge, S., Yan, M., Yu, J., and Song, X.: An inner filter effect fluorescent sensor based on g-C3N4 nanosheets/chromogenic probe for simple detection of glutathione. Sens. Actuators, B 248, 639 (2017).CrossRefGoogle Scholar
Wu, G., Hu, Y., Liu, Y., Zhao, J., Chen, X., Whoehling, V., Plesse, C., Nguyen, G.T.M., Vidal, F., and Chen, W.: Graphitic carbon nitride nanosheet electrode-based high-performance ionic actuator. Nat. Commun. 6, 7258 (2015).CrossRefGoogle ScholarPubMed
Liang, Y., Guo, C., Cao, S., Tian, Y., and Lui, Q.: A high quality BiOCl film with petal-like hierarchical structures and its visible-light photocatalytic property. J. Nanosci. Nanotechnol. 13, 919 (2013).CrossRefGoogle ScholarPubMed
Wei, Z., Liang, F., Liu, Y., Luo, W., Wang, J., Yao, W., and Zhu, Y.: Photoelectrocatalytic degradation of phenol-containing wastewater by TiO2/gC3N4 hybrid heterostructure thin film. Appl. Catal., B 201, 600 (2017).CrossRefGoogle Scholar
Liu, C., Zhang, C., Wang, J., Xu, Q., Chen, X., Wang, C., Xi, X., and Hou, W.: N-doped CsTi2NbO7@g-C3N4 core–shell nanobelts with enhanced visible light photocatalytic activity. Mater. Lett. 217, 235 (2018).CrossRefGoogle Scholar
Gunjakar, J.L., Kim, T.W., Kim, H.N., Kim, I.Y., and Hwang, S.J.: Mesoporous layer-by-layer ordered nanohybrids of layered double hydroxide and layered metal oxide: Highly active visible light photocatalysts with improved chemical stability. J. Am. Chem. Soc. 133, 14998 (2011).CrossRefGoogle ScholarPubMed
Xu, J., Zhang, L., Shi, R., and Zhu, Y.: Chemical exfoliation of graphitic carbon nitride for efficient heterogeneous photocatalysis. J. Mater. Chem. A 1, 14766 (2013).CrossRefGoogle Scholar
Liu, C., Wu, Q., Ji, M., Zhu, H., Hou, H., Yang, Q., Jiang, C., Wang, J., Tian, L., Chen, J., and Hou, W.: Constructing Z-scheme charge separation in 2D layered porous BiOBr/graphitic C3N4 nanosheets nanojunction with enhanced photocatalytic activity. J. Alloys Compd. 723, 1121 (2017).CrossRefGoogle Scholar
Xia, J., Ji, M., Di, J., Wang, B., Yin, S., Zhang, Q., He, M., and Li, H.: Construction of ultrathin C3N4/Bi4O5I2 layered nanojunctions via ionic liquid with enhanced photocatalytic performance and mechanism insight. Appl. Catal., B 191, 235 (2016).CrossRefGoogle Scholar
Park, H., Shin, D.H., Song, T., Park, W.I., and Paik, U.: Synthesis of hierarchical porous TiNb2O7 nanotubes with controllable porosity and their application in high power Li-ion batteries. J. Mater. Chem. A 5, 6958 (2017).CrossRefGoogle Scholar
Zhang, Z., Huang, J., Zhang, M., Yuan, Q., and Dong, B.: Ultrathin hexagonal SnS2 nanosheets coupled with g-C3N4 nanosheets as 2D/2D heterojunction photocatalysts toward high photocatalytic activity. Appl. Catal., B 163, 298 (2015).CrossRefGoogle Scholar
Liu, C., Sun, T., Wu, L., Liang, J., Huang, Q., Chen, J., and Hou, W.: N-doped Na2Ti6O13@TiO2 core–shell nanobelts with exposed {101} anatase facets and enhanced visible light photocatalytic performance. Appl. Catal., B 170–171, 17 (2015).CrossRefGoogle Scholar
Hou, Y., Zuo, F., Dagg, A., and Feng, P.Y.: A three-dimensional branched cobalt-doped α-Fe2O3 nanorod/MgFe2O4 heterojunction array as a flexible photoanode for efficient photoelectrochemical water oxidation. Angew. Chem., Int. Ed. 125, 1286 (2013).CrossRefGoogle Scholar
Xiang, Q., Yu, J., and Jaroniec, M.: Preparation and eenhanced visible-light photocatalytic H2-production activity of graphene/C3N4 composites. J. Phys. Chem. C 115, 7355 (2011).CrossRefGoogle Scholar
Laviron, E.: General expression of the linear potential sweep voltammogram in the case of diffusionless electrochemical systems. J. Electroanal. Chem. 101, 19 (1979).CrossRefGoogle Scholar
Afkhami, A., Soltani-Felehgari, F., Madrakian, T., and Ghaedi, H.: Surface decoration of multi-walled carbon nanotubes modified carbon paste electrode with gold nanoparticles for electro-oxidation and sensitive determination of nitrite. Biosens. Bioelectron. 51, 379 (2014).CrossRefGoogle ScholarPubMed
Pham, X.H., Li, C.A., Han, K.N., Huynh-Nguyen, B.C., Le, T.H., Ko, E., Kim, J.H., and Seong, G.H.: Electrochemical detection of nitrite using urchin-like palladium nanostructures on carbon nanotube thin film electrodes. Sens. Actuators, B 193, 815 (2014).CrossRefGoogle Scholar
Liu, C., Liang, J.Y., Han, R.R., Wang, Y.Z., Zhao, J., Huang, Q.J., Chen, J., and Hou, W.H.: S-doped Na2Ti6O13@TiO2 core–shell nanorods with enhanced visible light photocatalytic performance. Phys. Chem. Chem. Phys. 17, 15165 (2015).CrossRefGoogle ScholarPubMed
Brylev, O., Sarrazin, M., Roué, L., and Bélanger, D.: Nitrate and nitrite electrocatalytic reduction on Rh-modified pyrolytic graphite electrodes. Electrochim. Acta 52, 6237 (2007).CrossRefGoogle Scholar
Supplementary material: File

Wang et al. supplementary material

Wang et al. supplementary material 1

Download Wang et al. supplementary material(File)
File 1.1 MB